Trace element zoning in pyroxenes from ODP Hole 735B gabbros: diffusive exchange or synkinematic crystal fractionation?

Major and trace element profiles of clinopyroxene grains in oceanic gabbros from ODP Hole 735B have been investigated by a combined in situ analytical study with ion probe, and electron microprobe. In contrast to the homogeneous major element compositions, trace elements (REE, Y, Cr, Sr, and Zr) show continuous core to rim zoning profiles. The observed trace element systematics in clinopyroxene cannot be explained by a simple diffusive exchange between melts and gabbros along grain boundaries. A simultaneous modification of the melt composition is required to generate the zoning, although Rayleigh fractional crystallization modelling could mimic the general shape of the profiles. Simultaneous metasomatism between the cumulate crystal and the porous melt during crystal accumulation is the most likely process to explain the zoning. Deformation during solidification of the crystal mush could have caused squeezing out of the incompatible element enriched residual melts (interstitial liquid). Migration of the melt along grain boundaries might carry these melt out of the system. This process named as synkinematic differentiation or differentiation by deformation (Natland and Dick in J Volcanol Geotherm Res 110(3–4):191–233, 2001) may act as an important magma evolution mechanism in the oceanic crust, at least at slow-spreading ridges.     

Distribution and Abundance of Arsenic in the Soils and Sediments of O‘ahu,Hawai‘i

Lack of high-spatial-resolution soil and sediment arsenic data for Hawai‘i has generated substantial disagreement between researchers and regulators regarding the magnitude of natural levels of arsenic in Hawai‘i and rendered difficult the defining of areas of anthropogenically elevated arsenic. Our earlier research into the occurrence of arsenic in terrestrial and marine environments revealed widely disparate concentrations of arsenic with no apparent spatial pattern. To better understand the distribution and abundance of arsenic in soils and sediments of O‘ahu, we collected an additional 64 samples at locations chosen to represent different environments with varying degrees of human impact. We found surface arsenic values that ranged from 0.28 to 740 ppm with a median concentration of 8.1 ppm, which is above the global median of 5 ppm and US soil median of 5.2 ppm. Higher concentrations of arsenic (up to 913 ppm) were encountered at depth in soil cores. The median arsenic in streambed sediments from one of our earlier studies of 6.1 ppm was comparable to the conterminous US median of 6.3 ppm; however, we encountered arsenic concentrations as high as 43.9 ppm (median = 8.60 ppm, n = 75) in marine sediments in recent work off the leeward coast of O‘ahu. Overall, arsenic in the soils and sediments of O‘ahu is elevated relative to world and national values, but there still is no readily discernible pattern in the distribution of arsenic to explain these elevated values.     

Production of carbonate and silica nano-particles in stirred bead milling

This paper presents the experimental results of the mechanical production of silica and carbonate colloidal particles below 100 nm using two types of stirred bead mills (i.e., DCP Superflow 12 and PML H/V). It is shown that the stirred bead mill with very small beads can be used as an efficient equipment for the production of the colloidal particles in nanoscale from the feed materials of several microns in sizes at high energy consumptions. The DCP Superflow mill with high power densities is superior for the effective size reduction and production rate, compared to the conventional PML H/V mill with lower power densities. The smaller particles could be produced by the DCP Superflow mill at the same level of high energy inputs as from the PML H/V mill. The “grinding limit” for the processes in the mills has been discussed.     

Influence of sea surface wind wave turbulence upon wind-induced circulation, tide–surge interaction and bed stress

A three-dimensional finite volume unstructured mesh model of the west coast of Britain, with high resolution in the coastal regions, is used to investigate the role of wind wave turbulence and wind and tide forced currents in producing maximum bed stress in the eastern Irish Sea. The spatial distribution of the maximum bed stress, which is important in sediment transport problems, is determined, together with how it is modified by the direction of wind forced currents, tide–surge interaction and a surface source of wind wave turbulence associated with wave breaking. Initial calculations show that to first order the distribution of maximum bed stress is determined by the tide. However, since maximum sediment transport occurs at times of episodic events, such as storm surges, their effects upon maximum bed stresses are examined for the case of strong northerly, southerly and westerly wind forcing. Calculations show that due to tide–surge interaction both the tidal distribution and the surge are modified by non-linear effects. Consequently, the magnitude and spatial distribution of maximum bed stress during major wind events depends upon wind direction. In addition calculations show that a surface source of turbulence due to wind wave breaking in shallow water can influence the maximum bed stress. In turn, this influences the wind forced flow and hence the movement of suspended sediment. Calculations of the spatial variability of maximum bed stress indicate the level of measurements required for model validation.     

Coseismic Fault Slip of the September 16, 2015 <Emphasis Type="Italic">Mw</Emphasis> 8.3 Illapel,Chile Earthquake Estimated from InSAR Data

The complete surface deformation of 2015 Mw 8.3 Illapel, Chile earthquake is obtained using SAR interferograms obtained for descending and ascending Sentinel-1 orbits. We find that the Illapel event is predominantly thrust, as expected for an earthquake on the interface between the Nazca and South America plates, with a slight right-lateral strike slip component. The maximum thrust-slip and right-lateral strike slip reach 8.3 and 1.5 m, respectively, both located at a depth of 8 km, northwest to the epicenter. The total estimated seismic moment is 3.28 × 10²¹ N.m, corresponding to a moment magnitude Mw 8.27. In our model, the rupture breaks all the way up to the sea-floor at the trench, which is consistent with the destructive tsunami following the earthquake. We also find the slip distribution correlates closely with previous estimates of interseismic locking distribution. We argue that positive coulomb stress changes caused by the Illapel earthquake may favor earthquakes on the extensional faults in this area. Finally, based on our inferred coseismic slip model and coulomb stress calculation, we envision that the subduction interface that last slipped in the 1922 Mw 8.4 Vallenar earthquake might be near the upper end of its seismic quiescence, and the earthquake potential in this region is urgent.     

