Optimization of the freeze pipe arrangement and the necessary refrigeration plant capacity by a femcomputer program

The number and the arrangement of freeze pipes and the energy needed to freeze a certain amount of soil are important factors for the economic success of a freeze project. A thermal design in which these factors are considered is based on the solution of a nonlinear unsteady heat conduction equation including phase transition. The equation is solved by means of a finite-element-method (FEM), considering boundary conditions related to artificial ground freezing.

In this paper the basic mathematical techniques to deal with the transient heat conduction problem, with temperature-dependent soil properties, and the release of latent heat are described. The significance of the convective heat transfer coefficient and the temperature distribution in the coolant running through the freeze pipes are shown and their dependencies to other factors as refrigeration plant capacity or type of flow in the pipes are considered. Finally an example is presented.     

Hermann Wilhelm Abich im Kaukasus: Zum zweihundertsten Geburtstag

Hermann Abich was born in 1806 in Berlin and died in 1886 in Graz. He grew up in a wealthy family which had friendly relations with famous scientists like Alexander von Humboldt, Leopold von Buch or Carl Ritter. After his studies in Heidelberg and Berlin he turned to extended fieldwork at the volcanoes of Italy. In 1833–1834 he published excellent petrological/chemical results and got soon a good scientific reputation. Thus he was nominated as Professor for Geology and Mineralogy of the prestigious Russian University in Dorpat (now Tartu, Esthonia) in 1842. In 1844 he was sent to Armenia by the Russian authorities. For the next three decades his fieldwork with about 190 publications was concentrated on the Great and Lesser Caucasus. This was a period of Russian expansion to the South with long-lasting regional fights. But he enjoyed the support of powerful governors. He was an indefatigable and enthusiastic explorer and a precise observer and designer. His interests covered many fields: morphology, glaciology, structural geology, volcanology with Thermal Springs, mineral resources from hydrocarbons, coal, salt to ores, stratigraphy and paleontology as a base for geological maps. But he also gave advice for practical problems, and he was active in meteorology, botany and archaeology. Alltogether he became “the Father of Caucasus Geology”. The following sketch stresses only on three aspects of his activities. He was one of the first pioneers in hydrocarbon exploration, especially around the anticlines with the mud volcanoes near Baku. In many respects, however, his fundamental ideas were erronous. He explained the structure of the Great Caucasus by the traditional theories of Leopold von Buch and Elie de Beaumont. The Caucasus anticline “was elevated by forces acting from beneath”. Following them he tried to discover regularities in the strike of mountain chains. Similarily he treated volcanism like Alexander von Humboldt and Leopold von Buch with their two groups of phenomena: voluminous, mostly basaltic “elevation craters” versus isolated, mostly trachytic and relatively small cones of “true volcanoes”. In spite of the isolation of the Caucasus region he had cultivated continuously contacts with leading geologists in Europe and was honoured by many institutions. He left Russia in 1876 for Vienna planning to write there the final monograph volumes about his investigations but he died before he could complete them.     

A reflected light investigation of ruthenium

Summary The reflectance spectra of ruthenium were measured from 400 to 700 nm in air and in oil with polarized light for the ordinary and the extraordinary ray. The character of the bireflectance changes at about 500 nm from negative (at shorter wave lengths) to positive. Absorption coefficients, indices of refraction and absorption indices were calculated, compared to literature values and related to the HCP structure of ruthenium.

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Auflichtoptische Untersuchungen von Ruthenium

Zusammenfassung Die Reflexionsspektren von Ruthenium wurden von 400 bis 700 nm mit polarisiertem Licht in Luft und in Öl für den ordentlichen und den außerordentlichen Strahl gemessen. Der Charakter der Bireflexion wechselt bei ca. 500 nm von negativ (bei kürzeren Wellenlängen) nach positiv. Die Absorptionskoeffizienten, Brechungsindizes und Absorptionskonstanten wurden berechnet, mit Literaturwerten verglichen und mit der HCP-Struktur von Ruthenium in Bezichung gesetzt.

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Numerical approximation of water–air two-phase flow by the mixed finite element method

A new model for two-phase flow of water and air in soil is presented. This leads to a system of two mass balance equations and two equations representing conservation of momentum of fluid and gas, respectively. This paper is concerned with the verification of this model for the special case of a rigid soil skeleton by computational experiments. Its numerical treatment is based on the Raviart–Thomas mixed finite element method combined with an implicit Euler time discretization. The feasibility of the method is illustrated for some test examples of one- and two-dimensional two-phase flow problems.     

