Large-Scale and Mesoscale Distribution of Plankton Biomass and Metabolic Activity in the Northeastern Central Atlantic

Plankton biomass and indices of metabolism and growth [electron transport system (ETS), glutamate dehydrogenase (GDH) and aspartate transcarbamylase (ATC) activities] were studied over a 2,800 km east-west section of the tropical North Atlantic Ocean (21°N) in <200, 200–500 and >;500 µm size classes. On the large-scale, zooplankton (>;200 µm) enzymatic activities increased westward in the study section, where large cyanobacteria chains (Trichodesmium spp.) were observed. Parallel to it, an increase in medium calanoids (1–2 mm length) was observed towards the western part of the transect, whereas small calanoids (<1 mm) were dominant throughout the boundary area of the subtropical gyre. Microplankton ETS and mesoplankton ETS and ATC activities seemed to match the wave length of low frequency waves. Our results suggest that such waves are related to the observed enhancement of metabolic activity of micro- and mesoplankton. The large-scale and mesoscale variability observed give evidence of the inadequacy of assuming a steady-state picture of the euphotic zone of tropical and subtropical waters.     

On Data Interpolation at Three Croatian Repeat Stations by Using the Spherical Elementary Currents Systems Method

A general mathematical tool for expanding vector systems on a sphere into basis functions, spherical elementary current system (SECS) method, was applied for separation of the geomagnetic field variations into external and internal parts, over a limited region of central and southeastern Europe. The registered variations at three Croatian repeat stations were compared to the variations estimated by the SECS method using the variations from the different sets of observatories. The results of the SECS method were also compared to a simple assumption that the variations at repeat station are equal to those at particular observatory. The relevance of this comparison was to get an insight about the possibility of using the SECS method for estimating the geomagnetic field variations over Croatia. The guidelines for the application of the SECS method for the purpose of reducing repeat station data were also given.     

Estimation of the normal geomagnetic field and geological interpretation of the normal field anomalies over middle-northern Croatia

Based on the ground survey of total-field magnetic data at 53 sites, which recorded a time-series over the interval 2003–2005, the core field + long wavelength lithospheric field over the middle-northern Croatia region was calculated. The area of the survey was 18900 km², an average distance between the neighbouring sites being 12 km. The results were reduced to 2004.5 epoch. This “normal” total-field was estimated using the firstorder Taylor polynomial as a function of geographic coordinates, and the polynomial coefficients were calculated with three methods of adjustment: simple and weighted least squares fits and adjustment according to the most frequent value. The stability of the normal field was tested using the Monte Carlo-type test, by decreasing the input data set in each adjustment (up to 90%). All obtained field residuals (measured-“normal”) were mutually compared, as well as fit coefficients of the Taylor polynomials. The residual values indicate the presence of shorter-wavelength anomalies, specifically three major residual anomalies were found (−106 nT, 74 nT and 57 nT). The geostatistical analysis of the ground survey data and the normal field residuals (respectively), using the median absolute deviation method, was further conducted in order to evaluate the calculated anomalies. The geological situation around the anomalies derived by the median absolute deviation method, and around the normal field residual anomalies, is given. The correlation was found between higher value anomalies of the normal field residuals, and shallow volcanic rocks and oil field, respectively.     

Spectroscopic and bond-topological investigation of interstitial volatiles in beryl from Slovakia

Nine beryl samples from Western Carpathians, Slovakia, were investigated by infrared and Raman spectroscopy and differential thermal analysis. Two types of water H₂O I and H₂O II were detected. Infrared spectroscopy proved the presence of water type I and II in the presence of alkali cations with several bands: (1) symmetric stretching vibration—ν₁; (2) antisymmetric stretching mode—ν₃; (3) bending vibration—ν₂. The presence of singly and doubly coordinated type II water (IIs and IId) was confirmed by single-crystal IR spectroscopy. From Raman spectra a band at 3606 cm^?1 was assigned to ν₁ of water type I and the range of 3597–3600 cm^?1 to water type II. The presence of doubly coordinating water indicates a relatively highly hydrated environment with the presence of alkali ions including Na as the dominant cation coordinated by H₂O II. CO₂ bands were detected only by single-crystal IR spectroscopy. Thermal analysis proved total water loss in the range of 1.4–2.0 wt% and three main dehydration events. Based on the study of bond-topological arrangements two molecules of H₂O IId are each bound with two H···O1 bonds and one Na–O_W bond with an angular distortion, and by releasing one H₂O molecule more stable H₂O IIs is produced. The H₂O I molecule is bound only by two equivalent hydrogen bonds. The H₂O IIs molecule with a Na–O_W bond strength of 0.28 vu and two H···O1 bonds of 0.14 vu without any forced angular distortion is the most stable of all.     

