High-spectral-resolution solar irradiance in the 184.5 to 232.5 nm range from the SOLSPEC and UVSP spectrometers

The study of the minor constituents of the planetary atmospheres from the analysis of the scattered light properties requires the knowledge of the absolute incident solar irradiance at high resolution. The data were obtained from the UVSP experiment on board the Solar Maximum Mission satellite in the 184.5–232.5 nm spectral range. We have reconstituted the solar spectrum measured in three different regions of the solar disk with a spectral resolution of 0.01 nm and a spatial resolution of 3 arc sec. The wavelength scale was determined with a standard deviation of 0.0025 nm. The comparison of the relative intensities in three locations of the solar disk with those obtained by other authors allowed us to determine these positions accurately and to derive the integrated spectrum of the whole disk. Finally, the resulting spectrum has been expressed in absolute units using the spectral irradiance by the SOLSPEC and SUSIM spectrometers, respectively operated with the ATLAS 1 mission and from the Upper Atmosphere Research Satellite. We obtained the absolute solar irradiance with an accuracy of 10% in the 184.5–232.5 nm spectral range with a spectral resolution of 0.01 nm for the first time using data from space observations. Supplementary material to this paper is available in electronic form at http://dx.doi.org/10.1023/A:1017976515168     

First-principles study of OH defects in zircon

The infrared spectroscopic properties of selected OH defects in zircon are investigated by first-principles calculations. The explicit treatment of the coupled nature of OH motions in the stretching modes, together with the calculation of the intensity and polarization of absorption bands, makes it possible to directly compare theoretical and experimental data. The bands observed at 3,420 cm^?1 (polarization parallel to c axis) and 3,385 cm^?1 (polarization perpendicular to c axis) in natural and synthetic samples correspond to the IR-active vibrational modes of the hydrozircon defect, that is, fully protonated Si vacancy. The broad band observed at 3,515 cm^?1 in the spectrum of zircon crystals grown in F-rich environments is consistent with the occurrence of composite (OH,F) tetrahedral defects. Calculations also show that the band observed at 3,200 cm^?1 in the spectrum of synthetic undoped samples can be ascribed to fully protonated Zr vacancies. The theoretical values of integrated absorption coefficients indicate that general correlations can be reasonably used to determine the concentration of OH groups in zircon.     

Analyse conjointe des régimes pluviométriques et hydrologiques dans le bassin de la Tafna (Algérie Occidentale)

Résumé

La variabilité du climat, une gestion non optimale de la ressource en eau et l'intensification des activités anthropiques pourraient être les trois facteurs majeurs menaçant les écoulements et l'état de la ressource en eau dans les sous-bassins algériens. C'est le cas du bassin de la Tafna dans la partie occidentale de l'Algérie. Ce bassin est situé dans une région au climat semi-aride. Outre l'influence des précipitations, nous examinerons dans cet article la contribution possible d'autres facteurs (géologiques, topographiques et anthropiques) à la variabilité des écoulements dans le bassin de la Tafna. Pour cela, en plus de l'analyse du régime pluviométrique et des débits, nous avons choisi d'analyser le baseflow index ou BFI et les débits de base. Cinq sous-bassins de la Tafna, où des données journalières de pluie et de débit étaient disponibles sur la période 1976–2006 ont été étudiés. L'analyse, qui a distingué deux sous-régions déterminées par la topographie: les bassins d'altitude et ceux de plaine, montre que, selon leur contexte géologique, les sous-bassins ont des comportements différents en terme d'écoulement. Les zones en altitude présentant un écoulement de base et un BFI plus importants que les bassins de plaine. Ceci peut être relié à la nature lithologique des formations, les bassins d'altitude présentant une composante karstique importante. Les analyses de tendance/rupture sur les précipitations annuelles ne montrent aucune tendance significative sur la période 1976–2006. On note une baisse des débits moyens annuels uniquement sur deux stations en altitude (significatives aux seuils 1 et 10% respectivement). Une tendance à une diminution significative des débits de base est obtenue sur deux bassins d'altitude et un bassin de plaine (au seuil 1 ou 5%). La baisse du BFI est significative au seuil 1% pour seulement une station d'altitude. Ceci serait le signe d'une baisse du stock dans les bassins d'altitude. La modification des écoulements de base sur certains sous-bassins de la Tafna serait donc imputable à des causes, notamment de nature anthropique, ne relevant pas d'une diminution de la pluviométrie.

Editeur Z.W. Kundzewicz; Editeur associé M. Lang

Citation Bakreti, A., Braud, I., Leblois, E., et Benali, A. 2013. Analyse conjointe des régimes pluviométriques et hydrologiques dans le bassin de la Tafna (Algérie Occidentale). Hydrological Sciences Journal, 58 (1), 1–19.     

Astrodynamical Space Test of Relativity using Optical Devices I (ASTROD I)—a class-M fundamental physics mission proposal for cosmic vision 2015–2025: 2010 Update

