Geochemical constraints on the provenance of Oligocene–Miocene siliciclastic deposits (Zivah Formation) of NW Iran: implications for the tectonic evolution of the Caucasus

In this study, the whole-rock geochemistry of 35 Oligocene–Miocene sandstone and shale samples from the Zivah Formation, Moghan area (NW Iran) were collected and analyzed for evaluation of their provenance, tectonic setting and the intensity of paleo-weathering. Low to moderate values of the chemical index of alteration (mean CIA?=?53/68 for sandstones/shales) and relatively high values of index of compositional variability (mean ICV?=?1.23/1.08 for sandstones/shales) suggest weak chemical weathering and an immature source. These results support for the semi-arid and semi-humid paleoclimate conditions in the source area. The geochemistry results reveal that the sediments were deposited in a basin related to the island arc and active continental margin tectonic settings, probably indicating the time of initial collision between Arabia and Eurasia. The enrichment of Cr, Ni and V in the sandstone and shales are consistent with mafic input from the source area. However, La/Th vs. Hf and La/Sc vs. Co/Th plots reveal mixed source of felsic and intermediate volcanic rocks. The data indicate that the sediments most likely originated from a mixture of mafic, intermediate and felsic igneous source areas, possibly as the erosional products of localized topography of the Talysh and the Lesser Caucasus mountains (south to southwest), created by compression in the Moghan region during the syn-collisional development of the Caucasus.     

Facies Analysis and Sequence Stratigraphy of Silurian Carbonate Ramps in the Turan (Kopeh-Dagh) and Central Iran Plates with Emphasis on Gondwana Tectonic Event

Two sections from the Silurian deposits in the Central Iran Micro and Turan Plates were measured and sampled. These deposits are mostly composed of submarine volcanic rocks, skeletal and non-skeletal limestone, shale and sandstone that were deposited in low to high energy conditions (from tidal flat to deep open marine). According to gradual deepening trend, wide lateral distribution of facies as well as absence of resedimentation deposits, a depositional model of a homoclinal ramp was proposed for these deposits. Field observations and facies distribution indicate that, two depositional sequences were recognized in both sections. These sections show similarities in facies and depositional sequence during the Early Silurian in the area. Although there are some opinions and evidences that demonstrated Paleo-Tethys rifting phase started at the Late Ordovician-Early Silurian, similarities suggest that the Turan and Iran Plates were not completely detached tectonic block during this time, and that their depositional conditions were affected by global sea level changes and tectonic events.     

Palaeoecology and biostratigraphy of early Cretaceous (Aptian) calcareous nannofossils and the δCcarb isotope record from NE Iran

Upper Barremian-Lower Aptian sediments of the Sarcheshmeh and Sanganeh formations in the Kopet Dagh area, northeast Iran were studied with regard to their calcareous nannofossil content and their δ¹³C_carb signal. The sediments are composed mainly of marlstones, argillaceous limestones and limestones. Based on the occurrence of biostratigraphic index taxa, the calcareous nannofossil zones NC5, NC6 and the NC7A Subzone were recognised. The calcareous nannofossils and the δ¹³C_carb data enable recognition of the early Aptian Oceanic Anoxic Event 1a (OAE 1a). The deposits of the OAE 1a interval are characterised by the rarity of nannoconids and a sharp negative δ¹³C_carb excursion (1.36‰), followed by an abrupt positive δ¹³C_carb excursion of 4-5‰; both events have been recognised elsewhere in OAE 1a deposits in the Tethys. In the OAE 1a interval, the relative abundance of Watznaueria barnesiae/Watznaueria fossacincta is higher (more than 40%) than that of Biscutum spp., Discorhabdus spp. and Zeugrhabdotus spp., which indicates dissolution. In the upper part of the section, the higher relative abundance of mesotrophic and oligotrophic taxa (Watznaueria spp. and nannoconids respectively) and the enhanced relative abundance of eutrophic taxa (Biscutum spp., Discorhabdus spp., Zeugrhabdotus spp.) is indicative of an environment with slightly increased nutrient content. The presence of warm water taxa (Rhagodiscus asper and nannoconids) and the absence of cool water taxa (Repagulum and Crucibiscutum) suggest warm surface-water conditions.     

