The accuracy of altimétric surfaces

Summary. Estimates of the shape of the sea surface as determined from satellite altiméters have become of increasing importance in geophysics, geodesy and physical oceanography. The most effective error reduction procedures used in producing these surfaces have been some version of a crossing-arc analysis. The problem with this procedure is the absence of an easy means of evaluating the noise structure of the final result. By recasting the problem as one of objective mapping (optimal estimation) we both optimize the error reduction and obtain an explicit estimate of the wave-number structure of the final altimétric surface. Examples, suitable to a small computer, have been generated to show that the error reduction along the sub-satellite tracks is very great, with most of the residual lying in long wavelengths.     

Organic solids produced by electrical discharge in reducing atmospheres: Tholin molecular analysis

The complex dark brown solid of a class called tholins, produced on passage of an electrical discharge through a roughly equimolar mixture of methane and ammonia with 2.6% water vapor, is analyzed by vacuum pyrolysis followed by gas chromatography and mass spectrometry. Pyrolyzates include a wide range of aliphatic and aromatic nitriles, alkanes, aromatic hydrocarbons, pyrrole, and pyridine. This tholin is remarkably stable to 950°C. It and its degradation products are candidate constituents of planetary aerosols in the outer solar system and of the grains in the interstellar medium.     

A possible acceleration mechanism for a solar surge

We examine a non-linear mechanism for a solar surge in which plasma regions of high electrical conductivity and macroscopic dimension can be rapidly accelerated without diffusion of magnetic field. The mechanism is suggested by Rust's observations, which show that surges occur near sunspots in regions of reversed magnetic polarity. For the purposes of numerical calculation, we replace the magnetic field near a polarity reversal in a sunspot by magnetic fields of current loops. The relaxation of the magnetic field generated by two antiparallel coaxial current loops in an incompressible plasma is traced by computer. The results suggest that plasma in the form of a vortex ring can be expelled at the Alfvén velocity from active solar regions.     

The dynamics of tadpole and horseshoe orbits: II. The coorbital satellites of saturn

The recently discovered coorbital satellites of Saturn, 1980S1 and 1980S3, are shown to be librating in horseshoe orbits. By considering the effects of tangential forces on the semimajor axes of the satellite orbits, we derive an accurate relation between the sum of the satellite masses and (a) their minimum angular separation, (b) the variation of their angular separation with time and (c) the libration period. Observations of (b) and (c) are the most practical methods of determining the satellite masses. The orbits of the coorbital satellites of Dione and Tethys are discussed. We demonstrate the possibility of calculating a new value for the mass of Dione and we show that one of the coorbital satellites of Tethys could be moving in a horseshoe orbit even though another satellite is librating in a tadpole orbit about the leading Lagrangian equilibrium point L₄. The origin of coorbital satellites and the stability of their orbits are discussed.     

The mineral dissolution rate conundrum: Insights from reactive transport modeling of U isotopes and pore fluid chemistry in marine sediments

Pore water chemistry and ²³⁴U/²³⁸U activity ratios from fine-grained sediment cored by the Ocean Drilling Project at Site 984 in the North Atlantic were used as constraints in modeling in situ rates of plagioclase dissolution with the multicomponent reactive transport code Crunch. The reactive transport model includes a solid-solution formulation to enable the use of the ²³⁴U/²³⁸U activity ratios in the solid and fluid as a tracer of mineral dissolution. The isotopic profiles are combined with profiles of the major element chemistry (especially alkalinity and calcium) to determine whether the apparent discrepancy between laboratory and field dissolution rates still exists when a mechanistic reactive transport model is used to interpret rates in a natural system. A suite of reactions, including sulfate reduction and methane production, anaerobic methane oxidation, CaCO₃ precipitation, dissolution of plagioclase, and precipitation of secondary clay minerals, along with diffusive transport and fluid and solid burial, control the pore fluid chemistry in Site 984 sediments. The surface area of plagioclase in intimate contact with the pore fluid is estimated to be 6.9 m²/g based on both grain geometry and on the depletion of ²³⁴U/²³⁸U in the sediment via α-recoil loss. Various rate laws for plagioclase dissolution are considered in the modeling, including those based on (1) a linear transition state theory (TST) model, (2) a nonlinear dependence on the undersaturation of the pore water with respect to plagioclase, and (3) the effect of inhibition by dissolved aluminum. The major element and isotopic methods predict similar dissolution rate constants if additional lowering of the pore water ²³⁴U/²³⁸U activity ratio is attributed to isotopic exchange via recrystallization of marine calcite, which makes up about 10-20% of the Site 984 sediment. The calculated dissolution rate for plagioclase corresponds to a rate constant that is about 10² to 10⁵ times smaller than the laboratory-measured value, with the value depending primarily on the deviation from equilibrium. The reactive transport simulations demonstrate that the degree of undersaturation of the pore fluid with respect to plagioclase depends strongly on the rate of authigenic clay precipitation and the solubility of the clay minerals. The observed discrepancy is greatest for the linear TST model (10⁵), less substantial with the Al-inhibition formulation (10³), and decreases further if the clay minerals precipitate more slowly or as highly soluble precursor minerals (10²). However, even several orders of magnitude variation in either the clay solubility or clay precipitation rates cannot completely account for the entire discrepancy while still matching pore water aluminum and silica data, indicating that the mineral dissolution rate conundrum must be attributed in large part to the gradual loss of reactive sites on silicate surfaces with time. The results imply that methods of mineral surface characterization that provide direct measurements of the bulk surface reactivity are necessary to accurately predict natural dissolution rates.     