Cathodoluminescence, electron microscopy, and Raman spectroscopy of experimentally shock-metamorphosed zircon

Thorough understanding of the shock metamorphic signatures of zircon could be the basis for the use of this mineral as a powerful tool for the study of old, deeply eroded, and metamorphically overprinted impact structures and formations. This study of the cathodoluminescence (CL) and Raman spectroscopic signatures of experimentally (20-60 GPa) shock-metamorphosed zircon single crystals contributes to the understanding of high-pressure microdeformation in zircon. For all samples, an inverse relationship between the brightness of the backscattered electron (BSE) signal and the corresponding cathodoluminescence intensity was observed. The unshocked sample shows crosscutting, irregular fractures. The 20 GPa sample displays some kind of mosaic texture of CL brighter and darker domains, but does not exhibit any shock metamorphic features in BSE or CL images. The 40 GPa sample shows a high density of lamellar features, which might be explained by the phase transformation between zircon- and scheelite-structure phases of zircon and resulting differences in the energy levels of the activator elements. The CL spectra of unshocked and shocked (20, 40, and 60 GPa) zircon samples are dominated by narrow emission lines and broad bands in the region of visible light and in the near-UV range. The emission lines result from rare earth element activators and the broad bands might be associated with lattice defects. Raman spectra revealed that the unshocked and 20 GPa samples represent zircon-structure material, whereas the 40 GPa sample yielded additional peaks with relatively high peak intensities, which are indicative of the presence of the scheelite-type high-pressure phase. The 60 GPa sample has a Raman signature that is similar to that of an amorphous phase, in contrast to the observations of an earlier TEM study that the crystalline scheelite-structure phase is stable at this shock pressure. The 60 GPa Raman signature cannot be explained at this stage. The results show a clear dependence of the CL and Raman properties of zircon on shock pressure, which confirm the possible usage of these methods as shock indicators.     

Evaluation of the wave transformation in an open bay with two spectral models

An evaluation of two state of the art phase averaged wave models for the transformation scale, SWAN and STWAVE, is carried out in the present work. The target area is the Obidos Bay located in the central part of the Portuguese continental nearshore. The wave input for the two models is provided by an offshore buoy. In order to compare the nearshore outputs of the wave models against in-situ measurements, a directional buoy and an ADCP, operating in intermediate water depth, are used. The wave parameters considered for comparisons are significant wave height, peak period and wave direction. Sensitivity analyses studies and evaluations in the spectral and geographical spaces concerning the results of the two models are also carried out in both intermediate and shallow water. The present study provides some information on the performances of the two wave models in different forcing conditions as well as on their sensitivity in relationship with various input parameters and some physical processes. STWAVE appears to be faster and more robust than SWAN, which on the other hand has more options and flexibility. In statistical terms the results are comparable.     

Perception of flood risk in Danube Delta,Romania

For exposed and vulnerable communities, the perception of natural risk is an essential link in the analysis of man–environment coping relationship and also an important parameter in the quantification of complex vulnerability as a central predictive variable in the risk equation. The topic of flood risk in related perception is of considerable interest, as some recently published papers have proven (Messner and Meyer 2005, 2006; Raaijmakers et al. 2008). The aim of the current study is to reveal the conscious and unconscious attitudes towards the flood risk for the inhabitants of the Danube Delta/Romania. These attitudes, defined by different degrees of psychological vulnerability, represent the background for a series of psycho-behavioural patterns that generate certain adjustment mechanisms and strategies. Application of a specially designed questionnaire and the statistical analysis of the results revealed two psychological factors as essential in establishing the psychosocial vulnerability degree of the interviewed subjects: (i) an internal control factor and (ii) an external control factor. The persons characterized by inner control have a significantly reduced general anxiety level in comparison to individuals with the control factor placed externally. As confidence diminishes, it increases the tendency of the individual to rely on the external factors for support and security. The lack of resources (indicating lower resilience) and mistrust in the support given emphasizes non-adaptive behaviours.

