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71.
Eugenio Aragn Adrian Mario Iiguez Rodriguez Alfredo Benialgo 《Journal of South American Earth Sciences》1996,9(5-6)
Major volcanogenic structures within the Marifil Formation allowed to determine the location of a claderas field that spreads along 400 kilometers. This field has at least three large calderas with diameters near to 100 kilometers, recognizable by regional distribution of associated dikes and rhyolite lava flows present at the caldera border that separates a monotonous ignimbritic plateau from a depressed (150 meters) inner volcanic collapsed caldera. The Marifil ignimbritic plateau cover more than 50,000 square kilometers with thicknesses that reach 800 meters. Associated with these plateau ignimbrites there is an important fluorite mineralization. 相似文献
72.
Heavy metal retention in secondary precipitates from a mine rock dump and underlying soil, Dalarna, Sweden 总被引:7,自引:2,他引:7
This study investigates the retention of heavy metals in secondary precipitates from a sulfidic mine rock dump and underlying
podzolic soils by means of mineralogical and chemical extraction methods. The rock dump, which is at least 50 years old, consists
of a 5–10-cm-thick leached zone and an underlying 110–115-cm-thick accumulation zone. Optical microscopy and electron microprobe
analyses confirm that pyrrhotite weathering has proceeded much further in the leached horizon relative to the accumulation
horizon. The weathering of sulfides in the leached zone has resulted in the migration of most heavy metals to the accumulation
zone or underlying soils, where they are retained in more stable phases such as secondary ferric minerals, including goethite
and jarosite. Some metals are temporarily retained in hydrated ferrous sulfates (e.g., melanterite, rozenite).
Received: 28 October 1996 · Accepted: 24 February 1997 相似文献
73.
Colin S. Doyle Tom Kendelewicz Gordon E. Brown Jr 《Geochimica et cosmochimica acta》2004,68(21):4287-4299
We have used synchrotron-based soft X-ray core-level photoemission and adsorption spectroscopies to study the reaction of aqueous sodium chromate solutions with freshly fractured pyrite surfaces. Pyrite surfaces were reacted with 50 μM sodium chromate solution at pH 7 for reaction times between 1 min and 37 hr. Additional experiments were performed at pH 2 and pH 4 with 50 μM sodium chromate solutions and at pH 7 with 5 mM solutions. At chromate concentrations of 50 μM, all chromium present on the pyrite surface was in the form of Cr(III), while at 5 mM, both Cr(III) and Cr(VI) were present at the pyrite surface. Minor quantities of oxidized sulfur species (sulfate, sulfite, and zero-valent sulfur) were identified as reaction products on the pyrite surface. The amount of oxidized sulfur species observed on the surface was greater when pyrite was reacted with 5 mM Cr(VI) solutions because the rate of chromium deposition exceeded the rate of dissolution of pyrite oxidation products, effectively trapping Cr(VI) and oxidized sulfur species in an overlayer of iron(III)-containing Cr(III)-hydroxide. This work shows that pyrite, an extremely cheap and readily available waste material, may be suitable for the removal of hexavalent chromium from acidic to circumneutral waste streams. The reduced chromium ultimately forms a coating on the pyrite surface, which passivates the pyrite surface towards further oxidation. 相似文献
74.
75.
The Karst Feature Database (KFD) of Minnesota is a relational GIS-based Database Management System (DBMS). Previous karst feature datasets used inconsistent attributes to describe karst features in different areas of Minnesota. Existing metadata were modified and standardized to represent a comprehensive metadata for all the karst features in Minnesota. Microsoft Access 2000 and ArcView 3.2 were used to develop this working database. Existing county and sub-county karst feature datasets have been assembled into the KFD, which is capable of visualizing and analyzing the entire data set. By November 17 2002, 11,682 karst features were stored in the KFD of Minnesota. Data tables are stored in a Microsoft Access 2000 DBMS and linked to corresponding ArcView applications. The current KFD of Minnesota has been moved from a Windows NT server to a Windows 2000 Citrix server accessible to researchers and planners through networked interfaces. 相似文献
76.
The phase relations of quaternary systems are generally represented by projections onto ternary compositional planes. Such
projections often obscure relationships that would only be evident in a three-dimensional tetrahedral plot. The tetrahedral
plot requires that compositions of the minerals and melts be transformed into Cartesian coordinates. It is shown here how
this transformation is carried out. The application is demonstrated by tetrahedral plots of experimental melt compositions
of partially molten lherzolite. Furthermore, the plot can be used to evaluate whether or not a particular basaltic composition
represents a primary melt. The methods are applicable to any four-component system. 相似文献
77.
Atomic force microscopy (AFM) and Derjaguin-Landau-Verwey-Overbeek (DLVO) theory in combination with the interaction force boundary layer (IFBL) model have been used to empirically and theoretically calculate sticking efficiencies (α) of Enterococcus faecalis cells against a silica glass surface. Sticking efficiencies were calculated in solutions of varying pH and ionic strength and related to maximum distances of transport through a hypothetical soil block using colloid filtration theory.AFM measurements show that the repulsive and attractive forces between E. faecalis cells and a glass surface are a function of ionic strength but are less sensitive to changes in solution pH. Zeta (ζ)-potential measurements of the cells and glass surfaces correlate with these trends. Calculated DLVO energy profiles predict much greater sensitivity to changing solution chemistry. Sticking efficiencies derived from AFM measurements range from 9.6 × 10−17 to 1 in solutions of low ionic strength (IS) and from 2.6 × 10−33 to 1 at higher IS. Corresponding α values determined from DLVO theory are essentially zero in all tested solutions.Sticking efficiencies calculated in this study are smaller than values determined from column and field studies in similar systems; however, α derived from AFM data and the IFBL model more closely represent field data than do values calculated from DLVO energy values. A comparison with different methods of calculating α suggests that reversible adhesion may be significant in column-scale transport studies. 相似文献
78.
