Measurements of iron concentration in kaolinites considering disorder broadening of EPR lines

Only one part of the EPR lines of a kaolinite spectrum of structural Fe³⁺ is clearly observable because of the overlapping of other lines with other spectra. For this reason, to determine the structural Fe³⁺ concentration we used the line near g=9, although it is not intense. A standard is needed: powders of ZnS containing given concentrations of Mn²⁺ (isoelectronic to Fe³⁺) were used for this purpose. Using the simulations of the EPR spectra, the concentration (number of Fe³⁺ per Al³⁺) is determined; it is in the range 10^?5 to 10^?4 for our samples. Considering that the crystal-field disorder around Fe³⁺ is responsible for line broadening, we looked for a possible effect of the broadening on the intensity of the EPR spectra. This effect is taken as a distribution of the parameter λ=B₂²/B₂⁰. The influence of the parameter λ and its statistical distribution on the position, shape, width and intensity of the EPR line has been calculated using simulation procedures. The correction due to the disorder on the calculated concentration is of the same order of magnitude as the precision measurement. This method can be applied for other kaolinites by comparing the area of their g=9 lines with known ones.     

First direct age determination from the Jurassic radiolarian-bearing siliceous series (Jédidi Formation) of northwestern Tunisia

Our study presents preliminary biostratigraphic results from the Jurassic siliceous series of northwestern Tunisia. For the first time, radiolarians are extracted from the Jédidi formation and provide a direct age determination. They are the first radiolarian fauna documented from Tunisia. Two age assignments are comprised within the following intervals: (1) Late Bathonian–Early Callovian, (2) Late Bathonian–Early Oxfordian. These ages are compatible with recent stratigraphic synthesis proposed for the Jurassic series of Tunisia. The data suggest the correlation of the Jédidi formation with siliceous series of Middle–Late Jurassic age from the external zone of the Maghrebides belt rather than with true oceanic units from the Maghrebian flyschs or the internal zones of western Tethys. To cite this article: F. Cordey et al., C. R. Geoscience 337 (2005).     

SIMS analyses of oxygen isotopes: Matrix effects in Fe-Mg-Ca garnets

Large instrumental mass fractionation (IMF) may occur during measurements of oxygen isotope ratios by SIMS. Part of this fractionation depends on crystal structure and mineral composition. In order to improve the accuracy of SIMS measurements, we gathered 6 commonly used garnet standards and prepared 6 others to adequately cover the composition range Alm_0-73, Prp_0-99, Grs_0-20. Electron microprobe analyses were performed at UBP-Clermont to check the chemical homogeneity of these standards. Oxygen isotope compositions were determined by laser fluorination and mass spectrometry at UW-Madison. Ten SIMS sessions and 336 δ¹⁸O measurements at CRPG-Nancy, on a Cameca IMS1270 instrument, demonstrate that the standards are homogeneous with external reproducibility of 0.3‰ (1σ). In terms of δ¹⁸O, SIMS measurements indicate that, during a single session, IMF can vary up to 6.3‰ from one garnet standard to another. In most of the sessions, IMF can be correlated with the grossular content. However, for a satisfactory correction scheme, we suggest the combination of the 3 main components (Ca, Fe, Mg). This is done using a simple least square calculation routine. The correction coefficients determined for each session can be used to calculate the IMF and correct the measured isotopic ratio of a garnet of known chemical composition. This way, we were able to reproduce the δ¹⁸O values of most of the Fe-Mg-Ca garnet standards within ± 0.6‰. Interestingly, the use of only 3 end-member standards (AlmCMG, PrpMM, GrsSE) plus a standard of intermediate composition (e.g. UWG-2) is sufficient to reproduce δ¹⁸O within the same precision. Thus, linear interpolation among end-member standards is satisfactory in the case of the garnet solid-solutions. Two studies carried out on zoned garnets from the Alps and the Pyrenees indicate that matrix effects become significant when variations in grossular contents are important (> 10%). In order to obtain reliable isotope ratio measurements on Fe-Mg-Ca garnets using a SIMS, we suggest a correction scheme using at least 3 reliable end-member standards plus a standard of intermediate composition (a garnet standard closest to the average composition of the analysed garnet). This allows cross-checking and incorporates a correction based on the variations in composition of zoned crystals.     

