Distribution of trace and major elements in sediment and pore waters of the Lena Delta and Laptev Sea

Sediment cores collected during the SPASIBA expedition in 1991 were analysed for their trace- and major element concentrations. Leachable (0.1 N HCl) as well as residual concentrations were determined. Fe and Mn were measured in the interstitial waters to characterize redox conditions. Lateral distribution patterns of solid phase Cu, Cd, Ni, Pb and Zn show a small increase in concentration from the Lena Delta in seaward direction. In general concentrations of these metals are very low and similar to natural background values. With some exceptions, solid phase profiles with depth of all investigated elements do not show strong variations. No enrichment of Pb and Zn in surface layers was found. Remobilization processes and transport of particles enriched in Mn are responsible for Mn accumulation in a particular area. Pore-water concentrations of dissolved Mn in the latter sediments are very high (> 700 μM) and suggest strong Mn reduction directly below the sediment-water interface. In contrast to Mn, the depth profiles of Cd show a surface layer with lower concentrations and an increase deeper down the sediment. The C/N ratio in the sediment decreases from 13 in the Lena mouth to 9 in the more marine part of the Laptev Sea. Surface sediments in the Laptev Sea are very uniform and homogeneous and show only small concentration gradients.     

X-band sea-clutter nonstationarity: influence of long waves

In this paper, we deal with the problem of modeling the backscattering from sea surface for low-grazing-angle and high-resolution radar systems. Based on the electromagnetic two-scale model, we analyzed both the amplitude and frequency modulations induced on the small-scale Bragg resonant waves by the large-scale surface tilt and advection due to the swell presence. Evidence of sea-clutter nonstationarity has been verified and the relationship between the variations of clutter spectral features, such as texture, Doppler centroid, and bandwidth, have been studied by processing real sea-clutter data recorded by the IPIX radar of McMaster University, Hamilton, ON, Canada. An autoregressive nonstationary process is proposed and validated to model the physical phenomenon.     

Ecotone or Ecocline: Ecological Boundaries in Estuaries

Two main ecological boundaries, ecotone and ecocline, have been defined in landscape ecology. At this scale, the estuary represents a boundary between rivers and the sea, but there has been no attempt to fit empirical data for estuaries to these boundary models. An extensive data set from the Thames estuary was analysed using multivariate techniques and species-range analysis, in order to investigate whether the ecocline or the ecotone model was most relevant to this estuary. Data for periods of high and low freshwater flow allowed the impact of large-scale fluctuations implicit in both models to be determined.A continuum of assemblages existed along the salinity gradient from freshwater river to the North Sea, with shifts in the ranges of organisms apparent in response to changes in freshwater flow. This pattern closely fits an ecocline model. However, the estuary differs from previously defined ecoclines in having two overlapping gradients in the major stressor: from river to mid-estuary for freshwater species and from sea to mid-estuary for marine species. We propose, therefore, that the estuary represents a two-ecocline model, with fauna inhabiting the mid-estuary being either freshwater or marine species at the edge of their range, rather than ‘ true estuarine organisms ’. This allows a redefinition of the Remane diagram, with estuarine species removed, and supports previous arguments that brackish-water species do not exist. Such two-ecocline models may also exist in other marine systems, such as rocky shores.     

The composition and distribution of saturated and aromatic hydrocarbons in nearshore sediments, river sediments, and coastal peat of the Alaskan Beaufort Sea: Implications for detecting anthropogenic hydrocarbon inputs

A 3-year program, to determine spatial and temporal trends in sediment concentrations of hydrocarbons and metals from oil and gas exploration and development activities, was conducted in the US Beaufort Sea. Concentrations of saturated and aromatic hydrocarbons in sediments from the Beaufort Sea were elevated in comparison to non-polluted shelf-sediments from other regions of the US coast. Potential natural sources for hydrocarbons that were examined included riverine sediments and coastal peat. Significant quantities of fossil hydrocarbons characterize the surface sediments from the entire region. Sediment inputs from river discharges appear to account for this observation. The use of source-diagnostic ratios has allowed the differentiation of various sources in an area with high naturally-occurring hydrocarbon concentrations where effects due to oil and gas exploration and development activities may be obscured.     

Mud and fluid migration in active mud volcanoes in Azerbaijan

Mud volcanic eruptions in Azerbaijan normally last for less than a few hours, and are characterized by vigorous extrusion of mud breccias, hydrocarbon gases, and waters. Recent fieldwork and mapping on four active mud volcanoes show that dormant period activity ranges from quiet to vigorous flow of mud and fluids. Geochemical analyses of expelled waters show a wide range in solute concentrations, suggesting the existence of a complex plumbing system. The mud and fluids have a deep origin, but are sometimes stored in intermediate-depth mud chambers. A mixing model between deep-seated saline waters and shallow meteoric water is proposed.     

Large-scale in situ rotational failure on a low-angle delta slope: The Foreslope Hills,Fraser Delta,British Columbia,Canada

The Foreslope Hills are a series of ridges and troughs covering over 60 km² of the sea floor at the base of the Fraser Delta slope. Internally, the hills consist of blocks of prodelta and delta slope sediment (> 10.6 km³) bounded by offshore dipping faults and shear planes. Stratification within each block generally dips landward, indicating rotational failure. The amount of downslope translation of delta slope sediments was relatively minor. Deformation is restricted to a deep structural trough, suggesting failure resulted from yielding of soft underlying (early Holocene) prodelta sediments in the trough.     

Design of a tri-axial thrust anemometer for measurement of atmospheric turbulence over water

The BIO Mark 8 thrust anemometer measures the drag of the wind on a perforated table tennis ball mounted on a vertical beam. The tri-axial displacement of the beam is sensed by eddy current proximity sensors. This anemometer has a flat frequency response from 0 to 10 Hz and can measure wind from 0 to 28 m s⁻¹ at temperature from − 19 to + 28°C. It is designed for remote operation for extended periods of time such as on stable towers at sea.     

Nitrate reductase activity and the speciation of selenium at the mouth of Chesapeake bay

Nitrate reductase activity and the concentrations of selenite and selenate were monitored for six months at the mouth of Chesapeake Bay (USA). A positive correlation was found between nitrate reductase activity and the concentration of selenite, suggesting that selenite may be formed in coastal waters and nitrate reductase may be involved in the process.