Reactivity and point defects of double oxides with emphasis on simple silicates

Heterogeneous solid-state reactions in quasibinary oxide systems are analyzed. As long as local thermodynamic equilibrium prevails, diffusion processes through the reaction product are rate-controlling. The diffusion coefficients are governed by point-defect concentrations. Point-defect thermodynamics allow calculation of relative point-defect concentrations as a function of the relevant thermodynamic variables, if the disorder type of the crystalline product is known. Disorder types in ternary ionic crystals are introduced. On this basis, several reactions leading to simple silicates of the form A ₂ BO ₄ are discussed in terms of ion mobilities and Gibbs energies of formation, and the possible reaction mechanisms are analyzed. Finally some remarks are included on the influence of the gas atmosphere on the reaction rate, on powder reactions and on phase boundary-controlled reaction rates.     

Magmatische Würfelquarze in Rhyolithen (Quarzkeratophyren) des Rheinischen Schiefergebirges

Zusammenfassung Nach einer kurzen Erläuterung der Erkennungsmöglichkeit einfacher Kristallformen zur Unterscheidung von Hoch-und Tiefquarz wird das Auftreten von eindeutigen Würfelquarzen (Rhomboeder), und damit von Tiefquarzen, in Rhyolithen (Quarzkeratophyren) des südlichen Rheinischen Schiefergebirges (Bundesrepublik Deutschland) beschrieben. Diese Quarzrhomboeder-führenden Vulkanite lassen sich petrographisch wie auch chemisch von den übrigen Rhyolithtypen jenes Gebietes unterscheiden. Eine eindeutige genetische Aussage zur Bildung dieser Tiefquarze in einem Vulkanit ist nicht zu machen, es werden dazu zwei alternative Modelle vorgestellt.

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Pseudo-cubic quartz crystals of magmatic origin in rhyolites (quartz keratophyres) from the Rheinisches schiefergebirge

Summary Recognition of simple crystal forms for the distinction between high-and low-quartz is briefly outlined. Pseudo-cubic crystals of low-quartz are described from rhyolitic rocks (quartz keratophyres) of the southern Rheinisch Mountains (Federal Republic of Germany). These volcanics, carrying idiomorphic quartz rhombohedrons, can be distinguished by petrographic as well as by chemical means from the other rhyolites in that area. However, there is no decisive genetic solution to the origin of low-quartz in those volcanic rocks. Two alternative models are proposed.

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Mit 6 Abbildungen     

Geordnete Deponie von festen Siedlungs- und geeigneten Industrieabfällen

Ohne Zusammenfassung     

A model for the water regime of a deciduous forest

The relationships between actual evapotranspiration, atmospheric conditions and soil water content in the root zone are described in a simple functional model. Some constants which are used in these relationships, but unknown for forest areas, have been estimated for a deciduous forest near Zürich in Switzerland (Brülhart, 1969). On sufficiently humid soil the evapotranspiration of this forest was more than twice as high as for agricultural crops. On the other hand in the forest the evapotranspiration reacted much more sensitively on drying of the soil. On warm summer days (evaporation of free water about 0.4–0.6 cm per day) the trees considerably reduced their water delivery to the atmosphere at soil water suctions of slightly more then 0.05 bars (Fig. 7).