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261.
Water Resources - Numerical modelling of ice growth and transport of matter in lakes, estuaries, or coastal seas can provide crucial input for improving the environment. In this paper, the goal is...  相似文献   
262.
With transmission electron microscopy (TEM) we observed nanometer-sized pores in four ultracataclastic and fractured core samples recovered from different depths of the main bore hole of the San Andreas Fault Observatory at Depth (SAFOD). Cutting of foils with a focused ion beam technique (FIB) allowed identifying porosity down to the nm scale. Between 40 and 50% of all pores could be identified as in-situ pores without any damage related to sample preparation. The total porosity estimated from TEM micrographs (1–5%) is comparable to the connected fault rock porosity (2.8–6.7%) estimated by pressure-induced injection of mercury. Permeability estimates for cataclastic fault rocks are 10? 21–10? 19 m2 and 10? 17 m2 for the fractured fault rock. Porosity and permeability are independent of sample depth. TEM images reveal that the porosity is intimately linked to fault rock composition and associated with deformation. The TEM-estimated porosity of the samples increases with increasing clay content. The highest porosity was estimated in the vicinity of an active fault trace. The largest pores with an equivalent radius > 200 nm occur around large quartz and feldspar grains or grain-fragments while the smallest pores (equivalent radius < 50 nm) are typically observed in the extremely fine-grained matrix (grain size < 1 μm). Based on pore morphology we distinguish different pore types varying with fault rock fabric and alteration. The pores were probably filled with formation water and/or hydrothermal fluids at elevated pore fluid pressure, preventing pore collapse. The pore geometry derived from TEM observations and BET (Brunauer, Emmett and Teller) gas adsorption/desorption hysteresis curves indicates pore blocking effects in the fine-grained matrix. Observations of isolated pores in TEM micrographs and high pore body to pore throat ratios inferred from mercury injection suggest elevated pore fluid pressure in the low permeability cataclasites, reducing shear strength of the fault.  相似文献   
263.
A study on Lake Væng in Denmark demonstrates a high potential for loading of phosphorous via groundwater to seepage lakes. Groundwater discharges are displayed as an important source of phosphorous to a lake due to: (1) high concentrations in the aquifer just below the lake, and (2) the main flow paths through the aquifer–lakebed interface either being overland flow through a seepage face, or focused in zones with very high discharge rates. In-lake springs have measured discharge of up to 7.45 m3 per m2 of lakebed per day. These findings were based on seepage meter measurements at 18 locations, stable isotope (δ18O) analyses, temperature profiles and mapping of ice cover distribution. Groundwater–lake interaction was modelled with a 2D conceptual flow model (MODFLOW) with hydrogeology interpreted from catchment multi electrode profiling, on-lake ground-penetrating radar, well logging and borehole data. Discharge was found to be much focused and opposite to expected increase away from the shoreline. The average total phosphorus concentration in discharging groundwater sampled just beneath the lakebed was 0.162 mg TP/l and thereby well over freshwater ecological thresholds (0.043–0.612, median = 0.117 mg TP/l). The study illustrates a direct link between groundwater and lake chemistry.  相似文献   
264.
The ‘poly morphological (PM) concept’ is used to assess geological heterogeneity in glacial sediments and to evaluate groundwater recharge to aquifers, especially those underlying clay till. The novelty of the PM concept is that it enhances the knowledge of, especially, heterogeneity of till units in geological models by using superimposed geomorphological units with typical sediment types related to the individual landforms. The PM concept is demonstrated through the construction of a poly morphological map for Zealand in Denmark and an aggregated map comparing clay-till-thickness distribution within individual PM types. The hydrogeological applicability of the PM concept was tested with a physical-based distributed 3D hydrological model. The aggregated PM map was compared with fracture and redox conditions at 21 field sites to evaluate the PM-type correlation to: (1) till thickness, (2) thickness of the reduced-till zone, and (3) depth to the zone with fracture spacing >1 m The results show that the till thickness is a critical parameter for the formation of fracture networks in clay till, and that fracture density decreases in till thicker than 8–10 m. However, the amount of data is still inadequate for statistically proving the PM concept.  相似文献   
265.