Determination of optimum relaxation coefficient using finite difference method for groundwater flow

Solution of Laplace’s equation can be done by iteration methods likes Jacobi, Gauss–Seidel, and successive over-relaxation (SOR). There is no new knowledge about the relaxation coefficient (ω) in SOR method. In this paper, we used SOR for solving Laplace’s differential equation with emphasis to obtaining the optimum (minimum) number of iterations with variations of the relaxation coefficient (ω). For this purpose, a code in FORTRAN language has been written to show the solution of a set of equations and its number of iterations. The results demonstrate that the optimum value of ω with minimum iterations is achieved between 1.7 and 1.9. Also, with increasing β?=??x/?y from 0.25 to 10, the number of iterations reduced and the optimum value is obtained for β?=?2.     

Historical changes in distribution and partitioning of natural and anthropogenic shares of heavy metals in sediment core from the southern Caspian Sea

Distribution of seven major and trace elements (aluminum, iron, calcium, cobalt, copper, vanadium and manganese) and total organic matter were assessed for sediment cores, collected from the southwest of Caspian Sea sediment in September 2008. Sedimentation rate of 0.9?cm/year was obtained based on ²¹⁰ Pb and ¹³⁷ Cs activity study of sediment cores. The major and trace metal distributions over whole lengths of core lengths (14?C168?cm) were found to be uniform (except for Al, Fe and Ca). Such uniform distribution of elements over whole lengths of the cores of the study area indicates similarity among the lithogenous material delivered into the Caspian Sea by rivers running into the southern coast. Enrichment factor (EF) and modified Muller??s formula of geoaccumulation index I _poll (intensity of pollution) evaluated the degree of sediment contamination. The results of pollution indices are indicative of non-pollution status in the area of study. From the first to third transect, Al, Fe and Mn concentrations increase. Heavy metal concentrations show relatively lower elemental concentrations in the third transect, possibly due to distance from anthropogenic sources. Cluster analysis shows Cu and Co grouped in different clusters, while Mn, V and Fe display closer similarity coefficients and similar sources. The results of partition studies reveal the percentile of loose ions portion of the metals as: $$ {\text{Cu}}\, (25.4\%) > {\text{Co}}\,(15.1\%)> {\text{Mn}}\,( {7.5\% }) > {\text{V}}\, (5.8\%) > {\text{Fe}}\,(0.2\%) $$ It shows that Cu and Co are the most mobile metals that can be easily released into water under changing environmental conditions. There seems to be a slight increasing trend in the pollution level of the sediments of the study area for copper and cobalt over the last 60?years.     

Application of carbon isotope chemostratigraphy to the Renison dolomites,Tasmania: A Neoproterozoic age

This study uses carbon isotope chemostratigraphy to propose an age for the Success Creek Group and Crimson Creek Formation in the absence of any direct radiometric dates, palaeomagnetic or reliable palaeontological data. The δ¹³C values were determined for the least‐altered dolomite samples. Suitable samples were selected on the basis of grainsize, cathodoluminescence petrography, most enriched δ¹⁸O values (> ‐2%o) low Mn/Sr ratios and low Fe and Mn concentrations. The average least‐altered, most ¹³C‐enriched dolomicrite samples in the youngest (No. 1) dolomite horizon are + 4.6%o. This is typical of Neoproterozoic (but not Cambrian) carbonates. The δ¹³C values of all dolomite samples in the succession are significantly positive (up to + 7.5%o) and the excursion characteristic of the Proterozoic/Cambrian boundary has not been observed. The lack of negative δ¹³C values in all dolomite samples studied also suggests an absence of correlatives of Sturtian and Varanger tillites in the dolomite successions. The δ¹³C values in all three dolomite horizons suggest a Neoproterozoic age between about 820 to 570 Ma (Cryogenian to Neoproterozoic III) on the current global compilation carbon isotope curves. This age for the Success Creek Group and Crimson Creek Formation, inferred from carbon isotope chemostratigraphy, can be substantiated by other evidence. The age of the Renison dolomites is constrained by K‐Ar dates of 708 ± 6 Ma from detrital muscovite in the underlying Oonah Formation and 588 ± 8 and 600 ± 8 Ma from doleritic rock in a lithostratigraphic equivalent of the Crimson Creek Formation from the Smithton Basin. Furthermore, acritarchs and the stromatolite Baicalia cf. B. burra also suggest a Neoproterozoic rather than Cambrian age.     