A new methodology for energy-based seismic design of steel moment frames

A procedure is proposed whereby input and hysteretic energy spectra developed for single-degree-of-freedom (SDOF) systems are applied to multi-degree-of-freedom (MDOF) steel moment resisting frames. The proposed procedure is verified using four frames, viz., frame with three-, five-, seven- and nine-stories, each of which is subjected to the fault-normal and fault-parallel components of three actual earthquakes. A very good estimate for the three- and five-story frames, and a reasonably acceptable estimate for the seven-, and nine-story frames, have been obtained. A method for distributing the hysteretic energy over the frame height is also proposed. This distribution scheme allows for the determination of the energy demand component of a proposed energy-based seismic design (EBSD) procedure for each story. To address the capacity component of EBSD, a story-wise optimization design procedure is developed by utilizing the energy dissipating capacity from plastic hinge formation/rotation for these moment frames. The proposed EBSD procedure is demonstrated in the design of a three-story one-bay steel moment frame.     

Oblique oceanic opening and passive margin irregularity,as inherited in the Zagros fold‐and‐thrust belt

The Zagros fold‐and‐thrust belt of SW Iran represents deformation of the former Arabian passive margin since Permian–Triassic opening of the Neo‐Tethys ocean. The Zagros belt is characterized by a present‐day structural salient‐recess setting inherited from past marginal embayment‐promontory geometry, which was involved in discontinuous ophiolite obduction and diachronous continental collision. We examine outcrop‐scale Mesozoic extensional brittle tectonics, preserved as syn‐depositional normal faults within the folded strata, in terms of stress tensor inversion. The result is then integrated with belt‐scale isopach, seismic and topographical data to delineate the geometry of a major irregularity along the passive margin originating from oblique oceanic opening. The implication of this configuration within the tectonic framework of oceanic closure is discussed.     

Modeling in paleoceanography

The two last decades of research in paleoceanography are characterized by extensive data collection and by the development of numerous hypotheses based on these data. Both the nature of the thermohaline circulation and the nature of the surface circulation during past times are currently being debated. Physical models of the ocean circulation are beginning to play an important role in these debates. The models range from highly simplified mathematical representations intended to illustrate physical principles to three-dimensional time-dependent global models intended to simulate temperature, salinity and flow fields. At the very least such models can be applied to explore the limitations or appropriateness of various assumptions in paleoceanography. At the very best, paleoceanographic data may be used as a verification of simulations of past oceans.     

Natural disasters as the end of the insurance industry? Scalar competitive strategies, Alternative Risk Transfers, and the economic crisis

The aftermath of Hurricane Katrina has piqued interest in the insurance industry, and this scrutiny has led to assumptions that the industry has become unstable and unprofitable with the increased incidence of disasters in highly-insured regions of the world. This paper challenges that assumption by arguing that the insurance industry has responded by spreading risk through scaled and networked recovery schemes. We found that because of competitive strategies of risk-spreading and displacement arrangements, the industry has actually profited as a whole. Regional insurance companies have always relied on the higher financial scales of the reinsurance industry in Munich, Zurich, and London. But with claims reaching into the billions of dollars, the reinsurance industry itself has raised premiums, spread risk farther afield, and jumped scale by spreading risk to futures markets called Alternative Risk Transfers (ARTs). However, the recession beginning in 2008 has called into question the viability of using futures markets as insurance. It is shown through a media analysis of four major business publications (The Economist, The New York Times, The Financial Times and The Wall Street Journal) how the industry responded to the costs of the 2004, 2005, and 2006 hurricane seasons. Because geography is rather new to this literature, this paper also offers a broad review of the insurance industry.     

Dynamics of epiphytic photoautotrophs and heterotrophs inZostera marina (eelgrass) microcosms: Responses to nutrient enrichment and grazing

The combined effects of nutrient enrichment and grazing by isopods and amphipods on abundances of seagrass epiphytes were tested inZostera marina L. (eelgrass) microcosms. Using epifluorescence microscopy, densities of epiphytic diatoms, cyanobacteria, heterotrophic flagellates, and heterotrophic bacteria were enumerated after 1 mo and 2 mo of treatment. In general, numbers of diatoms decreased, in the presence of grazers and showed little response to nutrient enrichment, whereas numbers of cyanobacteria increased with nutrient enrichment and showed little response to grazing. Thus, macrofaunal grazing maintained a photoautotrophic community domainated by cyanobacteria, particularly under nutrient enriched conditions. Following 2 mo of treatment, dense macroalgal growth under nutrient-enriched conditins with grazers absent appeared to limit populations of both epiphytic autotrophs. Patterns of abundance of heterotrophic bacteria suggested that the original bacteria population was nutrient limited. Bacteria populations may have been limited by organic carbon supplies at the end of the experiment. Abundances of heterotrophic flagellates and bacteria were strongly correlated on both sampling dates. Results suggest that heterotrophic flagellates might serve as a link between heterotrophic bacterial production and higher trophic levels in seagrass epiphyte food webs.