Thermodynamic behaviour of the high-temperature P\bar 1{\text{-}}I\bar 1 phase transition along the CaAl2Si2O8–SrAl2Si2O8 join

In situ high-temperature synchrotron radiation powder diffraction patterns were taken from room temperature to T = 740°C from synthetic feldspars along the join CaAl₂Si₂O₈–SrAl₂Si₂O₈ (An–SrF). Three samples of composition An₉₅SrF₅, An₉₀SrF₁₀ and An₈₅SrF₁₅ were investigated, and the evolution of cell parameters with T was determined by Rietveld analysis of powder X-ray diffraction patterns. The high-temperature $P\bar 1{\text{-}}I\bar 1$ phase transition, previously observed with T _c = 241°C in anorthite, was found in An₉₅SrF₅, An₉₀SrF₁₀ and An₈₅SrF₁₅ feldspars at T _c = 233(5)°, 195(2)° and 174(2)°C respectively. The transition was revealed by the disappearance of critical reflections and variations in the rate of change of cell parameters with temperature. A significant, although small (between 0.0025 and 0.0012 at room temperature), spontaneous strain could be measured, allowing the thermodynamic behaviour of the transition to be modelled. A second-order trend for An₉₀SrF₁₀ and An₈₅SrF₁₅ [β = 0.504(7) and 0.505(7) respectively] or nearly second-order for An₉₅SrF₅[β = 0.458(4)] was observed in contrast with tricritical behaviour of end member anorthite. An extrapolation of the T _c versus composition to room temperature indicates that the critical composition for the $P\bar 1$ phase is An₆₀SrF₄₀.     

A site effect study in the Verchiano valley during the 1997 Umbria-Marche (Central Italy) earthquakes

Strong site effects were observed during the two M _W 5.7 and M _W 6.0 main shocks of the Colfiorito seismic crisis which occured on September 26, 1997 in Umbria-Marche (Central Italy).The most obvious indications of these effects are the dramatic differences in damage shown by buildings of similar construction in neighboring villages.Such observations were specifically made in the Verchiano valley in the fault area, 15 km south of Colfiorito where the Verchiano village and the Colle and Camino hamlets were heavily damaged (MCS intensity IX-X) since the first main shock of 1997/09/26,while in contrast, the Curasci village located 2 km eastwards remains almost intact.In order to study the anomalous ground motion amplifications in this area, an array of 11, 3-components seismo- and accelero-meters was set up during the 1997/10/20-24 period, extending from the western side of the valley, up to the top of Mount San Salvatore, going accross the Colle and Curasci hamlets.During the experiment, 67 aftershocks enlightened the valley from the Colfiorito (10 km north) and the Sellano (6 km south) active swarms.Seismic refraction experiments were conducted at the same time in the 500 m wide, 1500 m long Verchiano valley in order to determine the thickness and main characteristics of the alluvial infilling.The main results are: (i) compared to the valley side ground motion, and for all the events, recordings in the central part of the valley (piana di Verchiano) show relative amplification of 10 with a clear lengthening of the seismogram duration by a factor of 2 – (ii) broad band relative amplification of 6–8 is also clearly identified at the top of the Mount San Salvatore overhanging the valley – (iii) any of the site effect measurements done explains by itself the strongly contrasted damage observed at Colle and Curasci: i.e. the modification of the near-field radiation pattern by interaction with the free heterogeneous surface may have induced local shadow zones that saved Curasci.     

Paleomagnetic constraints on the Plio–Pleistocene geodynamic evolution of the external central–northern Apennines (Italy)