The OH site in topaz: an IR spectroscopic investigation

The OH site in topaz is investigated by IR spectroscopy depending on the OH concentration and temperature. The two OH bands that can be distinguished are due to the local ordering of F and OH in opposite sites of the crystal structure. The first typical sharp band stems from OH groups with fluorine in the opposite (=acceptor) site. The second band occurs as a shoulder on the low-energy wing and is related to two opposite OH groups. The degree of local OH–OH ordering depends on the OH concentration and, due to statistical F/OH distribution, can be predicted by probability calculations. The substitution of OH for F has a non-linear effect on the increase of the lattice parameters. An autocorrelation analysis of the IR spectra revealed two temperature-induced phase transitions. At −135°C, the local symmetry changes from P1 to Pbn2₁, although this change involves only the H atoms. The transition from Pbn2₁ to Pbnm at 160°C is caused by changes of the local F/OH ordering in the crystal structure.     

Cathodoluminescence, electron microscopy, and Raman spectroscopy of experimentally shock-metamorphosed zircon

Thorough understanding of the shock metamorphic signatures of zircon could be the basis for the use of this mineral as a powerful tool for the study of old, deeply eroded, and metamorphically overprinted impact structures and formations. This study of the cathodoluminescence (CL) and Raman spectroscopic signatures of experimentally (20-60 GPa) shock-metamorphosed zircon single crystals contributes to the understanding of high-pressure microdeformation in zircon. For all samples, an inverse relationship between the brightness of the backscattered electron (BSE) signal and the corresponding cathodoluminescence intensity was observed. The unshocked sample shows crosscutting, irregular fractures. The 20 GPa sample displays some kind of mosaic texture of CL brighter and darker domains, but does not exhibit any shock metamorphic features in BSE or CL images. The 40 GPa sample shows a high density of lamellar features, which might be explained by the phase transformation between zircon- and scheelite-structure phases of zircon and resulting differences in the energy levels of the activator elements. The CL spectra of unshocked and shocked (20, 40, and 60 GPa) zircon samples are dominated by narrow emission lines and broad bands in the region of visible light and in the near-UV range. The emission lines result from rare earth element activators and the broad bands might be associated with lattice defects. Raman spectra revealed that the unshocked and 20 GPa samples represent zircon-structure material, whereas the 40 GPa sample yielded additional peaks with relatively high peak intensities, which are indicative of the presence of the scheelite-type high-pressure phase. The 60 GPa sample has a Raman signature that is similar to that of an amorphous phase, in contrast to the observations of an earlier TEM study that the crystalline scheelite-structure phase is stable at this shock pressure. The 60 GPa Raman signature cannot be explained at this stage. The results show a clear dependence of the CL and Raman properties of zircon on shock pressure, which confirm the possible usage of these methods as shock indicators.     

Perception of flood risk in Danube Delta,Romania

For exposed and vulnerable communities, the perception of natural risk is an essential link in the analysis of man–environment coping relationship and also an important parameter in the quantification of complex vulnerability as a central predictive variable in the risk equation. The topic of flood risk in related perception is of considerable interest, as some recently published papers have proven (Messner and Meyer 2005, 2006; Raaijmakers et al. 2008). The aim of the current study is to reveal the conscious and unconscious attitudes towards the flood risk for the inhabitants of the Danube Delta/Romania. These attitudes, defined by different degrees of psychological vulnerability, represent the background for a series of psycho-behavioural patterns that generate certain adjustment mechanisms and strategies. Application of a specially designed questionnaire and the statistical analysis of the results revealed two psychological factors as essential in establishing the psychosocial vulnerability degree of the interviewed subjects: (i) an internal control factor and (ii) an external control factor. The persons characterized by inner control have a significantly reduced general anxiety level in comparison to individuals with the control factor placed externally. As confidence diminishes, it increases the tendency of the individual to rely on the external factors for support and security. The lack of resources (indicating lower resilience) and mistrust in the support given emphasizes non-adaptive behaviours.

Evaluation of the wave transformation in an open bay with two spectral models

An evaluation of two state of the art phase averaged wave models for the transformation scale, SWAN and STWAVE, is carried out in the present work. The target area is the Obidos Bay located in the central part of the Portuguese continental nearshore. The wave input for the two models is provided by an offshore buoy. In order to compare the nearshore outputs of the wave models against in-situ measurements, a directional buoy and an ADCP, operating in intermediate water depth, are used. The wave parameters considered for comparisons are significant wave height, peak period and wave direction. Sensitivity analyses studies and evaluations in the spectral and geographical spaces concerning the results of the two models are also carried out in both intermediate and shallow water. The present study provides some information on the performances of the two wave models in different forcing conditions as well as on their sensitivity in relationship with various input parameters and some physical processes. STWAVE appears to be faster and more robust than SWAN, which on the other hand has more options and flexibility. In statistical terms the results are comparable.     

Walther Penck 1921: Pläne für eine deutsche Pazifik-Expedition

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