Chlorinated hydrocarbons and hatching success in Baltic herring spring spawners

Eggs from 69 females of spring spawning herring from the German Baltic coast (Travemünde, April 1979) were incubated in clean sea water (20‰ S, temperature 8°C) under standard conditions. Sixty-one trials could be used for the evaluation of hatching success. Viable hatch was taken as a measure to evaluate the effects of chlorinated hydrocarbons accumulated in gonads, liver and muscle of parental fish.PCB levels in running ripe females ranged on a wet weight basis between 19 and 241 ng g^?1 (gonad), 20 and 377 ng g^?1 (liver) and 11 and 1820 ng g^?1 (muscle). Concentrations of other chlorinated hydrocarbons (DDD, DDE, γ-HCH, etc.) were in the same range as reported by other authors for Baltic herring (Huschenbeth, 1973, 1977). Viable hatch was significantly affected at ovary DDE concentrations higher than 18 ng g^?1 (wet wt) and PCB concentrations of more than 120 ng g^?1 (wet wt).Results are compared with data obtained during earlier investigations with flounder eggs.     

Protracted Environmental Issues on a Proposed Titanium Minerals Development in Kenya's South Coast

This study takes cognizance of the fact that the TIOMIN (TIOMIN Resources Inc. of Canada) project has resulted in controversy over its handling of environmental issues and especially the Environmental Impact Assessment (EIA). The authors address many of the protracted issues that have slowed the development of the mining project in Kwale. The main emphasis is on the impacts of the mining and mineral separation processes on the environment, including the governing legislation, the role of consultation and public participation, and socioeconomic issues. In their public documents TIOMIN has specified neither the type of minerals it wants to extract from the area nor their chemical composition. It is well known, however that the titanium minerals and zircon targeted have impurities of iron, thorium and uranium. In the absence of an Environmental Management Plan, the effects of stockpiling radioactive wastes and other impurities that could possibly lead to environmental degradation in both the terrestrial and marine environments have not been publically addressed. The measures proposed to mitigate ecological damage as a result of the establishment of a minerals processing plant in the area seem inadequate. Pollution resulting from accidental spillage or breakage could have significant impact on marine life and residents living near the mining site. Other issues that have not been addressed satisfactorily pertain to the use of surface and underground water. The area already faces a huge water deficit and the calculations presented on aquifer recharge and stream flow rates do not indicate the large quantities of water that would be required in the mineral processing plant. The project, if approved in its present state, risks violation of international conventions. Furthermore, it could cause a conflict between Kenya and Tanzania in the event of an oil spill at the proposed ship loading facility at Shimoni. The proposed mining area includes the district's most fertile land, is home to many fisherfolk and is a major tourist destination. An analysis of the effects of this project on other available opportunities must be thoroughly understood to ascertain the economic and environmental benefits and costs of the mining venture. The proposed compensation rate of $1,000 per acre, for resettlement for example, appears to be grossly inadequate. Compensation should take into account family size and structure family assets and the cost of relocation.     

Past and present sedimentary activity in the Capbreton Canyon, southern Bay of Biscay

Located in the south-eastern part of the Bay of Biscay, the Capbreton Canyon incises the continental shelf up to the 30 m isobath contour, and acts as a natural conduit for continental and shelf-derived sediments. EM1000 multibeam bathymetry shows two main features characterising the canyon — a deeply entrenched meandering channel, bordered by fluvial-like terraces constituting large sediment traps. A dataset of cores and seismic profiles together with a multibeam bathymetry map has enabled the characterisation of recent sedimentary activity in the axial channel and on the terraces. Data analysis evidenced the major role of the canyon head in recent sediment dynamics. This part of the canyon is a temporary reservoir for sediments, accumulated by coastal hydrodynamic processes. Exceptional climatic, tectonic or hydrodynamic events can mobilise the sediments and generate gravity-driven flows. Under the present-day sea-level highstand conditions, these flows are not powerful enough to bring their bedload to the deep sea, and are confined mainly to the upper part of the canyon. Turbidity currents model the axial channel pathway and are at the origin of terrace formation. Terraces in the Capbreton Canyon are not typical but rather are reduced to confined levees. Three factors control the vertical growth of a terrace: (1) the amount of overspilled sediments brought by turbidity currents, (2) hemipelagic sedimentation and (3) terrace height. The amount of sediment spilling over a terrace decreases with increased terrace elevation. Concurrently, the proportion of hemipelagic fallout depositing on a terrace increases. Terraces are considered to be fossil when the height of the terrace prevents further deposition by overspilling. The terraces studied in this paper are interpreted as having formed during the Holocene, implying that the sediment dynamics of the Capbreton Canyon is continuous through time. Highstand periods differ from lowstand periods because they show a decrease in the energy of erosive processes. Temporal variations in erosive and depositional processes in the canyon are controlled by the Adour River, which delivers large amounts of sediment to the system.     