Denudation rates of the Quadrilátero Ferrífero (Minas Gerais, Brazil): Preliminary results from measurements of solute fluxes in rivers and in situ-produced cosmogenic Be

This paper investigates the denudation rates in the Quadrilátero Ferrífero, Minas Gerais State (Brazil). The aim is to compare chemical weathering rates from measurements of solute fluxes in rivers and long-term mean erosion rates deduced from in situ-produced cosmogenic ¹⁰Be concentrations measured in fluvial sediments. Both water samples and sediments were collected in fifteen stations (checkpoints) located in four hydrographic basins with low anthropogenic perturbations.Depending of the type of substratum, three degrees of chemical denudation rates from water samples are observed: (i) high rates in marbles; (ii) medium rates in schists, phyllites, granites, gneisses and migmatites; (iii) low rates in quartzites and itabirites. Preliminary results of long-term erosion rates deduced from in situ-produced ¹⁰Be are comparable with those of chemical rates.     

New Perspectives on Mantle Dynamics from High-resolution Seismic Tomographic Model P1200

—Recently a high-resolution tomographic model, the P1200, based on P-wave travel times was developed, which allowed for detailed imaging of the top 1200 km of the mantle. This model was used in diverse ways to study mantle viscosity structure and geodynamical processes. In the spatial domain there are lateral variations in the transition zone, suggesting interaction between the lower-mantle plumes and the region from 600 km to 1000 km. Some examples shown here include the continental region underneath Manchuria, Ukraine and South Africa, where horizontal structures lie above or below the 660 km discontinuity. The blockage of upwelling is observed under central Africa and the interaction between the upwelling and the transition zone under the slow Icelandic region appears to be complex. An expansion of the aspherical seismic velocities has been taken out to spherical harmonics of degree 60. For degrees exceeding around 10, the spectra at various depths decay with a power-law like dependence on the degree, with the logarithmic slopes in the asymptotic portion of the spectra containing values between 2 and 2.6. These spectral results may suggest the time-dependent nature of mantle convection. Details of the viscosity structure in the top 1200 km of the mantle have been inferred both from global and regional geoid data and from the high-resolution tomographic model. We have considered only the intermediate degrees (l = 12–25) in the nonlinear inversion with a genetic algorithm approach. Several families of acceptable viscosity profiles are found for both oceanic and global data. The families of solutions for the two data sets have different characteristics. Most of the solutions asociated with the global geoid data show the presence of asthenosphere below the lithosphere. In other families a low viscosity zone between 400 and 600 km depth is found to lie atop a viscosity jump. Other families evidence a viscosity decrease across the 660 km discontinuity. Solutions from oceanic geoid show basically two low viscosity zones one lying right below the lithosphere; the other right under 660-km depth. All of these results bespeak clearly the plausible existence of strong vertical viscosity stratification in the top 1000 km of the mantle. The presence of the second asthenosphere may have important dynamical ramifications on issues pertaining to layered mantle convection. Numerical modelling of mantle convection with two phase transitions and a realistic temperature- and pressure-dependent viscosity demonstrates that a low viscosity region under the endothermic phase transition can indeed be generated self-consistently in time-dependent situations involving a partially layered configuration in an axisymmetric spherical-shell model.     

Genetic differentiation ofNiphargus rhenorhodanensis (Amphipoda) from interstitial and karst environments

Electrophoretic variation in proteins encoded by seven presumptive gene loci was analyzed in four populations of the stygobiont amphipodNiphargus rhenorhodanensis. The four populations occur in different habitats, including one in drainage canals, another from sediments of the Ain River, a tributary of the Rhône River, and the remaining two occur in a karstic massif (Dorvan, Ain, France) in the epikarstic and at the base level of the massif, respectively. Six of the seven loci were polymorphic within or among populations, with as many as three electromorphs segregating at the most variable loci. Significant deficiencies in the frequency of heterozygotes were common. Genetic divergence between the two populations of the Dorvan Massif and between the two of the Ain River (forest and sediment habitats) was large. This was highly unexpected, particularly in the case of the two hydrologically connected populations of the Dorvan Massif. It is suggested that either low migration rates or the presence of ecological barriers to gene flow may result in strong genetic differention among local populations ofNiphargus.     

