Plagioclase nucleation and growth kinetics in a hydrous basaltic melt by decompression experiments

Isothermal single-step decompression experiments (at temperature of 1075 °C and pressure between 5 and 50 MPa) were used to study the crystallization kinetics of plagioclase in hydrous high-K basaltic melts as a function of pressure, effective undercooling (ΔT _eff) and time. Single-step decompression causes water exsolution and a consequent increase in the plagioclase liquidus, thus imposing an effective undercooling (?T _eff), accompanied by increased melt viscosity. Here, we show that the decompression process acts directly on viscosity and thermodynamic energy barriers (such as interfacial-free energy), controlling the nucleation process and favoring the formation of homogeneous nuclei also at high pressure (low effective undercoolings). In fact, this study shows that similar crystal number densities (N _a) can be obtained both at low and high pressure (between 5 and 50 MPa), whereas crystal growth processes are favored at low pressures (5–10 MPa). The main evidence of this study is that the crystallization of plagioclase in decompressed high-K basalts is more rapid than that in rhyolitic melts on similar timescales. The onset of the crystallization process during experiments was characterized by an initial nucleation event within the first hour of the experiment, which produced the largest amount of plagioclase. This nucleation event, at short experimental duration, can produce a dramatic change in crystal number density (N _a) and crystal fraction (?), triggering a significant textural evolution in only 1 h. In natural systems, this may affect the magma rheology and eruptive dynamics on very short time scales.     

The non‐stationary cross‐correlation coefficients in the seismic analysis of MDOF structural systems

A method concerning the evaluation, in a very compact form, of the non‐stationary modal cross‐correlation coefficients of MDOF structural systems subjected to seismic excitations is presented. It is available both in the case when the excitation is considered as a white‐noise process and when it is considered as a filtered process. The evaluation of these coefficients is required when a transient seismic analysis is performed by the use of the modal response spectrum approach. This is necessary when the strong‐motion phase of the earthquake is significantly short with respect to the fundamental period of the structure. Copyright © 2003 John Wiley & Sons, Ltd.     

Effects of near‐fault ground motions on the nonlinear dynamic response of base‐isolated r.c. framed buildings

Near‐fault ground motions are characterized by long‐period horizontal pulses and high values of the ratio between the peak value of the vertical acceleration, PGA_V, and the analogous value of the horizontal acceleration, PGA_H, which can become critical for base‐isolated (BI) structures. The objective of the present work is to check the effectiveness of the base isolation of framed buildings when using High‐Damping‐Rubber Bearings (HDRBs), taking into consideration the combined effects of the horizontal and vertical components of near‐fault ground motions. To this end, a numerical investigation is carried out with reference to BI reinforced concrete buildings designed according to the European seismic code (Eurocode 8). The design of the test structures is carried out in a high‐risk region considering (besides the gravity loads) the horizontal seismic loads acting alone or in combination with the vertical ones and assuming different values of the ratio between the vertical and horizontal stiffnesses of the HDRBs. The nonlinear seismic analysis is performed using a step‐by‐step procedure based on a two‐parameter implicit integration scheme and an initial‐stress‐like iterative procedure. At each step of the analysis, plastic conditions are checked at the potential critical sections of the girders (i.e. end sections of the sub‐elements in which a girder is discretized) and columns (i.e. end sections), where a bilinear moment–curvature law is adopted; the effect of the axial load on the ultimate bending moment (M‐N interaction) of the columns is also taken into account. The response of an HDRB is simulated by a model with variable stiffness properties in the horizontal and vertical directions, depending on the axial force and lateral deformation, and linear viscous damping. Copyright © 2011 John Wiley & Sons, Ltd.     

Vulnerability study on a large industrial area using satellite remotely sensed images

The aim of this paper is to disseminate knowledge in the seismic science community about a possible tool which is not largely popular, despite its potential usefulness. In this paper it will be shown how satellite remotely sensed images may represent a powerful source of information where traditional sources of information are unable to deliver it, or at least to do so timely. Even when traditional information flow can ensure delivery, an advantage may still be found in terms of sooner availability and smaller amount of labour required. In the case shown here a vulnerability study was made on a vast industrial area in the gulf of Siracusa, Sicily, Italy. A series of concurrent factors made it particularly troublesome to obtain information on the structures found in the site (tanks, pipes, chimneys, roads, ...), required to suitably carry out the study. Satellite images were then acquired to obtain the information needed. Processing of the images was carried out relying on in-house software formerly developed for similar information extraction issues, and integrated with new, specifically developed elements, some pieces of information were obtained useful for seismic risk evaluation. In particular, location, footprint, elevation of significant structures (e.g. tanks, chimneys) could be evaluated, obtaining results in a format compatible with the most widespread GIS (Geographic Information System) standards. Such compatibility allowed a considerable savings on labour time required to lay a GIS of the area, which is a fundamental tool for risk and vulnerability analyses.     

Influence of hydrostratigraphy and structural setting on the arsenic occurrence in groundwater of the Cimino-Vico volcanic area (central Italy)

Arsenic occurrence in groundwater near the Cimino-Vico volcanoes (central Italy) was analysed considering the hydrostratigraphy and structural setting and the shallow and deep flows interacting within the Quaternary volcanics. Groundwater is the local source of drinking water. As documented in the past, arsenic in the groundwater has become a problem, and the European maximum allowable contaminant level was recently lowered to 10 μg/L. Chemical analyses of groundwater were conducted, sampled over an area of about 900 km², from 65 wells and springs representative of the volcanic aquifer and thermal waters. Considering the type of aquifer, the nature of the aquifer formation and its substratum, the hydrochemical data highlight that the arsenic content of the groundwater is mainly connected with the hydrothermal processes in the volcanic area. Thermal waters (54–60°C) fed from deep-rising fluids show higher arsenic concentrations (176–371 μg/L). Cold waters sampled from the volcanic aquifer are characterized by a wide variability in their arsenic concentration (1.6–195 μg/L), and about 62% exceed the limit of 10 μg/L. Where the shallow volcanic aquifer is open to deep-rising thermal fluids, relatively high arsenic concentrations (20–100 μg/L) are found. This occurs close to areas of the more recent volcano-tectonic structures.     

What causes the spread of model projections of ocean dynamic sea-level change in response to greenhouse gas forcing?

Sea levels of different atmosphere–ocean general circulation models (AOGCMs) respond to climate change forcing in different ways, representing a crucial uncertainty in climate change research. We isolate the role of the ocean dynamics in setting the spatial pattern of dynamic sea-level (ζ) change by forcing several AOGCMs with prescribed identical heat, momentum (wind) and freshwater flux perturbations. This method produces a ζ projection spread comparable in magnitude to the spread that results from greenhouse gas forcing, indicating that the differences in ocean model formulation are the cause, rather than diversity in surface flux change. The heat flux change drives most of the global pattern of ζ change, while the momentum and water flux changes cause locally confined features. North Atlantic heat uptake causes large temperature and salinity driven density changes, altering local ocean transport and ζ. The spread between AOGCMs here is caused largely by differences in their regional transport adjustment, which redistributes heat that was already in the ocean prior to perturbation. The geographic details of the ζ change in the North Atlantic are diverse across models, but the underlying dynamic change is similar. In contrast, the heat absorbed by the Southern Ocean does not strongly alter the vertically coherent circulation. The Arctic ζ change is dissimilar across models, owing to differences in passive heat uptake and circulation change. Only the Arctic is strongly affected by nonlinear interactions between the three air-sea flux changes, and these are model specific.