Geochemical Control of Heavy Metal Concentrations and Distribution Within Bahia Blanca Estuary (Argentina)

Chromium and lead concentrations and distribution have been fully studied within Bahía Blanca estuary inner area, which is strongly influenced by urban and industrial stress. Not only metals dissolved in estuarine water but also those included in sediments and suspended particulate matters (SPM) were measured. In all cases, internationally standardized protocols were applied to metal measurements, including analytical quality check test through analysis of certified reference materials. Total metal contents from surface sediments and SPM were compared with those from a historical database of the area, as well as with values representing the natural geochemical baseline within the system. Results showed that heavy metal pollution is mainly localized in the areas close to both industrial effluents discharge system and urban sewage outfall discharge. Data from sequential extractions indicate that metals from anthropogenic sources (i.e., Pb) are potentially more mobile than those inherited from geological parent material (i.e., Cr). The influences of other potential sources of metals (i.e., streams, runoff) were also considered. SPM was clearly identified as the main carrier of the studied heavy metals within the system, and its significance to metals input into sediments and/or biota was verified. Finally, the normalization of measured metal concentrations against background reference elements (i.e., Al or Fe) has allowed to identify that most of the measured Cr was lithogenic, while a significant percentage of Pb was from anthropogenic origin within Bahía Blanca estuary.     

An Experimental Study of the Statistics of Temperature Fluctuations in the Atmospheric Boundary Layer

A statistical characterization for two-point temperature fluctuations in the planetary boundary layer (PBL) is analyzed and its implications on the long-standing closure problem discussed. Despite the non-triviality of the dynamics of temperature fluctuations, our analysis supports the idea that the most relevant statistical properties can be captured solely in terms of two scaling exponents. They turned out to be weakly dependent on the stability properties of the PBL. Its statistics have been investigated by collecting data from a field experiment carried out in the urban area of Turin (Italy) from January 2007 to March 2008. Our results confirm those from a large-eddy simulation (LES) analysis carried out for the convective PBL with different level of convection. We extend the scenario to the stable PBL, a regime much more difficult to simulate when exploiting LES.     

Possible stellar asterisms carved on a protohistoric stone

Chisel marks on a stone uncovered in Rupinpiccolo protohistoric hill fort from north-eastern Italy were suggested to be a representation of the night sky (Bernardini et al. 2022 Documenta Praehistorica XLIX). The patterns of the 29 marks are analyzed here to establish if they reproduce popular stellar asterisms. Nine marks are found to match the Tail of Scorpius and five the Orion's Belt, together with Rigel and Betelgeuse. Nine marks are found in the approximate position of the Pleiades showing some match with the cluster members. On the back side, 5 marks possibly reproduce Cassiopeia. One mark slightly North of Orion cannot be identified. The 28 marks show a Pearson correlation coefficient $$(28) with stellar positions higher than 0.99 with a probability $$ of a wrong correlation lower than 0.001. Departures are about one degree, or about 7 mm, as the mean diameter of the marks, which suggests a manufacturing limitation in the charting. The fort dates $$1800–400 BCE when Scorpius and Orion showed about the same orientation at the heliacal rising. The unidentified mark challenges the whole picture. We suggest it could have been the progenitor of a failed supernova, thus offering also the possibility of a verification.