Changes in total abundance and in species composition of phytoplankton in the last 150 years in the southern Black Sea were investigated through a paleoecological study of two sediment cores. The results show changes in the species composition and a marked increase in total abundance of siliceous protists after around 1960. In core 22 (42°13.534′ N/36°29.555′ E), the dominating species before 1960 were Cyclotella choctawhatcheeana and Thalassiosira oestrupii. In core 25 (42°6.212′ N/36°37.460′ E), the dominating species before 1960 were T. oestrupii, Cyclotella meneghiniana, C. choctawhatcheeana, and Pseudosolenia cf. calcar-avis. Core 22 was located in closer proximity to the rim current than core 25, and the differences in total abundance between the cores could be related to differences in local nutrient loading prior to 1960. After around 1960, both cores changed to a community dominated by C. choctawhatcheeana. The changes in total abundance and species composition after around 1960 could be related to the increased nutrient loading from the Danube River into the rim current after the late 1960s. The results also showed changes in both total abundance and in species composition of dinoflagellate cysts. The dominating dinoflagellate cysts recorded were Lingulodinium polyedrum, Polykrikos schwartzii, and Spiniferites spp.  相似文献   
266.
Twelve samples belonging to the chassignite and nakhlite subgroups of Martian meteorites were investigated using a variety of micro‐beam analytical techniques to gain insight into the petrogenesis of these two meteorite classes. There are a striking number of geochemical similarities between the chassignites and nakhlites, including mineralogy and petrology, crystallization age, cosmic‐ray exposure age, and radiogenic isotopic compositions. However, there are also geochemical differences, namely in trace element systematics of pyroxenes, that have led some authors to conclude that the nakhlites are comagmatic with each other, but not comagmatic with the chassignites. On the basis of data presented here, we propose a model in which these differences can be reconciled by the addition of an exogenous Cl‐rich fluid to the chassignite‐nakhlite magma body shortly after the formation of the cumulate horizon that was sampled by the Chassigny meteorite. This model is supported by the textural and chemical associations of the volatile‐bearing minerals apatite, amphibole, and biotite, which record a history starting with the addition of a Cl‐ and LREE‐enriched fluid to the magma body. As the magma continued to crystallize, it eventually reached chloride saturation and degassed a Cl‐rich fluid phase. Depending on the provenance of the Cl‐rich fluid, this model could explain how the chassignites and nakhlites originated from an LREE‐depleted source, yet all exhibit LREE‐enriched bulk‐rock patterns. Additionally, the model explains the range in oxygen fugacity that is recorded by the chassignites and nakhlites because eventual exsolution and loss of Cl‐rich fluid phases near the end of crystallization of the nakhlite sequence leads to auto‐oxidation of the magma body due to the preferential partitioning of Fe2+ into the fluid phase.  相似文献   
267.
Cladocerans are valuable indicators of environmental change in lakes. Their fossils provide information on past changes in lake environments. However, few studies have quantitatively examined the relationships between contemporary and sub-fossil cladoceran assemblages and no investigations are available from Mediterranean lakes where salinity, eutrophication and top-down control of large-bodied cladocerans are known to be important. Here we compared contemporary Cladocera assemblages, sampled in summer, from both littoral and pelagic zones, with their sub-fossil remains from surface sediment samples from 40 Turkish, mainly shallow, lakes. A total of 20 and 27 taxa were recorded in the contemporary and surface sediment samples, respectively. Procrustes rotation was applied to both the principal components analysis (PCA) and redundancy analysis (RDA) ordinations in order to explore the relationship between the cladoceran community and the environmental variables. Procrustes rotation analysis based on PCA showed a significant accord between both littoral and combined pelagic–littoral contemporary and sedimentary assemblages. RDA ordinations indicated that a similar proportion of variance was explained by environmental variation for the contemporary and fossil Cladocera data. Total phosphorus and salinity were significant explanatory variables for the contemporary assemblage, whereas salinity emerged as the only significant variable for the sedimentary assemblage. The residuals from the Procrustes rotation identified a number of lakes with a high degree of dissimilarity between modern and sub-fossil assemblages. Analysis showed that high salinity, deep water and high macrophyte abundance were linked to a lower accord between contemporary and sedimentary assemblages. This low accord was, generally the result of poor representation of some salinity tolerant, pelagic and macrophyte-associated taxa in the contemporary samples. This study provides further confirmation that there is a robust relationship between samples of modern cladoceran assemblages and their sedimentary remains. Thus, sub-fossil cladoceran assemblages from sediment cores can be used with confidence to track long-term changes in this environmentally sensitive group and in Mediterranean lakes, subjected to large inter-annual variation in water level, salinity and nutrients.  相似文献   
268.