Effect of Location and Angle of Cutoff Wall on Uplift Pressure in Diversion Dam

Some facility for the prevention of piping, reducing exit gradient and seepage amount under hydraulic structures, is construction of cutoff wall and drain. Therefore, this study compares the efficiency of cutoff wall on some design parameters in an assumed diversion dam cross-section. For this purpose, different placements of cutoff wall with various angle of inclination were used in the dam foundation. Results of this study showed that minimum uplift pressure happens when cut off wall is in the heel (upstream) of the dam. With fixing of longitudinal cut off wall placement, inclination of cutoff wall respect to the vertical position, results in reducing of uplift pressure. Effect of inclination of cutoff wall in upstream of the dam; respect to vertical position, in reducing of uplift pressure is very high.     

Biostratigraphy of the Surgah formation in Kuh-e-Surgah and correlation with Tang-e-Gerab (West of Iran)

In biostratigraphic studies of the Surgah formation in the Kuh-e-Surgah section, 145 samples were collected. The thickness of the Surgah formation is about 175 m, and it consists mainly of limestone and shale. The lower and upper boundaries of the Surgah formation are Sarvak and Ilam formations, respectively, and they are conformable with sharp lithology. Seventeen species which belong to six genera of planktonic foraminifera and four biozones have been identified in this study. Based on foraminifera assemblages and biozone determinations, the age of the Surgah formation is Late Turonian to Early Late Santonian. This section is correlated with the Tang-e-Gerab section.     

Impact of tailings dam failure on spatial features of copper contamination (Mazraeh mine area,Iran)

Mining activities pose a potential risk of metal contamination around mining sites. On May 6, 2010, a tailings dam failure of the Mazraeh copper mine near Ahar in East Azerbaijan province, Iran, released vast amounts of mine wastes. To better understand the magnitude of copper contamination in the waste-affected soils, it is important to assess the spatial distribution of soil copper content at unsampled points. A total of 30 soil samples and their surficial sediments together with the 6 uncontaminated control samples (0–10 and 10–30 cm) were collected along the stream flow that joined Ahar-Chai River. Some of soil properties as well as total copper concentration were determined in all samples. The mean value of the latter in the surface contaminated soils was found to be approximately two times more than controls. Furthermore, the mean concentration of copper in the surface loaded material was 10 times more than the soils. High copper concentrations were observed in surficial sediments of the soils near the broken tailings dam. The Inverse Distance Weighting (IDW) method was employed in data analysis. The spherical and Gaussian semivariogram models were properly fitted to the data of copper contents in soils and surficial sediments.     

Petrography and geochemistry of Silurian Niur sandstones,Derenjal Mountains,East Central Iran: implications for tectonic setting,provenance and weathering

Petrographical and geochemical studies of Silurian Niur sandstones, Derenjal Mountains, Central Iran, were carried out to infer their provenance and tectonic setting. Modal analysis data of 37 medium sand size and well-sorted samples revealed that most quartz is composed of monocrystalline grains with straight to slightly undulos extinction and about 3 % polycrystalline quartz has inclusions, such as rutile needles. The sandstones are classified as quartzarenite, sublitharenite, and subarkose types based on framework composition and geochemistry. Petrographic studies reveal that these sandstones contain quartz, feldspars, and fragments of sedimentary rocks. The detrital modes of these sandstones indicate that they were derived from recycled orogen and stable cratonic source. Major and trace element contents of them are generally depleted (except SiO₂) relative to upper continental crust which is mainly due to the presence of quartz and absence of Al-bearing minerals. Modal composition (e.g., quartz, feldspar, and lithic fragments) and discrimination diagrams based on major elements, trace elements (Ti, La, Th, Sc, and Zr), and also such ratios as La/Sc, Th/Sc, La/Co, and Th/Co, in sandstones suggest a felsic igneous source rock and quartzose polycyclic sedimentary provenance in a passive continental margin setting. Furthermore, high Zr/Sc values in these sandstones are considered as a sign of recycling. We indicated paleo-weathering conditions by modal compositions, the CIA index and Al₂O₃?+?K₂O?+?Na₂O% vs. SiO₂% bivariate for these sandstones. Based on these results, although recycling is important to increase the maturity of the Niur sandstones, humid climate conditions in the source area have played a decisive role.