Spatial Representation of Aquatic Vegetation by Macrofossils and Pollen in a Small and Shallow Lake

We have explored the contemporary spatial relationship between aquatic vegetation and surficial macrofossil and pollen remains in a small, shallow, English lake. A detailed point-based (n = 87) underwater vegetation survey was undertaken in the middle of the plant-growing season in July 2000. Then following plant die-back in November 2000, surface sediment samples (upper 1.5 cm) were collected from 30 of these plant survey points and analysed for plant macro-remains (all 30 samples), and pollen (4 evenly spaced samples). All data were stored as separate layers in a geographical information system and spatial relationships between the aquatic vegetation and plant remains were explored. In contrast to pollen types, plant macrofossils were not evenly dispersed across all parts of the lake and, with the exception of Chara oospores, higher concentrations of remains (particularly for Potamogeton) were found close to areas of source-plant dominance. The spatial pattern of macrophyte–macrofossil relationships revealed that vegetative remains (particularly leaf fragments) were probably deposited at source, whereas seeds were recovered close to the shore suggesting slightly wider dispersal. Overall, however, macro-remains best represented local ‘patch-scale’ vegetation within 20–30 m of the core site. The macro-remains effectively recorded the dominant plants in the lake with 63% of samples containing a combination of remains of Chara, Elodea, and Potamogeton. However, relationships between macrophytes and fossils were complex. Some species were significantly over-represented by macrofossils (e.g., Chara spp., Nitella flexilis agg., and Zannichellia palustris), while others were either under-represented (e.g., Potamogeton spp.), or not represented at all (e.g., Lemna trisulca). Pollen represented macrophyte diversity poorly, but some taxa were found (e.g., Myriophyllum spicatum, Ceratophyllum demersum) that were not recorded by macro-remains. We conclude that macrofossil analysis may be very usefully employed to determine the dominant taxa in past aquatic plant communities of shallow, productive lakes and that the addition of pollen analysis provides further information on former species richness.     

The use of short‐lived radionuclides to quantify transitional bed material transport in a regulated river

We investigate the use of the short‐lived fallout radionuclide beryllium‐7 (⁷Be; t_1/2 = 53·4 days) as a tracer of medium and coarse sand (0·25–2 mm), which transitions between transport in suspension and as bed load, and evaluate the effects of impoundment on seasonal and spatial variations in bed sedimentation. We measure ⁷Be activities in approximately monthly samples from point bar and streambed sediments in one unregulated and one regulated stream. In the regulated stream our sampling spanned an array of flow and management conditions during the annual transition from flood control in the winter and early spring to run‐of‐the‐river operation from late spring to autumn. Sediment stored behind the dam during the winter quickly became depleted in ⁷Be activity. This resulted in a pulse of ‘dead’ sediment released when the dam gates were opened in the spring which could be tracked as it moved downstream. Measured average sediment transport velocities (30–80 metres per day (m d^?1)) exceed those typically reported for bulk bed load transport and are remarkably constant across varied flow regimes, possibly due to corresponding changes in bed sand fraction. Results also show that the length scale of the downstream impact of dam management on sediment transport is short (c. 1 km); beyond this distance the sediment trapped by the dam is replaced by new sediment from tributaries and other downstream sources. Copyright © 2006 John Wiley & Sons, Ltd.     

Effects of an Acute Hypoxic Event on Microplankton Community Structure in a Coastal Harbor of Southern California

Fish mortality and hypoxic events occur in many coastal and inland systems and may result from natural or anthropogenically mediated processes. The effects of consequent changes in water biogeochemistry have been investigated for communities of benthic invertebrates and pelagic metazoans. The responses of micro-plankton assemblages, however, have remained largely unstudied. The northern basin of King Harbor, a small embayment within Santa Monica Bay, CA, USA, suffered a massive fish kill in March 2011 as a consequence of acute hypoxia. Dissolved oxygen concentrations < 0.1 ml?l^?1 were measured in the northern basin of the harbor for several days following the mortality event, and a strong spatial gradient of oxygen was observed from the northern basin to waters outside the harbor. The microplankton community within King Harbor differed significantly from a diatom-dominated community present in neighboring Santa Monica Bay. The latter region appeared unaffected by physicochemical changes, induced by the fish kill, that were observed within the harbor. A trophic shift was observed throughout King Harbor from a photoautotrophic-dominated assemblage to one of heterotrophic forms, with relative abundances of bacterivorous ciliates increasing by more than 80 % in the most impacted part of the harbor. Significant changes in community structure were observed together with dramatically reduced photosynthetic yield of the remaining phytoplankton, indicating severe physiological stress during the extreme hypoxia.