Coastal conglomerates around the Hadjer el Khamis inselbergs (western Chad,central Africa): new evidence for Lake Mega‐Chad episodes

This paper reports on a study dealing with the rhyolitic inselbergs of Hadjer el Khamis that formed palaeoislands during Lake Mega‐Chad events. Field observations have shown that: (1) conglomeratic patches of immature to mature clasts are preserved at the feet of the Hadjer el Khamis inselbergs; (2) in cross‐section, their pro?le reveals a well de?ned cliff–platform junction at a constant elevation (325 m). The monolithological clasts show all degrees of roundness, from angular cobbles to well rounded pebbles. This wide range of maturity suggests a coastal origin for these cobbles. The system was permanently fed with angular clasts, which were progressively worn by waves. Cobbles that were wave‐worked for the longest time are the best rounded. The cliff–platform junction is the result of erosion by waves, which attacked and undercut the inselberg cliffs during Lake Mega‐Chad events. Asymmetrical erosion pro?les moreover suggest a wind regime dominated by SW to NE oriented winds. These interpretations have two implications. The elevation of the cliff–platform junction is an indication of the highest water level of Lake Mega‐Chad at 320–325 m, which is in agreement with other observations elsewhere in the basin. The SW to NE oriented winds show that monsoon‐related winds were prevalent during Lake Mega‐Chad events, suggesting the Inter‐Tropical Convergence Zone was located higher in latitude than today. Copyright © 2003 John Wiley & Sons, Ltd.     

Simulation des changements climatiques au cours du XXIe siècle incluant l'ozone stratosphériqueSimulation of climate changes during the 21st century including stratospheric ozone

Two climate simulations of 150 years, performed with a coupled ocean/sea-ice/atmosphere model including stratospheric ozone, respectively with and without heterogeneous chemistry, simulate the tropospheric warming associated with an increase of the greenhouse effect of carbon dioxide and other trace gases since 1950 and their impact on sea–ice extent, as well as the stratospheric cooling and its impact on ozone concentration. The scenario with heterogeneous chemistry reproduces the formation of the ozone hole over the South Pole from the 1970s and its deepening until the present time, and shows that the ozone hole should progressively fill during the coming decades. To cite this article: J.-F. Royer et al., C. R. Geoscience 334 (2002) 147–154.     

Significance of a combined approach for replacement stones in the heritage buildings’ conservation frame

Stone substitution is a conventional operation during heritage buildings’ restoration, but becomes problematic for architects and restorers when the quarry is mined out. The compatibility of the substitution stones with the original ones has been for long mainly based on the aesthetical aspect, this resulting too often in a patchwork of original and substitution stones with different patina after several years because of differences of properties. In this study, the objective is to show how substitution stones can be selected by combining aesthetic criteria and stones properties that are relevant for analyzing their compatibility. A couple of French limestones with their potential substitution stones were selected for the study. Our results showed that potential substitution stones selected on their aesthetic criteria require to be rejected because of their differences of physical properties. On the other hand, our results showed also the possibility to select substitution stones with satisfactory aesthetic aspect and properties that enable to expect a satisfactory compatibility with the original stone.     

Tracking past mining activity using trace metals,lead isotopes and compositional data analysis of a sediment core from Longemer Lake,Vosges Mountains,France

A 157-cm-long sediment core from Longemer Lake in the Vosges Mountains of France spans the past two millennia and was analyzed for trace metal content and lead isotope composition. Trace metal accumulation rates highlight three main input phases: Roman Times (cal. 100 BC–AD 400), the Middle Ages (cal. AD 1000–1500), and the twentieth century. Atmospheric contamination displays a pattern that is similar to that seen in peat bogs from the region, at least until the eighteenth century. Thereafter, the lake sediment record is more precise than peat records. Some regional mining activity, such as that in archaeologically identified eighteenth-century mining districts, was detected from the lead isotope composition of sediment samples. Compositional data analysis, using six trace metals (silver, arsenic, cadmium, copper, lead and zinc), enabled us to distinguish between background conditions, periods of mining, and of other anthropogenic trace metal emissions, such as the recent use of leaded gasoline.