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301.
This paper introduces the software solution Bingo-Antidote for thermodynamic calculations at equilibrium based on iterative thermodynamic models. It describes a hybrid strategy combining the strength of Gibbs energy minimization (GEM) and inverse thermobarometry models based on the comparison between the modelled and observed mineral assemblage, modes and compositions. The overall technique relies on quantitative compositional maps acquired by electron probe micro-analyser for obtaining a mutually consistent set of observed data such as bulk rock and mineral compositions. Thus it offers the opportunity to investigate metamorphic rocks on a microscale. The scoring part Bingo integrates three statistical model quality factors for the assemblage, for the mineral modes, for the mineral compositions combined in a global evaluation criterion that quantifies how the model reproduces the observations for the investigated volume. The input parameters of GEM affecting the model quality such as pressure, temperature and eventually some components of the bulk composition (e.g. the molar amount of hydrogen, carbon or oxygen) or activity variables of fluids and gases (e.g. , , f(O2)) can be optimized by inversion in Antidote using several mapping stages followed by a direct search optimization. Examples of iterative models based on compositional maps processed with Bingo-Antidote demonstrate the utility of the program. In contrast to the qualitative interpretation of phase diagrams, the inversion maximizes the benefits of GEM and permits the derivation of statistically ‘optimal’ pressure–temperature conditions for well-equilibrated samples. In addition, Bingo-Antidote opens new avenues for petrological investigations such as the generation of chemical potential landscape maps. 相似文献
302.
Isaac Wirgin Cheryl Grunwald Erik Carlson Joseph Stabile Douglas L. Peterson John Waldman 《Estuaries and Coasts》2005,28(3):406-421
Riverine populations of shortnose sturgeon (Acipenser brevirostrum) once occurred in rivers and estuaries along the east coast of North America from the St. John River, New Brunswick, to the St. Johns River, Florida. Within this range, 19 population segments were identified by the U.S. Federal Shortnose Sturgeon Recovery Team; empirical data supporting this structure is limited. We obtained samples from 11 (12 including a small sample from the Cape Fear River, North Carolina) of these population segments and used PCR and direct sequence analysis of 440 base pairs of the mitochondrial DNA (mtDNA) control region to define the coast-wide genetic population structure of shortnose sturgeon. Collections from most population segments exhibited significant differences in haplotype frequencies with their nearest neighbors, including from the Ogeechee and Savannah Rivers, Georgia (despite the known movement of hatchery-reared offspring from the Savannah into the Ogeechee River). Collections from the Chesapeake Bay and Delaware River exhibited similar haplotype frequencies, suggesting that specimens collected in the Chesapeake Bay had dispersed from the Delaware River. Collections from the Kennebec River and Androscoggin River within a hypothesized single population segment did not exhibit significant differentiation of mtDNA haplotype frequencies. Haplotype frequencies were almost identical between collections from above and below the Holyoke Dam on the Connecticut River, indicating that these aggregations should be managed as a single unit. Our results support the population segment status afforded to shortnose sturgeon in at least the following 9 systems; St. John River, Kennebec-Androscoggin Rivers, upper-lower Connecticut River, Hudson River, Delaware River-Chesapeake Bay, Pee Dee River, Cooper River, Savannah River, and Ogeechee-Altamaha Rivers. 相似文献
303.
304.
Microinclusions analyzed in a coated diamond from the Diavik mine in Canada comprise peridotitic minerals and fluids. The fluids span a wide compositional range between a carbonatitic melt and brine. The diamond is concentrically zoned. The brine microinclusions reside in an inner growth zone and their endmember composition is K19Na25Ca5Mg8Fe3Ba2Si4Cl32 (mol%). The carbonatitic melt is found in an outer layer and its endmember composition is K11Na21Ca11Mg26Fe7Ba2Si10Al3P2Cl5. The transition in inclusion chemistry is accompanied by a change in the carbon isotopic composition of the diamond from −8.5‰ in the inner zone to −12.1‰ in the outer zone. We suggest that this transition reflects mixing between already evolved brine and a freshly introduced carbonatitic melt of different isotopic composition.
The compositional range found in diamond ON-DVK-294 is the widest ever recorded in a single diamond. It closes the gap between brine found in cloudy octahedral diamonds from South Africa and carbonatitic melt analyzed in cubic diamonds from Zaire and Botswana. Thus, all microinclusions analyzed to date fall along two arrays connecting the carbonatitic melt composition to either a hydrous-silicic endmember or to a brine endmember. This connection suggests that many diamonds are formed from fluids derived form a mantle source not significantly influenced by local heterogeneities. 相似文献
305.