ASTROD I is a planned interplanetary space mission with multiple goals. The primary aims are: to test General Relativity with an improvement in sensitivity of over 3 orders of magnitude, improving our understanding of gravity and aiding the development of a new quantum gravity theory; to measure key solar system parameters with increased accuracy, advancing solar physics and our knowledge of the solar system; and to measure the time rate of change of the gravitational constant with an order of magnitude improvement and the anomalous Pioneer acceleration, thereby probing dark matter and dark energy gravitationally. It is envisaged as the first in a series of ASTROD missions. ASTROD I will consist of one spacecraft carrying a telescope, four lasers, two event timers and a clock. Two-way, two-wavelength laser pulse ranging will be used between the spacecraft in a solar orbit and deep space laser stations on Earth, to achieve the ASTROD I goals.For this mission, accurate pulse timing with an ultra-stable clock, and a drag-free spacecraft with reliable inertial sensor are required. T2L2 has demonstrated the required accurate pulse timing; rubidium clock on board Galileo has mostly demonstrated the required clock stability; the accelerometer on board GOCE has paved the way for achieving the reliable inertial sensor; the demonstration of LISA Pathfinder will provide an excellent platform for the implementation of the ASTROD I drag-free spacecraft. These European activities comprise the pillars for building up the mission and make the technologies needed ready. A second mission, ASTROD or ASTROD-GW (depending on the results of ASTROD I), is envisaged as a three-spacecraft mission which, in the case of ASTROD, would test General Relativity to one part per billion, enable detection of solar g-modes, measure the solar Lense-Thirring effect to 10 parts per million, and probe gravitational waves at frequencies below the LISA bandwidth, or in the case of ASTROD-GW, would be dedicated to probe gravitational waves at frequencies below the LISA bandwidth to 100?nHz and to detect solar g-mode oscillations. In the third phase (Super-ASTROD), larger orbits could be implemented to map the outer solar system and to probe primordial gravitational-waves at frequencies below the ASTROD bandwidth. This paper on ASTROD I is based on our 2010 proposal submitted for the ESA call for class-M mission proposals, and is a sequel and an update to our previous paper (Appouchaux et al., Exp Astron 23:491?C527, 2009; designated as Paper I) which was based on our last proposal submitted for the 2007 ESA call. In this paper, we present our orbit selection with one Venus swing-by together with orbit simulation. In Paper I, our orbit choice is with two Venus swing-bys. The present choice takes shorter time (about 250?days) to reach the opposite side of the Sun. We also present a preliminary design of the optical bench, and elaborate on the solar physics goals with the radiation monitor payload. We discuss telescope size, trade-offs of drag-free sensitivities, thermal issues and present an outlook.     

Liquidus surfaces of ultracalcic primitive melts: formation conditions and sources

CaO-rich, Al₂O₃-poor ultracalcic primitive melts occur at mid-ocean-ridges, back-arc basins, ocean islands and volcanic arcs. They are subdivided into a nepheline-normative alkaline-rich, silica-poor group uniquely found in arcs and in hypersthene-normative fairly refractory melts which occur in all of the above environments. The high CaO contents (to 19.0 wt%) and CaO/Al₂O₃ ratios (to 1.8) exclude an origin from fertile lherzolites at volatile-absent conditions. Experimental investigation of the liquidus of a hypersthene-normative and a nepheline-normative ultracalcic melt results in quite distinct pressure-temperature conditions of multiple saturation: whereas the hypersthene-normative liquid saturates in olivine + clinopyroxene at 1.2 GPa and 1,410°C, this occurs at 0.2 GPa and 1,220°C for the nepheline-normative ultracalcic liquid. Our results in combination with melting experiments from the literature suggest that hypersthene-normative melts result from melting of a refractory olivine + clinopyroxene ± orthopyroxene source at elevated mantle temperatures. Contrasting, nepheline-normative ultracalcic melts form from wehrlitic cumulates in the arc crust; to account for the high alkaline and low silica contents, and the relatively low temperatures, source wehrlites must have contained amphibole.     

Behaviour of Li and its isotopes during metasomatism of French Massif Central lherzolites

Li behaviour and distribution in the mantle were investigated by ion microprobe in situ measurements on co-existing olivine (ol), orthopyroxene (opx), clinopyroxene (cpx) and amphibole (amp) in xenoliths from the French Massif Central. The fertile spinel lherzolites of this study record increasing degrees of mantle metasomatism, from unmetasomatised anhydrous samples through cryptically metasomatised samples to highly metasomatised amphibole-rich samples. In anhydrous lherzolites, Li is preferentially incorporated into olivine (1.1-1.4 ppm, average values) compared to pyroxenes (0.2-0.9 ppm). The hydrous samples clearly show enrichment of Li in ol (1.5-5.0 ppm), opx (1.1-2.4 ppm) and cpx (2.4-5.4 ppm), while amphibole incorporates less Li than the co-existing phases (0.8-1.3 ppm). Average δ⁷Li values range from +7.6 to +14.5‰ in ol, from 5.1 to +13.7‰ in opx and from 8.8 to +10.3‰ in cpx from the anhydrous lherzolites. A layered peridotite sample (Sdi) shows higher Li content in all phases, with lighter isotopic composition in opx and cpx (−0.6 and −2‰ average δ⁷Li values, respectively). In the hydrous lherzolites average δ⁷Li values both overlap and extend beyond these ranges in ol (up to 17.5 ‰) and in opx (up to 22.9‰), and vary widely in cpx (−2.7 to +9.7‰). Low δ⁷Li values are observed in some opx (−10.4‰) and cpx (−13‰) from sample Sdi, and in cpx from three hydrous samples (from −9.7 to −5.3‰). The different anhydrous phases from the hydrous samples show large intra-grain variations in Li isotopic ratios (e.g., up to 18‰) compared to the same phases from the anhydrous samples (mostly less than 6‰), excepting sample Sdi which has up to 20.4‰ variation in cpx. Similar to the anhydrous silicates, amphiboles show a wide variation of δ⁷Li values on the intra-grain scale (2-27‰). These variations are interpreted to result from fractionation processes during metasomatism by a silicate melt undergoing compositional changes as it percolates through and reacts with the peridotite phases. Thus Li abundances and isotopic in situ measurements are useful for tracing metasomatic processes but the heterogeneities observed in the samples preclude any identification of a specific mantle source by its Li signature.