Notwithstanding optimistic rhetoric about integrating geospatial data from different sources and supporting good governance, much of the literature on geoinformation management is limited to a technical orientation with a positivist paradigm. Complex geoinformation management, like public policy, must go beyond these boundaries. The article calls attention to the underexposed role of dilemmas in geoinformation management and how to cope with them. It uses lessons from the development of ‘integrated surveys’ at the former International Training Centre for Aerial Survey (ITC) in The Netherlands as an early and practical case of managing geoinformation for public policy some 40 years ago. These lessons are apparently also relevant to modern digital geoinformation management, as in SDI. Focus on public policy requires not only integration of geospatial data from different sources but also integration of geoinformation into complex decision‐making processes. This complexity probably creates dilemmas because of mutually incompatible perspectives between different actors on what is to be managed. Geoinformation management for public policy therefore requires the ability to find, over and over again, a common ground between and beyond incompatible perspectives. The article proposes a ‘transdisciplinary’ framing of geoinformation management to support the required thinking outside the box.  相似文献   
269.
Complex flow processes at river bifurcations and the influence of the layout of a bifurcation make it difficult to predict sediment distribution over the downstream branches in case bedload transport dominates. In one‐dimensional models we need a nodal point relationship that prescribes the distribution of sediment over the downstream branches. We have identified which factors need to be included in such a relationship for the division of bedload transport at bifurcations. Next, irrotational flow theory for idealized geometries has been used to derive a simple physics‐based nodal point relationship that accounts for the effects of helical flow in the situation that a channel takes off under an angle from a straight main channel. This first step towards a complete nodal point relationship is applicable to bedload transport situations if the flow is clearly curved and if there is no pronounced bed topography. The relationship has been tested against data from a unique set of laboratory measurements, numerical data and data from a scale model of the Rhine bifurcation at Pannerden in the Netherlands. We find that the derived model yields a reasonable prediction of the sediment division over the downstream branches, and yields better predictions than the Wang et al. model for the situation considered. Considering the relative complexity and limited accuracy of the nodal point relationship for the effect of helical flow alone, however, we conclude thatderiving a practical physics‐based 1‐D relationship including all relevant processes is not feasible. We therefore recommend 2‐D or 3‐D modelling for all cases in general where morphological evolution depends on the division of bedload transport at bifurcations. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
270.
Major components of lacustrine sediments, such as carbonates, organic matter, and biogenic silica, provide significant paleoenvironmental information about lake systems. Fourier transform infrared spectroscopy (FTIR) and scanning X-ray fluorescence (XRF) techniques are fast, cost effective, efficient methods to determine the relative abundances of these components. We investigate the potential of these techniques using sediments from two large lakes, Lake Malawi in Africa and Lake Qinghai in China. Our results show statistically significant correlations of conventionally measured concentrations of carbonate (%CaCO3), total organic carbon (%TOC), and biogenic silica (%BSi), with absorbance in the corresponding FTIR spectral regions and with XRF elemental ratios including calcium:titanium (Ca/Ti), incoherent:coherent X-ray scatter intensities (Inc/Coh), and silicon:titanium (Si/Ti), respectively. The correlation coefficients (R) range from 0.66 to 0.96 for comparisons of FTIR results and conventional measurements, and from 0.70 to 0.90 for XRF results and conventional measurements. Both FTIR and XRF techniques exhibit great potential for rapid assessment of inorganic and organic contents of lacustrine sediments. However, the relationship between XRF-ratios or FTIR-absorbances and abundances of corresponding sedimentary components can vary with sediment source and lithology.  相似文献   
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