Petrology and thermobarometry of mafic granulites and migmatites from the Chafalote Metamorphic Suite: New insights into the Neoproterozoic P–T evolution of the Uruguayan—Sul-Rio-Grandense shield

This paper reports a study of the metamorphic evolution of pelitic, semi-pelitic migmatites and mafic granulites of the Chafalote Metamorphic Suite (CMS), Uruguay, which represents the southernmost exposures of high-grade metamorphic rocks in the Dom Feliciano Belt, Uruguain—Sul-Rio-Grandense shield, South America. This belt is one of the Brasiliano orogens that crop out along the Brazilian and Uruguayan Atlantic margin, and the CMS is one of several disconnected segments of supracrustal rock in a dominantly granitic terrain. Petrological evidence from CMS mafic granulites and semi-pelitic migmatites indicates four distinct metamorphic assemblages. The early prograde assemblage (M₁) is preserved only as inclusions in porphyroblasts of the peak-metamorphic (M₂) assemblage. Peak-metamorphism was followed by near-isothermal decompression (M₃), which resulted in symplectites and coronitic textures in the mafic granulites and compositional zoning of Ca in garnet (decreasing rimwards) and plagioclase (increasing rimwards) in the semi-pelitic migmatites. The retrograde metamorphic assemblage (M₄) is represented by hydration reaction textures replacing minerals of the M₂ and M₃ assemblages. Average P–T calculations using the program THERMOCALC and conventional thermobarometric methods yield peak-metamorphic (M₂) P–T conditions of 7–10 kbar and 830–950 °C, near-decompressional (M₃) P–T conditions of 4.8–5.5 kbar and 788–830 °C and M₄ retrograde P–T conditions of 3–6 kbar and 600–750 °C. The calculated P–T path for the CMS rocks is ‘clockwise’ and incorporates a near-isothermal decompression segment followed by minor cooling, consistent with a history of crustal thickening followed by extensional collapse at ca. 650–600 Ma. The metamorphism recorded by rocks of this crustal segment may be correlated with 650 Ma metamorphism in the Coastal Terrane of the Kaoko Belt in Namibia, being the first unequivocal match between South America and Africa provided by crystalline rocks south of the Congo Craton.     

Tidal effects on phytoplankton assemblages in a near‐pristine estuary: a trait‐based approach for the case of a shallow tropical ecosystem in Brazil

The study of near‐pristine estuaries can be used as a tool for mitigation projects of harmful effects in anthropogenic eutrophic systems, since one can analyze the effect of temporal and spatial variations generated mainly by natural forces. Phytoplankton taxonomy has been used as a classical indicator to assess changes in transitional water communities, however alternative methods based on morphological, behavioral and physiological traits offer the opportunity to compare sites or moments with different taxonomic compositions. Our goal, in this context, is to evaluate phytoplankton community short‐term and seasonal variability in a near‐pristine estuary, Barra Grande estuary (Ilha Grande, RJ, Brazil), through species functional traits and thus community functional diversity. Samplings were carried out in a mooring in complete tidal cycles, seasonally during 2012. Our results showed a diverse phytoplankton community with 38 frequent and abundant taxa, marked by density variation (1.2 × 10.4–2 × 10.7 cell L^?1) in depth, with abundance inversely related to tidal currents. The functional structure of the phytoplankton community measured by functional diversity (FD), varied seasonally in and across a gradient of tidal energy. A core community, mainly represented by flagellates and dinoflagellates, occurred in all observations and was highly functional (high FD), exploiting a variety of habitats. The chain‐forming diatoms were associated with high tidal energy, and occurred in higher densities during summer. Phytoplankton cell size, cell shape, and the ability to form colonies are extremely plastic traits that can be regulated by the environment, however, isolated tychopelagic diatoms were present in the study area across all seasons, with higher contributions in autumn and winter, reflecting the shallow characteristic of this system. During the winter, an exposed sandbar was formed, and the lack of connection with the ocean resulted in an abundance of riverine and brackish water taxa. In this near‐pristine estuary the densities and occurrences of HAB phytoplankton are low. Trait‐based analyses add information about community structure, which can be impacted by anthropogenic actions in urbanized coastal systems. Thus the information provided by this study regarding phytoplankton functional diversity and its relation to nutrients and hydrography in Barra Grande Estuary can be applied as a baseline model for the development of public policies.     

Poly-aromatic hydrocarbon (PAH) inputs from the Rhône River to the Mediterranean Sea in relation with the hydrological cycle: impact of floods

The concentrations of dissolved and particulate polycyclic aromatic hydrocarbons (PAHs) were monitored in waters of the Rhône River (France) every fortnight for a full calendar year, from June 1994 to May 1995. All flood events occurring over the course of the experiment were sampled at higher frequency to better quantify the impact of these extreme hydrological episodes on the annual export of PAHs to the Mediterranean Sea. This time-series indicates that more than 90% of the annual load of particulate PAHs is transported during flood episodes, with 77% discharged during the course of only one extreme flood event occurring in November 1994. During these intense events, riverine particles are depleted in PAHs while at low river discharge particles are PAH-enriched. Dissolved PAHs were less variable and less abundant than adsorbed PAHs, consistently with the low solubility of these compounds.     

