Measurement of stress effects (scope for growth) and contaminant levels in mussels (Mytilus edulis) collected from the Irish Sea

The objective of this research was to quantify the impact of pollution along the coastlines of the Irish Sea. Pollution assessment was based on the combined measurement of scope for growth (SFG), and chemical contaminants in the tissues of mussels (Mytilus edulis) collected from 38 coastal sites around the Irish Sea during June-July in 1996 and 1997. On the UK mainland coast, the SFG showed a general trend with a significant decline in water quality in the Liverpool and Morecambe Bay region. High water quality was recorded along the west coast of Wales, as well as southwest England and northwest Scotland (clean reference sites outside the Irish Sea). Along the coast of Ireland there was a similar trend with reduced SFG within the Irish Sea region. SFG was generally low north of Duncannon and then improved north of Belfast. The poor water quality on both sides of the Irish Sea is consistent with the prevailing hydrodynamics and the spatial distribution of contaminants associated with urban/ industrial development. The decline in SFG of mussels on both sides of the Irish Sea was associated with a general increase in contaminant levels in the mussels. Certain contaminants, including PAHs, TBT, sigmaDDT, Dieldrin, gamma-HCH, PCBs, and a few of the metals (Cd, Se, Ag, Pb), showed elevated concentrations. Many of these contaminants were particularly elevated in the coastal margins of Liverpool Bay, Morecambe Bay and Dublin Bay. A quantitative toxicological interpretation (QTI) of the combined tissue residue chemistry and SFG measurements indicated that at the majority of coastal sites, c. 50 to > 80% of the observed decline in SFG was due to PAHs as a result of fossil fuel combustion and oil spills. TBT levels were highest at major ports and harbours, but these concentrations only made a minor contribution to the overall reduction in SFG. At no sites were individual metals accumulated to concentrations that could cause a significant effect on SFG. The study identified many sites where the observed reduction in SFG was far greater than predicted from the limited number of chemical contaminants analysed, thus indicating the presence of additional 'unknown toxicants'. Sewage (containing domestic, agricultural and industrial components) appears to be an important contributor to reduced SFG and linear alkylbenzenes (LABs) and As may provide suitable 'sewage markers'. There was a highly significant positive correlation between SFG and As (P < 0.001). This relationship may be due to reduced As uptake by algal food material and mussels at sites with elevated P04 concentrations (e.g. at sites with sewage inputs). Phosphate is a known competitive inhibitor of As accumulation, at least in algae. The results highlight that further research is required on 'sewage markers' in mussels. The SFG approach therefore provides a rapid, cost-effective and quantitative measure of pollution impact, as well as a means of identifying the causes through a QTI of tissue contaminants levels. It also serves to identify the presence of unidentified toxicants and areas that require further study.     

Silica depleted melting of pelites. Petrogenetic grid and application to the Susqueda Aureole, Spain

Metapelitic rocks in the low pressure contact metamorphic aureole around the Susqueda igneous complex, Spain show a number of features that make them an ideal testing ground for the modelling of silica‐undersaturated melting. Rocks in the aureole experienced localized depletion in silica by the segregation of quartz veins during a pre‐anatectic, regional cordierite‐andalusite grade metamorphic event. These rocks were then intruded by gabbroic to dioritic rocks of the Susqueda igneous complex that formed a migmatitic contact metamorphic aureole in the country rocks. This migmatisation event caused quartz‐saturated hornfels and restite formation in rocks that had experienced no quartz vein segregation in the previous regional metamorphic event, but silica‐undersaturated melting in those rocks that were previously depleted in silica. Silica‐undersaturated melting is investigated using a new petrogenetic P–T projection and equilibrium pseudosections calculated in the KFMASH and NCKFMASH systems, respectively. The grid considers quartz absent equilibria and a range of phases that form typically in silica‐undersaturated bulk compositions, for example corundum. It is shown that the quartz‐rich precursors in the Susqueda contact aureole produced about 10% melt during contact metamorphism. However, most of this melt was extracted leaving behind rocks with restitic bulk compositions and minor leucosome segregation. It is suggested that the melt mixed with the host igneous rocks causing an apparent magmatic zoning from diorite in the centre of the complex to tonalite at the margins. In contrast, the quartz‐poor precursors (from which the quartz veins segregated) melted in the silica‐undersaturated field producing a range of assemblages including peritectic corundum and spinel. Melting of the silica‐undersaturated rocks produced only negligible melt and no subsequent melt loss.     

Intraplate deformation and 3D rheological structure of the Rhine Rift System and adjacent areas of the northern Alpine foreland

The lithosphere of the Northern Alpine foreland has undergone a polyphase evolution during which interacting stress-induced intraplate deformation and upper mantle thermal perturbations controlled folding of the thermally weakened lithosphere. In this paper we address relationships among deeper lithospheric processes, neotectonics and surface processes in the Northern Alpine foreland with special emphasis on tectonically induced topography. We focus on lithosphere memory and neotectonics, paying special attention to the thermo-mechanical structure of the Rhine Graben System and adjacent areas of the northern Alpine foreland lithosphere. We discuss implications for mechanisms of large-scale intraplate deformation and links with surface processes and topography evolution.     