Uranyl adsorption onto montmorillonite: Evaluation of binding sites and carbonate complexation 总被引:2,自引:0,他引:2
The fate and transport of uranium in contaminated soils and sediments may be affected by adsorption onto the surface of minerals such as montmorillonite. Extended X-ray absorption fine structure (EXAFS) spectroscopy has been used to investigate the adsorption of uranyl (UO22+) onto Wyoming montmorillonite. At low pH (∼4) and low ionic strength (10−3 M), uranyl has an EXAFS spectrum indistinguishable from the aqueous uranyl cation, indicating binding via cation exchange. At near-neutral pH (∼7) and high ionic strength (1 M), the equatorial oxygen shell of uranyl is split, indicating inner-sphere binding to edge sites. Linear-combination fitting of the spectra of samples reacted under conditions where both types of binding are possible reveals that cation exchange at low ionic strengths on SWy-2 may be more important than predicted by past surface complexation models of U(VI) adsorption on related montmorillonites. Analysis of the binding site on the edges of montmorillonite suggests that U(VI) sorbs preferentially to [Fe(O,OH)6] octahedral sites over [Al(O,OH)6] sites. When bound to edge sites, U(VI) occurs as uranyl-carbonato ternary surface complexes in systems equilibrated with atmospheric CO2. Polymeric surface complexes were not observed under any of the conditions studied. Current surface complexation models of uranyl sorption on clay minerals may need to be reevaluated to account for the possible increased importance of cation exchange reactions at low ionic strengths, the presence of reactive octahedral iron surface sites, and the formation of uranyl-carbonato ternary surface complexes. Considering the adsorption mechanisms observed in this study, future studies of U(VI) transport in the environment should consider how uranium retardation will be affected by changes in key solution parameters, such as pH, ionic strength, exchangeable cation composition, and the presence or absence of CO2. 相似文献
79.
We investigate the influence of mantle flow relative to the lithosphere on subduction dynamics. We use 2D thermo‐mechanical models assuming incompressible non‐Newtonian fluid rheology. Different mantle flow velocities consistent with absolute plate motion models are tested, as well as both directions of flow, either sustaining or opposing slab dip. The effects of different inflow/outflow velocity profiles, slab strengths and upper–lower mantle viscosity contrasts are also evaluated. Slab dip deviations between models with opposite mantle flow directions range from 37° for relatively strong slabs (ηmax = 1025 Pa s) to 50° for weaker slabs (ηmax = 1024 Pa s), accounting for a significant amount of natural slab dip variability. For imposed mantle flow supporting the slab, the initial stage of slab steepening is followed by a stage of continuous slab dip decrease. This slab shallowing eventually leads to mantle wedge closure, subduction cessation and slab break‐off, possibly driving subduction flips. 相似文献
80.
James R. Ledwell Dennis J. McGillicuddy Jr. Laurence A. Anderson 《Deep Sea Research Part II: Topical Studies in Oceanography》2008,55(10-13):1139
An intense deep chlorophyll layer in the Sargasso Sea was reported near the center of an anticyclonic mode-water eddy by McGillicuddy et al. [2007. Eddy–wind interactions stimulate extraordinary mid-ocean plankton blooms, Science, accepted]. The high chlorophyll was associated with anomalously high concentrations of diatoms and with a maximum in the vertical profile of 14C primary productivity. Here we report tracer measurements of the vertical advection and turbulent diffusion of deep-water nutrients into this chlorophyll layer. Tracer released in the chlorophyll layer revealed upward motion relative to isopycnal surfaces of about 0.4 m/d, due to solar heating and mixing. The density surfaces themselves shoaled by about 0.1 m/d. The upward flux of dissolved inorganic nitrogen, averaged over 36 days, was approximately 0.6 mmol/m2/d due to both upwelling and mixing. This flux is about 40% of the basin wide, annually averaged, nitrogen flux required to drive the annual new production in the Sargasso Sea, estimated from the oxygen cycle in the euphotic zone, the oxygen demand below the euphotic zone, and from the 3He excess in the mixed layer. The observed upwelling of the fluid was consistent with theoretical models [Dewar, W.K., Flierl, G.R., 1987. Some effects of wind on rings. Journal of Physical Oceanography 17, 1653–1667; Martin, A.P., Richards, K.J., 2001. Mechanisms for vertical nutrient transport within a North Atlantic mesoscale eddy. Deep-Sea Research II 48, 757–773] in which eddy surface currents cause spatial variations in surface stress. The diapycnal diffusivity at the base of the euphotic zone was 3.5±0.5×10−5 m2/s. Diapycnal mixing was probably enhanced over more typical values by the series of storms passing over the eddy during the experiment and may have been enhanced further by the trapping of near-inertial waves generated within the eddy. 相似文献