R. Timothy Patterson W. Brian McKillop Sid Kroker Erik Nielsen Eduard G. Reinhardt 《Journal of Paleolimnology》1997,18(2):131-143
A Holocene ecological succession was documented using palynological, foraminiferal, and molluscan faunas sampled from an excavated trench on the margin of Bell River Bay, Lake Winnipegosis, Manitoba. The palynological data record the known gradually isostatically-induced shift from aquatic to terrestrial conditions at the site, and clearly delineates the Holocene Hypsithermal maximal warm interval (commencing here about 5500 years BP). Concurrent with this warming the site became occupied by the extinct salt tolerant gastropod Marstonia gelida and the marine foraminifer Cribroelphidium gunteri by at least 5430 years BP. Water fowl-assisted colonization of non-marine habitats by foraminifera has previously been suggested as a dispersal mechanism for other non-marine foraminiferal occurrences. However, as this relatively warm-water foraminifer (presently found as far north as Cape Cod, MA on the Atlantic USA coast, and Vancouver, BC on the Canadian Pacific coast but also found in Canadian Maritime provinces during the Hypsithermal) did not inhabit the area either prior to or following the Hypsithermal warm interval, this occurrence indicates the efficiency with which foraminifera can utilize non-selective avian transport to colonize new non-marine and marine habitats. It may be that only a few years were required for colonization of the site to occur (2000–3000 km distant from native populations); this suggests that avian transport is a much more important foraminiferal dispersal mechanism than previously realized. The appearance of foraminifera at this site may also constrain models designed to determine the time required for hydraulically injected glacial freshwater to be flushed from normally brine producing aquifers in the region. 相似文献
306.
Erik W. Grafarend 《Journal of Geodesy》1985,59(2):124-138
Summary From a two-dimensional network adjustment it is well understood that the one orientation unknown of a theodolite frame is
estimable, once the orientation datum parameter, e.g., one azimuth, is fixed. In three-dimensional networks the problem of
estimability of three orientation unknowns inherent in a theodolite frame is more complex. Here we prove that not only the
classical horizontal orientation unknown is estimable (up to the datum degrees of freedom), but also astronomical longitude
and astronomical latitude which can be considered as two additional orientation unknowns of the theodolite frame moving with
respect to an earth-fixed equatorial frame of reference. Thus the theodolite instrument can be considered—at least theoretically—a
gradiometer measuring the variation of the directional parameters of the gravity vector from one point to another. Or up to
the datum degrees of freedom astronomical longitude and astronomical latitude can be determined from only theodolite observations
between exclusively terrestrial points. M?nicke (1982), has shown that despite the refraction problem the method works sufficiently
well in practice. 相似文献
307.
308.
Erik R. Christensen 《Aquatic Sciences - Research Across Boundaries》1984,46(1):100-108
Information about the toxicity of heavy metals and organics to aquatic organisms can be obtained from bioassays. These are
classified according to the type of response obtained: quantal or continuous, and according to whether individual organisms
originate from a single clone or have a tolerance distribution. Basic features of the probit, logit, and Weibull dose-response
models for one toxic substance are considered. It is shown that a version of the logit model is complementary to the Monod
equation for the growth rate of microorganisms under substrate limitation. Multiple toxicity models can be of the non-interactive
or competitive type. The standard water quality criterion for concentration addition is based on the assumption that the toxicants
act on similar biological systems, and that the action tolerances for individuals are fully correlated. Pertinent examples
of the application of the models for one or several toxic substances are discussed. 相似文献
309.
Hans-Rudolf Wenk Erik Rybacki Georg Dresen Ivan Lonardelli Nathan Barton Hermann Franz Gabriela Gonzalez 《Physics and Chemistry of Minerals》2006,33(10):667-676
Mechanical Dauphiné twinning in quartz has been of long-standing interest, both in single crystals and polycrystalline aggregates. This study investigates texture development in fine-grained quartz rock novaculite with no initial texture using compression experiments conducted in the Paterson gas apparatus to explore the influence of stress and temperature. Texture patterns are measured with time-of-flight neutron diffraction and hard synchrotron X-rays, analyzing diffraction data with the Rietveld method. Similar texture patterns are observed as described previously but the new results establish a profound influence of temperature and document that twinning initiates at stresses less than 50 MPa. Possibilities of using Dauphiné twinning as a paleopiezometer in quartz-bearing rocks are discussed. 相似文献
310.
James A. Van Orman Alberto E. Saal Erik H. Hauri 《Geochimica et cosmochimica acta》2006,70(18):4797-4812
U-series radioactive disequilibria in basaltic lavas have been used to infer many important aspects of melt generation and extraction processes in Earth’s mantle and crust, including the porosity of the melting zone, the solid mantle upwelling rate, and the melt transport rate. Most of these inferences have been based on simplified theoretical treatments of the fractionation process, which assume equilibrium partitioning of U-series nuclides among minerals and melt. We have developed a numerical model in which solid-state diffusion controls the exchange of U-series nuclides among multiple minerals and melt. First the initial steady-state distribution of nuclides among the phases, which represents a balance between diffusive fluxes and radioactive production and decay, is calculated. Next, partial melting begins, or a foreign melt is introduced into the system, and nuclides are again redistributed among the phases via diffusion. U-series nuclides can be separated during this stage due to differences in their diffusivity; radium in particular, and possibly protactinium as well, can be strongly fractionated from slower-diffusing thorium and uranium. We show that two distinct processes are not required for the generation of 226Ra and 230Th excesses in mid-ocean ridge basalts, as has been argued previously; instead the observed negative correlations of the (226Ra/230Th) activity ratio with (230Th/238U) and with the extent of trace element enrichment may result from diffusive fractionation of Ra from Th during partial melting of the mantle. Alternatively, the (226Ra/230Th) disequilibrium in mid-ocean ridge basalts may result from diffusive fractionation during shallow-level interaction of mantle melts with gabbroic cumulates, and we show that the results of the interaction have a weak dependence on the age of the cumulate if both plagioclase and clinopyroxene are present. 相似文献