Gamma-ray bursts: optical afterglows in the deep Newtonian phase

Gamma-ray burst remnants become trans-relativistic typically in days to tens of days, and they enter the deep Newtonian phase in tens of days to months, during which the majority of shock-accelerated electrons will no longer be highly relativistic. However, a small portion of electrons are still accelerated to ultra-relativistic speeds and are capable of emitting synchrotron radiation. The distribution function for electrons is re-derived here so that synchrotron emission from these relativistic electrons can be calculated. Based on the revised model, optical afterglows from both isotropic fireballs and highly collimated jets are studied numerically, and compared to analytical results. In the beamed cases, it is found that, in addition to the steepening due to the edge effect and the lateral expansion effect, the light curves are universally characterized by a flattening during the deep Newtonian phase.     

Lateral tidal mixing in the Antarctic marginal seas

Tidal mixing plays an important role in the modification of dense water masses around the Antarctic continent. In addition to the vertical (diapycnal) mixing in the near-bottom layers, lateral mixing can also be of relevance in some areas. A numerical tide simulation shows that lateral tidal mixing is not uniformly distributed along the shelf break. In particular, strong mixing occurs all along the Ross Sea and Southern Weddell Sea shelf breaks, while other regions (e.g., the western Weddell Sea) are relatively quiet. The latter regions correspond surprisingly well to areas where indications for cross-shelf exchange of dense water masses have been found. The results suggest that lateral tidal mixing may account for the relatively small contribution of Ross Sea dense water masses to Antarctic Bottom Water.     

A constitutive model for mechanical and chemo‐mechanical compaction in sedimentary basins and finite element analysis

Compaction and associated fluid flow are fundamental processes in sedimentary basin deformation. Purely mechanical compaction originates mainly from pore fluid expulsion and rearrangement of solid particles during burial, while chemo‐mechanical compaction results from Intergranular Pressure‐Solution (IPS) and represents a major mechanism of deformation in sedimentary basins during diagenesis. The aim of the present contribution is to provide a comprehensive 3D framework for constitutive and numerical modeling of purely mechanical and chemo‐mechanical compaction in sedimentary basins. Extending the concepts that have been previously proposed for the modeling of purely mechanical compaction in finite poroplasticity, deformation by IPS is addressed herein by means of additional viscoplastic terms in the state equations of the porous material. The finite element model integrates the poroplastic and poroviscoplastic components of deformation at large strains. The corresponding implementation allows for numerical simulation of sediments accretion/erosion periods by progressive activation/deactivation of the gravity forces within a fictitious closed material system. Validation of the numerical approach is assessed by means of comparison with closed‐form solutions derived in the context of a simplified compaction model. The last part of the paper presents the results of numerical basin simulation performed in one dimensional setting, demonstrating the ability of the modeling to capture the main features in elastoplastic and viscoplastic compaction. Copyright © 2016 John Wiley & Sons, Ltd.     

Hydrodynamical simulations of Galactic fountains – I. Evolution of single fountains

The ejection of the gas out of the disc in late-type galaxies is related to star formation and is due mainly to Type II supernovae. In this paper, we studied in detail the development of the Galactic fountains in order to understand their dynamical evolution and their influence on the redistribution of the freshly delivered metals over the disc. To this aim, we performed a number of 3D hydrodynamical radiative cooling simulations of the gas in the Milky Way where the whole Galaxy structure, the Galactic differential rotation and the supernova explosions generated by a single OB association are considered. A typical fountain powered by 100 Type II supernovae may eject material up to ∼2 kpc which than collapses back mostly in the form of dense, cold clouds and filaments. The majority of the gas lifted up by the fountains falls back on the disc remaining within a radial distance  Δ R = 0.5 kpc  from the place where the fountain originated. This localized circulation of disc gas does not influence the radial chemical gradients on large scale, as required by the chemical models of the Milky Way which reproduce the metallicity distribution without invoking large fluxes of metals. Simulations of multiple fountains fuelled by Type II supernovae of different OB associations will be presented in a companion paper.     

Simulating future Caspian sea level changes using regional climate model outputs

We report on simulations of present-day climate (1961–1990) and future climate conditions (2071–2100, Special Report on Emissions Scenario A2) over the Caspian sea basin with a regional climate model (RCM) nested in time-slice general circulation model (GCM) simulations. We also calculate changes (A2 scenario minus present-day) in Caspian sea level (CSL) in response to changes in the simulated hydrologic budget of the basin. For the present-day run, both the GCM and RCM show a good performance in reproducing the water budget of the basin and the magnitude of multi-decadal changes in CSL. Compared to present-day climate, in the A2 scenario experiment we find an increase in cold season precipitation and an increase in temperature and evaporation, both over land and over the Caspian sea. We also find a large decrease of CSL in the A2 scenario run compared to the present-day run. This is due to increased evaporation loss from the basin (particularly over the sea) exceeding increased cold season precipitation over the basin. Our results suggest that the CSL might undergo large changes under future climate change, leading to potentially devastating consequences for the economy and environment of the region.