Modelling nitrogen and oxygen isotope fractionation during denitrification in a lacustrine redox-transition zone

The stable isotope composition (δ¹⁵N and δ¹⁸O) of nitrate was measured during Summer 1999 in the anaerobic hypolimnion of eutrophic Lake Lugano (Switzerland). Denitrification was demonstrated by a progressive nitrate depletion coupled to increasing δ¹⁵N and δ¹⁸O values for residual nitrate. Maximum δ¹⁵N and δ¹⁸O values amounted to 27.2 and 15.7‰, respectively.¹⁵N and ¹⁸O enrichment factors for denitrification (ε) were estimated using a closed-system model and a dynamic diffusion-reaction model. Using the Rayleigh equation (closed-system approach), we obtained ε values of −11.2 and −6.6‰ for nitrogen and oxygen, respectively. The average ε values derived using the diffusion-reaction model were determined to be −20.7 ± 3.8 for nitrogen and −11.0 ± 1.7 for oxygen. Both N and O isotope fractionation appeared to be lower when denitrification rates where high, possibly in association with high organic carbon availability. In addition, variations in the isotope effects may be attributed to the variable importance of sedimentary denitrification having only a small isotope effect on the water column. The combined measurement of N and O isotope ratios in nitrate revealed that coupled nitrification-denitrification in the open-water was of minor importance. This is the first study of nitrogen and oxygen isotope effects associated with microbial denitrification in a natural lake. Moreover, this study confirms the high potential of δ¹⁸O of nitrate as a valuable biogeochemical tracer in aquatic systems, complementing nitrate δ¹⁵N.     

REE distribution in the resin-asphaltene fractions as a geochemical criterion for identification of sources of trace elements in oil

This paper reports REE data on resin-asphaltene components of oil from six oil-gas-bearing provinces and on bitumoids from inferred oil-source rocks (domanikites and bazhenites). It was shown that, regardless of geological-tectonic structure of the regions, oil composition, depth of reservoirs, and host lithologies, oil exhibits significant REE fractionation, and, unlike bitumoids, positive Eu anomaly. The (Eu/Sm)_n ratio increases from asphaltenes to resins and further to oils. Based on REE distribution in oil, source rocks, and bitumoids, it was concluded that deep-seated fluids were one of the possible sources that defined the trace element composition of oil.     

3d transition metal L-edge X-ray absorption studies of the dichalcogenides of Fe, Co and Ni

The X-ray absorption spectra of the transition metal L_3,2-edges of the dichalcogenides FeS₂ (pyrite), FeSe₂, FeTe₂, CoS₂, CoSe₂, CoTe₂, NiS₂, NiSe₂ and NiTe₂ have been studied. These spectra are compared with theoretical simulations make using the atomic multiplet approach assuming on octahedral site for the metal atoms. The Ni spectra can be closely simulated using this approach but the Fe and Co spectra show less good fits to the experimental data. The reasons for this and its implications for the use of L-edge spectra in the study of such minerals are discussed in terms of the covalency and the ground states of the compounds; these results indicate the mixing of the ground states increases in the order Ni<Co<Fe.     

Cosmological application of the New General Relativity

The field equations of the New General Relativity NGR, constructed by Hayashi and Shirafuji (1979), have been applied to two geometric structures, given by Robertson (1932), in the domain of cosmology. In the first application a family of models, involving two of the parameters characterizing the field equations of the NGR, is obtained. In the second application the models obtained are found to involve one parameter only. The cosmological parameters in both applications are calculated and some cosmological problems are discussed in comparison with the corresponding results of other field theories .     

Planetary atmosphere evolution:Do other habitable planets exist and can we detect them?

The goal of this conference is to consider whether it is possible within the next few decades to detect Earth-like planets around other stars using telescopes or interferometers on the ground or in space. Implicit in the term “Earth-like” is the idea that such planets might be habitable by Earth-like organisms, or that they might actually be inhabited. Here, I shall address two questions from the standpoint of planetary atmosphere evolution. First, what are the chances that habitable planets exist around other stars? And, second, if inhabited planets exist, what would be the best way to detect them?     

Nonlinear inertial oscillations of a multilayer eddy: An analytical solution

Nonlinear axisymmetric oscillations of a warm baroclinic eddy are considered within the framework of an reduced-gravity model of the dynamics of a multilayer ocean. A class of exact analytical solutions describing pure inertial oscillations of an eddy formation is found. The thicknesses of layers in the eddy vary according to a quadratic law, and the horizontal projections of the velocity in the layers depend linearly on the radial coordinate. Owing to a complicated structure of the eddy, weak limitations on the vertical distribution of density, and an explicit form of the solution, the latter can be treated as a generalization of the exact analytical solutions of this form that were previously obtained for homogeneous and baroclinic eddies in the ocean.     

On some characteristics of umbral fine structure

Photographic spectra of the umbra of a sunspot (1971, August 24, Rome No. 6205) around 6150 Å show fine bright threads which were identified as the spectra of a lightbridge, of the bright end of a penumbral filament and of umbral dots, respectively. It was found, in agreement with the results of other authors, that the magnetic field in bright structures is considerably weaker than in dark umbral material. Analysis of line profiles of Fe ii 6149.2 Å in umbral dots indicates (a) a fieldstrength reduced by a factor 2 compared to the surroundings, (b) an outflow with v3.0 km s^–1 relative to the penumbra and (c) possibly photospheric temperatures in umbral dots.Mitteilungen aus dem Fraunhofer Institut Nr. 115.     

Sunspot intensities and their correction for scattered light

Photoelectric measurements of monochromatic spot intensities obtained with the domeless Coudé refractor in Anacapri are given. The scattered light superimposed on the spot, as deduced from measurements outside the sun's limb, amounts on the average to about 4% of the photospheric intensity. The accuracy of the derived spot intensities is better than 10%. Two of four investigated spots yielded temperatures below 3900K (ΔΘ > 0.5).     

Solar wind induction in Mercury: Constraints on the formation of a magnetosphere

The discovery of Mercury's magnetosphere by Mariner 10 was surprising since the conventional view of regenerative planetary dynamos had been that the spin requirement would likely have been in excess of the observed spin rate of Mercury. Also internal fluid motions were not expected to be sufficiently large. This paper explores the alternative model of the formation of Mercury's magnetosphere via electromagnetic induction forced by the solar wind. It is shown, however, that the constraints are so severe as to limit severely the applicability of such a model. Although induction is easily observed on the Moon, the modification of the magnetic boundary condition associated with a plasma magnetosphere on Mercury rules out its formation via induction except for interplanetary driving fields which are decreasing in amplitude. That model is explored but retains the difficulty that induced magnetospheres tend to be of small radial and temporal extent compared to that inferred by Ness et al. for Mercury.