Persistent volcanic signature observed around Barren Island, Andaman Sea, India

This study delineates the formation of a warm pool (>34°C) of air to the west (downwind) of the active volcano of the Barren Island during October–November 2005. Barren Island is located in the Sumatra–Andaman region, about 135 km east of Port Blair, and lies within the Burma microplate, the southern tip of which experienced a submarine earthquake (M _w 9.3) causing a tsunami in December 2004. Barren Island is the only volcano, which has shown sustained eruptive activity since shortly after the Great Sumatran Earthquake of December 2004. Our observations require further corroboration to relate how submarine earthquakes activate volcanoes and how far these thermal emissions influence climate changes. Because it links global warming and climate changes to the frequent emissions from a volcano activated by submarine earthquakes, this case study is of special interest to the earth-ocean-atmosphere sciences community.     

Simulation of additive transport from the land surface on the basis of experimental data on heat transfer in the atmospheric surface layer

A method is proposed to study the transport of a passive additive in the atmospheric surface layer with the use of the atmospheric transfer function. This method makes it possible to estimate the spatial distribution of the concentration of a passive additive in the atmospheric surface layer from the additive’s surface source without experimentally determining the vertical profile of the transport coefficient or without resorting to various hypotheses for the character of its behavior. The transfer function, which contains the information on the wind-field structure, can be obtained from simple one-point measurements of surface-and air-temperature fluctuations and from subsequent spectral processing of the data. The effects of the wind-velocity profile and turbulence on the spatial distribution of additive concentration are assessed. This method allows one to simplify experiments during development and verification of the models of atmospheric diffusion. This method may also be useful in emergency situations to predict the propagation of hazardous additives.     

Condition of coastal mesoplankton communities in the northeastern area of the Black Sea in 2005

The structure and distribution of mesoplankton in the northeastern part of the Black Sea along 6-mile and 100-mile sections in the area off Golubaya Bay (near the city of Gelendzhik) were analyzed. The studies were performed from R/V Akvanavt and the boat Ashamba. The observations were carried out during the vegetation season from the beginning of June to the first half of October 2005. Samples of mesoplankton were collected with use of a BSD net with an opening of 0.1 m² and a mesh size of 180 μm. Both the total (over the entire water column) and layer-by-layer (separately for the upper quasi-homogeneous layer, the seasonal thermocline, and the subthermocline layer) hauls were performed down to the bottom (at sea depths of less than 200 m) or down to the upper boundary of the hydrogen sulfide waters. The particular hydrophysical conditions that were observed in 2005 resulted in an approximately one-month advance of the phenological condition of the planktonic community as compared to the usual pattern. Beroe ovata appeared in the plankton at the end of July, the mass development of Mnemiopsis leidyi was suppressed, and the duration of its influence on edible zooplankton was essentially reduced. As a result, the total mesoplankton biomass in August–October 2005 was 1.5–2 times as great as that in 2004. The abundance of Acartia clausi increased approximately 4–5 times and the quantity of Sagitta setosa also considerably increased. At selected stations, Mnemiopsis leidyias, the main predator in the community, was replaced by Sagitta setosa.     