We report on new paleomagnetic results obtained from 27 sites sampled in the Plio–Pleistocene sequences at the external front of the central–northern Apennines. Previous analyses of Miocene (Messinian) sediments indicated that the present shape of the northern Apenninic arc is due to the oroclinal bending of an originally straight belt oriented around N320° and that vertical axis rotations accompanied the migration of the thrust fronts toward the Adriatic foreland [F. Speranza et al., J. Geophys. Res. 102 (1997) 3153–3166]. We tried to provide new paleomagnetic constraints for the timing and rates of the oroclinal bending process during the Pliocene and the Pleistocene. The results suggest that CCW rotations observed in the northern part of the studied area are possibly younger than 3 Ma. No regional rotation is recorded in the Pliocene and Pleistocene sediments from the southern part of the study area, analogously to the Messinian sediments of the ‘Acquasanta’ domain of Speranza et al. [F. Speranza et al., J. Geophys. Res. 102 (1997) 3153–3166]. A local significant CCW rotation (23°±10°) is identified in the Early Pleistocene sediments that crop out along the Adriatic coast between Ascoli and Pescara, indicating differential motion of the thrust sheets. This rotation must be younger than 1.43 Ma.     

Testing the use of an image‐based technique to measure gully erosion at Sparacia experimental area

The first part of this investigation was aimed at testing the use of a three‐dimensional (3D) digital terrain model and a quasi‐tridimensional (2.5D) digital elevation model obtained by a large series of oblique images of eroded channels taken from consumer un‐calibrated and non‐metric cameras. For two closed earth channels having a different sinuosity, the ground measurement of some cross sections by a profilometer (P) was carried out and their real volume was also measured. The comparison among the three methods (3D, 2.5D, and P) pointed out that a limited underestimation of the total volume always occurs and that the 3D method is characterized by the minimum difference between measured and real volume. For this reason, 3D model can be used as benchmark. In the subsequent part of the investigation, the three ground measurement methods were applied for surveying of an ephemeral gully (EG) channel at the Sparacia area. The morphological and hydraulic variable values of the 24 surveyed cross sections determined by both 2.5D model and profilometer were compared. This comparison showed that the estimate error is generally less than ±10%. The EG measurements carried out by the three methods supported the applicability both of the empirical relationship between EG length and its eroded volume and the theoretical dimensionless relationship among the morphological variables describing the channelized erosion process. Finally, it was demonstrated that the effect of the distance interval on the EG volume measurement by 3D and 2.5D models is negligible for the investigated EG.     

Fluid geochemistry of natural manifestations from the Southern Poroto–Rungwe hydrothermal system (Tanzania): Preliminary conceptual model

The South Poroto–Rungwe geothermal field, in the northern part of the Malawi rift, Tanzania divides in two main areas. The relatively high altitude northern area around the main Ngozi, Rungwe, Tukuyu and Kyejo volcanoes, is characterised by cold and gas-rich springs. In contrast, hot springs occur in the southern and low-altitude area between the Kyela and Livingstone faults. The isotopic signature of the almost stagnant, cold springs of the Northern district is clearly influenced by H₂O–CO_2(g) exchange as evidenced from negative oxygen-shifts in the order of few deltas permil. In contrast, the isotopic signature of waters discharged from the hot springs of the Southern district is markedly less affected by the H₂O–CO_2(g) interaction. This evidence is interpreted as an effect of the large, permanent outflow of these springs, which supports the hypothesis of a regional-scale recharge of the major thermal springs. Measurements of carbon isotope variations of the dissolved inorganic carbon of waters and CO_2(g) from the Northern and Southern springs support a model of CO_2(g)-driven reactivity all over the investigated area. Our combined chemical and isotopic results show that the composition of hot springs is consistent with a mixing between (i) cold surface fresh (SFW) and (ii) Deep Hot Mineralised (DHMW) Water, indicating that the deep-originated fluids also supply most of the aqueous species dissolved in the surface waters used as local potable water. Based on geothermometric approaches, the temperature of the deep hydrothermal system has been estimated to be higher than 110 °C up to 185 °C, in agreement with the geological and thermal setting of the Malawi rift basin. Geochemical data point to (i) a major upflow zone of geothermal fluids mixed with shallow meteoric waters in the Southern part of the province, and (ii) gas absorption phenomena in the small, perched aquifers of the Northern volcanic highlands.     

