Water release patterns of heated speleothem calcite and hydrogen isotope composition of fluid inclusions

Speleothem fluid inclusions are a potential paleo-precipitation proxy to reconstruct past rainwater isotopic composition (δ¹⁸O, δD). To get a better insight in the extraction of inclusion water from heated speleothem calcite, we monitored the water released from crushed and uncrushed speleothem calcite, heated to 900 °C at a rate of 300 °C/h, with a quadrupole mass spectrometer. Crushed calcite released water in three not well individualised peaks between 25 and 360 °C, 360 and 650 °C and between 650 and 800 °C while uncrushed calcite released water in two distinct temperature intervals: between 25 and 550 °C and between 550 and 900 °C.Water from two speleothems from the Han-sur-Lesse cave was recovered using three different techniques: i) the crushing and heating to 360 °C technique, ii) the decrepitation by heating to 550 °C and iii) the decomposition by heating to 900 °C technique. Measurements of the δD of water recovered by the decomposition of Han-sur-Lesse calcite heated to 900 °C did not show a 20 to 30‰ offset as found by previous authors. However a difference of 7‰ was observed between water released before and after decomposition of the calcite. Water recovery from the Han-sur-Lesse samples suggests that a simple heating technique (up to 550 °C) without crushing could both (a) recover water with δD representative of that of the drip water and (b) double the water yield as compared to the crushing and heating method.Our study warns for possible contamination of the recovered inclusion water with hydration water of lime, responsible for the recovery of water with very negative δD values.     

Aerosol characterization and optical thickness retrievalsusing GOME and METEOSAT satellite data

Summary ?Retrievals of atmospheric aerosol optical thickness are highly dependent on the choice of the class describing the aerosol properties leading to significant errors while using classes available in the literature. High spectral resolution measurements from GOME (Global Ozone Monitoring Experiment) between the ultraviolet and the near infrared can be used for an accurate characterization of the aerosol optical properties. The radiometer MVIRI (METEOSAT Visible and Infrared Imager) on board the geostationary satellite METEOSAT, while being equipped only with broadband VIS channel, ensures an adequate half-hourly monitoring of the atmospheric conditions over a large portion of the Earth. The present algorithm is based on a combination of data from both sensors for the retrieval of the aerosol optical thickness at the reference wavelength of 0.55 μm (AOT). A case of a desert dust outbreak from the African continent over the Atlantic Ocean is examined. AOT values obtained using a priori fixed classes taken from the literature are compared with those retrieved with this algorithm using the GOME-derived classes. Systematic differences of the order of a few tenths on average are found which remain significant also after considering the measurement errors. This represents a novelty introduced by the synergetic use of both sensors. Received March 13, 2002     

Dérive à la surface de l'océan sous l'effet des vagues

We model the drift velocity near the ocean surface separating the motion induced by the local current, itself influenced by winds and waves, and the motion induced by the waves, which are generated by local and remote winds. Application to the drift of ‘tar balls’, following the sinking of the oil tanker Prestige-Nassau in November 2002, shows that waves contribute at least one third of the drift for pollutants floating 1 m below the surface, with a mean direction about 30° to the right of the wind-sea direction. Although not new, this result was previously obtained with specific models, whereas the formalism used here combines classical wave and circulation forecasting models. To cite this article: F. Ardhuin et al., C. R. Geoscience 336 (2004).     

Unusual features of the millisecond pulsar 1937 + 21 at 406.9 MHz

Observations of the millisecond pulsar PSR B1937 + 21 acquired in Summer 1997 with the Medicina cross telescope revealed two interesting features: the existence of long-lived microstructures persisting over several minutes, and a close relationship between the pulsar flux and pulse arrival times, due to refraction on a discrete inhomogeneity. The latter effect, though observed earlier at higher frequencies by the Nancay group, is rather peculiar at our low frequency.     

The economics of climate change impacts and policy benefits at city scale: a conceptual framework

Cities are particularly vulnerable to climate change and climate extremes in part because they concentrate many activities, people and wealth in limited areas. As a result they represent an important scale for assessment and understanding of climate change impacts. This paper provides a conceptual and methodological framework for urban economic impact assessment of climate change. The focus of the paper is on model-based analysis of future scenarios, including a framing of uncertainty for these projections, as one valuable input into the decision-making process. The paper highlights the main assessment difficulties, methods and tools, and selected examples across these areas. A number of challenges are unique to climate change impact assessment and others are unique to the problem of working at local scales. The paper also identifies the need for additional research, including the need for more integrated and systemic approaches to address climate change as a part of the urban development challenge as well as the need to assess the economic impacts of climate change and response policy at local scale.     

Monitoring gravel augmentation in a large regulated river and implications for process‐based restoration

The artificial gravel augmentation of river channels is increasingly being used to mitigate the adverse effects of river regulation and sediment starvation. A systematic framework for designing and assessing such gravel augmentations is still lacking, notably on large rivers. Monitoring is required to quantify the movement of augmented gravel, measure bedform changes, assess potential habitat enhancement, and reduce the uncertainty in sediment management. Here we present the results of an experiment conducted in the Rhine River (French and German border). In 2010, 23 000 m³ of sediments (approximately the mean annual bedload transport capacity) were supplied in a by‐passed reach downstream of the Kembs dam to test the feasibility of enhancing sediment transport and bedform changes. A 620‐m‐long and 12‐m‐wide gravel deposit was created 8 km downstream from the dam. Monitoring included topo‐bathymetric surveys, radio‐frequency particle tracking using passive integrated transponder (PIT) tags, bed grain size measurement, and airborne imagery. Six surveys performed since 2009 have been described (before and after gravel augmentation, and after Q₂ and Q₁₅ floods). The key findings are that (i) the augmented gravel was partially dispersed by the first flood event of December 2010 (Q₁); (ii) PIT tags were found up to 3200 m downstream of the gravel augmentation site after four years, but the effects of gravel augmentation could not be clearly distinguished from the effects of floods and internal remobilization on more than 3500 m downstream; (iii) linear and log‐linear relationships linking bedload transport, particle mobility, and grain size were established; and (iv) combined bathymetry and PIT tag surveys were useful for evaluating potential environmental risks and the first morpho‐ecological responses. This confirmed the complementary nature of such techniques in the monitoring of gravel augmentation in large rivers. Copyright © 2017 John Wiley & Sons, Ltd.