Primary production in the eastern tropical Pacific: A review

The eastern tropical Pacific includes 28 million km² of ocean between 23.5°N and S and Central/South America and 140°W, and contains the eastern and equatorial branches of the north and South Pacific subtropical gyres plus two equatorial and two coastal countercurrents. Spatial patterns of primary production are in general determined by supply of macronutrients (nitrate, phosphate) from below the thermocline. Where the thermocline is shallow and intersects the lighted euphotic zone, biological production is enhanced. In the eastern tropical Pacific thermocline depth is controlled by three interrelated processes: a basin-scale east/west thermocline tilt, a basin-scale thermocline shoaling at the gyre margins, and local wind-driven upwelling. These processes regulate supply of nutrient-rich subsurface waters to the euphotic zone, and on their basis we have divided the eastern tropical Pacific into seven main regions. Primary production and its physical and chemical controls are described for each.Enhanced rates of macronutrient supply maintains levels of primary production in the eastern tropical Pacific above those of the oligotrophic subtropical gyres to the north and south. On the other hand lack of the micronutrient iron limits phytoplankton growth (and nitrogen fixation) over large portions of the open-ocean eastern tropical Pacific, depressing rates of primary production and resulting in the so-called high nitrate-low chlorophyll condition. Very high rates of primary production can occur in those coastal areas where both macronutrients and iron are supplied in abundance to surface waters. In these eutrophic coastal areas large phytoplankton cells dominate; conversely, in the open-ocean small cells are dominant. In a ‘shadow zone’ between the subtropical gyres with limited subsurface ventilation, enough production sinks and decays to produce anoxic and denitrified waters which spread beneath very large parts of the eastern tropical Pacific.Seasonal cycles are weak over much of the open-ocean eastern tropical Pacific, although several eutrophic coastal areas do exhibit substantial seasonality. The ENSO fluctuation, however, is an exceedingly important source of interannual variability in this region. El Niño in general results in a depressed thermocline and thus reduced rates of macronutrient supply and primary production. The multi-decadal PDO is likely also an important source of variability, with the ‘El Viejo’ phase of the PDO resulting in warmer and lower nutrient and productivity conditions similar to El Niño.On average the eastern tropical Pacific is moderately productive and, relative to Pacific and global means, its productivity and area are roughly equivalent. For example, it occupies about 18% of the Pacific Ocean by area and accounts for 22–23% of its productivity. Similarly, it occupies about 9% of the global ocean and accounts for 10% of its productivity. While representative, these average values obscure very substantial spatial and temporal variability that characterizes the dynamics of this tropical ocean.     

Equilibrium constants of triethanolamine in major seawater salts

Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl₂ or CaCl₂), with binary mixtures of MgCl₂ and CaCl₂, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl₂, while it is increased by the other electrolytes used in this work.     

Baroclinic Buoyancy-Inertia Joint Stability Parameter

At present, the barotropic buoyant stability parameter has been derived from a vertical virtual displacement of a water parcel. The barotropic inertial stability parameter in the eccentrically cyclogeostrophic, basic current field was derived in 2003 from a horizontal cross-stream virtual displacement of a parcel. By expressing acceleration of a parcel due to a virtual displacement, which is arbitrarily sloping within a vertical section across the basic current, in terms of natural coordinates, we derived the vertical component of baroclinic buoyant stability parameter B ₂ ², the horizontal component of baroclinic inertial stability parameter I ₂ ², the baroclinic joint stability parameter J ², its buoyant component B ² and its inertial component I ². B ² is far greater than I ₂ ², and when neglecting relative vorticity except for vertical shear, a downward convex curve of J ² plotted against the slope of a virtual displacement follows a trend of B ² curve. If a parcel displaces along a horizontal surface or an isopycnal surface, however, B ² vanishes, and J ² becomes equal to I ². Actual parcel is apt to displace not only along the bottom slope, but also along the sea surface and an isopycnal interfacial surface, which is approximately equivalent to an isentropic surface, preferred by lateral mixing and exchange of momentum. Such actual displacement makes B ² vanishing, and grants I ² an important role. The present analysis of I ² examining effects due to curvature and horizontal and vertical shear vorticities are useful in deepening our understanding of baroclinic instability in actual oceanic streams.