CO<Subscript>2</Subscript>-driven large mafic explosive eruptions: the Pozzolane Rosse case study from the Colli Albani Volcanic District (Italy)

Generally, the intensity and magnitude of explosive volcanic activity increase in parallel with SiO₂ content. Pyroclastic-flow-forming eruptions in the Colli Albani ultrapotassic volcanic district (Italy) represent the most striking exception on a global scale, with volumes on the order of tens of cubic kilometres and K-foiditic compositions (SiO₂ even <42 wt.%). Here, we reconstruct the pre-eruptive scenario and event dynamics of the ~456 ka Pozzolane Rosse (PR) eruption, the largest mafic explosive event of the Colli Albani district. In particular, we focus on the driving mechanisms for the unusually explosive eruption of a low-viscosity, mafic magma. Geologic, petrographic and geochemical data with mass balance calculations, supported by experimental data for Colli Albani magma compositions, provide evidence for significant ingestion of carbonate wall rocks by the Pozzolane Rosse K-foiditic magma. Moreover, the scattered occurrence of cored bombs in Pozzolane Rosse pyroclastic-flow deposits records carbonate entrainment even at the eruptive time scale, as also tested quantitatively by thermal modelling of magma–carbonate interaction and carbonate assimilation experiments. We suggest that the addition of free CO₂ from decarbonation of country rocks was the major factor controlling magma explosivity. High CO₂ activity in the volatile component, coupled with magma depressurisation, produced extensive leucite crystallisation at short time scales, resulting in a dramatic increase in magma viscosity and volatile pressurisation, which was manifested a change of eruptive dynamics from early effusion to the Pozzolane Rosse's highly explosive eruption climax.     

Extrusion vs. accretion at the frictional–viscous décollement transition in experimental thrust wedges: the role of convergence velocity

In many cases, thrust wedges accreted at shallow crustal levels show an across‐strike rheological variability along the basal décollement, notably from brittle to ductile behaviour. In this paper, we illustrate the results of sandbox analogue modelling research devoted to studying the influence of convergence velocity on wedge architecture when laterally juxtaposed frictional and viscous materials occur along the basal décollement of accreting thrust wedges. Our results show that slow convergence favours a near symmetrical distribution of thrust vergence within wedge sectors accreted above viscous décollement material, whereas fast convergence favours vergence asymmetry. In particular, at fast convergence rates the hinterlandward extrusion of viscous décollement material at the toe of the frictional wedge is favoured and contributed to accommodate a significant amount of the total contraction. Terra Nova, 18, 241–247, 2006     

The Cosmic Foreground Explorer (COFE): A balloon-borne microwave polarimeter to characterize polarized foregrounds

The COsmic Foreground Explorer (COFE) is a balloon-borne microwave polarimeter designed to measure the low-frequency and low-ℓ characteristics of dominant diffuse polarized foregrounds. Short duration balloon flights from the Northern and Southern Hemispheres will allow the telescope to cover up to 80% of the sky with an expected sensitivity per pixel better than 100 μK/deg² from 10 GHz to 20 GHz. This is an important effort toward characterizing the polarized foregrounds for future CMB experiments, in particular the ones that aim to detect primordial gravity wave signatures in the CMB polarization angular power spectrum.     

Fault‐bend folding as an end‐member solution of (double‐edge) fault‐propagation folding

Fault‐bend folding is the most commonly used kinematic mechanism to interpret the architecture and evolution of thrust‐related anticlines in thrust wedges. However, its basic requirement of an instantaneous propagation of the entire fault before hangingwall deformation, limits its kinematic effectiveness. To overcome this limitation, we used the interdependence between fold shape and fault slip vs. propagation rate (S/P ratio) implemented in double‐edge fault‐propagation folding. We show that very small S/P values produce fault‐propagation anticlines that, when transported forelandward along an upper décollement layer, closely resemble fault‐bend anticlines. Accordingly, if small geometric discrepancies between the two solutions are accepted, transported double‐edge fault‐propagation provides an effective kinematic alternative to fault‐bend folding. Even at very low S/P values, it in fact predicts a fast but finite propagation rate of the fault. We thus propose that double‐edge fault‐propagation folding provides a broadly applicable model of fault‐related folding that includes fault‐bend folding as an end‐member kinematic solution. Terra Nova, 18, 270–275, 2006