Polycyclic Aromatic Hydrocarbons in the Arctic: Ob and Yenisei Estuaries and Kara Sea Shelf

Suspended matter (SM) and surface sediments were analysed for polycyclic aromatic hydrocarbons (PAH) throughout the Ob and Yenisei River estuaries and in the Kara Sea in order to evaluate the contamination of Arctic shelves by these two major Siberian rivers. PAH concentrations were extremely low, among the lowest measured up to now in the Arctic region. Particle-associated PAH were in many cases non-detectable. A total PAH maximum value of 3·2ngl ^{− 1}was found in surface waters. In surficial sediments, they spanned a range from 24 to 115ngg ^{− 2}in the Ob River, from 40 to 131ngg ^{− 2}in the Yenisei and from 16 to 94ngg ^{− 2}in the Kara Sea. Compositional features revealed a contribution of detrital material eroded from soils of the drainage basins and inputs from airborne pyrolytic PAH emitted at lower latitudes and from industrial complexes in Siberia. Particulate and sedimentary PAH distributions were highly variable both in type and concentration. The Ob and Yenisei estuaries are geographically large features where hydro-dynamical and sedimentary processes are complex. As a consequence, inhomogeneities—in the form of patch-structures—develop and make it difficult to resolve the fate of riverborne constituents based on ship measurements only. Remote sensing in conjunction with oceanographic observations may provide further guidance to study large river systems.     

Statistical analysis of high-frequency decimetric type III bursts

Here we report the statistical analysis of 160 isolated decimetric type III bursts, a majority of them (74%) having central frequency above 1000 MHz, observed in 8 flares by the spectrometer Phoenix. The most important finding of the detailed analysis is: 67% of all the bursts are reverse slope, 38% normal and 5% bi-directional. Also, we obtained the following results: (a) the best fits for the average half power duration and for the average drift rate as a function of frequency are given by t_1/2=1.7×10⁴f^–0.60and /df/dt|=(0.09±0.03)f^{(1.35 ± 0.10)}, respectively; (b) the frequency range of most of the type III bursts is less than 250 MHz; (c) the number of bursts decreases with increasing starting frequency and flux; (d) peak flux decreases with increasing frequency. The relations obtained fit well for higher frequency observations. Assuming an improved density model and type III emission at 2^ndharmonic, the beam parameters of type III bursts are determined.     

Mass and Metallurgical Balance Forecast for a Zinc Processing Plant Using Artificial Neural Networks

Natural Resources Research - The forecasting of ore concentrate and tailings mass and metallurgical recovery at a processing plant is not a simple task. It starts with data collection, which is...     

Narrow-band split frequency decimeter solar burst

A wide-band digital decimetric spectroscope is in the process of development at INPE (Brazil), in conjunction with a 9-m diameter polar mounted antenna. Initially, this spectroscope was operating over a narrow-band 1.6 ± 0.05 MHz in an analogue mode. Here we report a slow drifting 5.0 MHz s^-1, narrow-band 1630-1580 MHz, split frequency solar burst lasting for about 15 s, observed on 15 June, 1991. The separation between the split components is 30 MHz, and the upper split frequency component is more intense than the lower split frequency component. These observed characteristics favour the hypothesis of conversion of plasma waves by combinational scattering on upgoing ion-sound waves in a magnetic loop. Existing strong electron density gradients across the magnetic field in the source region will reduce the free-free absorption of radiation at the fundamental frequency. In order to explain the observed temporal characteristics of the upper and lower split frequency components, the radiation has to propagate at some angle to the electron density gradient in the source region. Estimated physical parameters of the source and exciters are as follows: (i) maximum source size (height) 2 × 10⁷ cm; (ii) velocity and length of ion-sound pulse 3.1 × 10⁶ cm s^-1 and 5 × 10⁷ cm, respectively, and (iii) velocity of the exciter of plasma waves (electron or proton beam) 5 × 10⁸ cm s^-1.On leave from the Institute of Applied Physics, Russian Academy of Sciences, Nizhny Novgorod, Russia.     

Distorted polyester lines for model testing of offshore moored platforms

Model tests of floating offshore platforms replace the mooring lines by inextensible cables connected to steel springs with a linear restoring capability. With the help of fundamental investigation on the similarity laws, the present work shows that the use of very thin polyester lines in model scaling is feasible and may allow a better physical representation of the full-scale polyester lines. The proposal is to use polyester lines with length distortion in order to keep the similar restoring capability and therefore, the same non-linear behavior would also be present during the tests. The work describes the application of these ideas in a model test of an Floating Production Storage and Offloading (FPSO) submitted to regular and random waves. The tests include both the linear spring lines and the distorted equivalent polyester lines, holding the FPSO model, submitted transversally to the same waves.