Principles of quantitative absorbance measurements in anisotropic crystals

The accurate measurement of absorbance (A=-log T; T=I/I ₀) in anisotropic materials like crystals is highly important for the determination of the concentration and orientation of the oscillator (absorber) under investigation. The absorbance in isotropic material is linearly dependent on the concentration of the absorber and on the thickness of the sample (A=?·c·t). Measurement of absorbance in anisotropic media is more complicated, but it can be obtained from polarized spectra (i) on three random, but orthogonal sections of a crystal, or (ii) preferably on two orthogonal sections oriented parallel to each of two axes of the indicatrix ellipsoid. To compare among different crystal classes (including cubic symmetry) it is useful to convert measured absorbance values to one common basis (the total absorbance A _tot), wherein all absorbers are corrected as if they were aligned parallel to the E-vector of the incident light. The total absorption coefficient (a _tot=A _tot/t) is calculated by $$\left( {\text{i}} \right)a_{{\text{tot}}} = \sum\limits_{i = 1}^3 {(a_{\max ,i} + a_{\min ,i} )} /2, {\text{or}} {\text{by}} {\text{(ii) }}a_{{\text{tot}}} = a_x + a_y + a_z .$$ Only in special circumstances will unpolarized measurements of absorbance provide data useful for quantitative studies of anisotropic material. The orientation of the absorber with respect to the axes of the indicatrix ellipsoid is calculated according to A _x/A _tot=cos² (x < absorber), and analogously for A _yand A _z. In this way, correct angles are obtained for all cases of symmetry. The extinction ratio of the polarizer (Pe=I _crossed/I _parallel) has considerable influence on the measured amplitude of absorption bands, especially in cases of strong anisotropic absorbance. However, if Pe is known, the true absorbance values can be calculated even with polarizers of low extinction ratio, according to A _max=?log[(T _max,obs?0.5·Pe·T _min,obs)/(1?0.5·Pe)], and similar for A _min. The theoretical approach is confirmed by measurements on calcite and topaz.     

Evolutionary processes in protoplanetary accretion disks: the propagation of axisymmetric shock waves

In this paper we investigate both the global and the local hydrodynamics of axisymmetric accretion disks around young stellar objects under the simultaneous action of viscosity, self-gravity and pressure forces. For simplicity, we take for the global model a polytropic equation of state, make the infinitely thin disk approximation and characterize the surface density and temperature profiles in the disk as power laws in the radial distance r from the protostar. We solve the problem of the general density profile of a Keplerian disk showing that self-gravity could not be an important factor for the fast formation of the rocky cores of giant gaseous planets in our solar system. Under the hypothesis that the unperturbed rotation curve of the disk is nearly Keplerian throughout the radial extent, we can estimate with our polytropic model a lower limit for the resulting masses M_d(r) of stable disks up to 100 AU. These masses are in the range of the so-called minimum mass solar nebular (_d/M_s ≈ 0.01–0.02).By adopting a simplified viscosity model, where the height-integrated turbulent dynamical viscosity ν is a function of the surface density σ like η ∝ σ^Γ, we derive in the local shearing sheet model linearized evolution equations for small density perturbations describing both a diffusion process and the propagation of acoustic density waves. We solve a special initial value problem and calculate the appropriate Green's function. The analytical solutions so obtained describe in the case Γ < 0 the successive formation of quasi-stationary ring-shaped density structures in a disk with a definite mode of maximum instability, whereas in the case Γ > Γ_c the density wave equation describes the propagation of an “overstable” ring-shaped acoustic density wavelet to the outer ranges of the accretion disk. Whereas the group velocity of the wave packet is subsonic, the phase velocities of individual wave crests in the wave packet are supersonic. The mode of maximum instability, the growth rate and the number of growing waves in the wavelet are controlled by Γ and α. Our present knowledge concerning turbulent viscosity in protoplanetary disks is not sufficient to decide whether or not the case Γ > Γ_c is realized.The suggested structuring processes in the linear theory should initiate in the non-linear regime the formation of narrow ring-shaped density shock waves moving through the protoplanetary disk. These non-linear waves could produce extremely spatially and temporally heterogeneous temperature regions in the disk. We speculate that ring-shaped density waves, excited by inner boundary conditions and which have dominated the disk's evolution at early times, are responsible both for the fast growth of dust to planetesimals and at least for the rapid accretion of the rocky cores of giant gaseous planets in the protoplanetary accretion disk (shock wave trigger hypothesis). We derive provisional scaling rules for planetary systems regarding the spacing of orbits as a function of the mass ratio of the protoplanetary disk to the protostar. However, further analytical work and linear as well as nonlinear numerical simulations of density waves excited by inner boundary conditions are needed to consolidate the results and speculations of our linear wave mechanics in the future.