Pyrite tracks assimilation of crustal sulfur in Pyrenean peridotites

Cobalt-bearing pyrite (0.5?C2.0?wt.% Co) is abnormally abundant (up to 35?vol.% of the total volume of the sulfide phase) in some eastern Pyrenean peridotite massifs, compared to pieces of subcontinental mantle studied so far for sulfides. Pyrite occurs as vermicular intergrowths inside pentlandite and/or chalcopyrite or as coarser, blocky grains in the intergranular pores of host peridotites. Those different pyrites are characterized by different platinum-group element systematics (measured by laser ablation microprobe and ICP-MS). Vermicular pyrite intergrown with pentlandite displays Os-, Ir-, Ru- and Rh-enriched chondrite normalized PGE patterns of Monosulfide solid solution (Mss). In contrast, coarse-grained intergranular (??blocky??) pyrites, are PGE-poor. Chalcophile trace elements (i.e. Zn, Pb, Ag, Au) that are not usually concentrated in mantle-derived sulfides were commonly detected. By contrast, selenium contents are generally low, yielding thus pyrite with high S/Se ratio (>10⁵), consistent with a sedimentary sulfur source. Pyrite microtextures and chalcophile trace element contents support a process of assimilation of crustal sulfur from the metamorphosed sedimentary country rocks. These latter generated highly reactive CO₂-S fluids, which were injected into structural discontinuities of the lherzolitic bodies. Sulfur has reacted at T?=?300?C550°C with pre-existing, mantle-derived, metal-rich sulfide assemblages (pentlandite-chalcopyrite). Addition of crustal sulfur did produce Mss which, on cooling, exsolved the Os-rich pyrite in addition to pentlandite. The coarse-grained pyrite types have crystallized directly from S-rich fluids.     

PAssive COastal TOMography: an Innovative Approach for the Remote Monitoring of Sea Temperature

Abstract. This paper describes a new Ocean Acoustic Tomography (OAT) methodology - a passive tomography - presently in an advanced development phase. This technique has been developed for long-term, extensive, remote monitoring of the seawater temperature spatial distribution, which is estimated from the received noise emitted from ships of opportunity. To test the passive tomographic processor under controlled conditions, the components of the naval noise from different kinds of vessels was analysed and realistic naval noise was simulated. The feasibility of the proposed methodology was confirmed by test-runs on semi-synthetic data; its capability to resolve temperature profiles will be better assessed with the use of real acoustic and environmental data collected during the INTIMATE00 experiment performed in October 2000 in the Atlantic Ocean off the Portuguese coast. An analysis of the space and time variability of the Empirical Orthogonal Function (EOF) decomposition of the sound speed (SSP) in the Mediterranean Sea has been carried out to identify areas where acoustic tomography can be successfully applied. Results from simulations in the South Adriatic Sea, which was identified as a region with a high sound speed variability associated with the seasonal cycle and with the main oceanographic processes, are reported.     

Age of river basins in Guadeloupe impacting chemical weathering rates and land use

The Lesser Antilles have very high chemical weathering rates, with values that can reach 1290 t/km²/a. The tropical environment induces high precipitation rates, high temperature, dense vegetation, with sharp relief and thick soils. Because of volcanic activity, frequent pyroclastic flows produce very erodible and porous materials. In addition, agriculture induces important land use changes which replace existing native forest cover with banana and sugar cane plantations. Their surface can cover as much as 40% of the total area of a river basin. The aim of this study is to identify key parameters, either natural or anthropogenic, that control chemical weathering rates. Among the combined impact of all parameters (climate, runoff, slopes, vegetation etc.), basin age seems to be the control parameter: the younger the basin, the higher the weathering rate. A correlation between the chemical weathering rate and the basin age suggests that young volcanic rocks are more easily weathered than old ones: young fresh material is easily mobilized by erosion, while for older rocks with thick soil covers, chemical rates are much lower. A combined effect between the higher erodibility and a higher climate erosivity of the younger relief could be observed. Moreover, a correlation between banana plantations and the chemical weathering rates that can be explained by an increase of infiltration, due to stem flow processes is shown here. Banana plantations also have a correlation with the basin age, older basins being more favorable terrains for cultivation.     

Operational performance of current synthetic aperture radar sensors in mapping soil surface characteristics in agricultural environments: application to hydrological and erosion modelling

Synthetic aperture radar (SAR) sensors are often used to characterize the surface of bare soils in agricultural environments. They enable the soil moisture and roughness to be estimated with constraints linked to the configurations of the sensors (polarization, incidence angle and radar wavelength). These key soil characteristics are necessary for different applications, such as hydrology and risk prediction. This article reviews the potential of currently operational SAR sensors and those planned for the near future to characterize soil surface as a function of users' needs. It details what it is possible to achieve in terms of mapping soil moisture and roughness by specifying optimal radar configurations and the precision associated with the estimation of soil surface characteristics. The summary carried out for the present article shows that mapping soil moisture is optimal with SAR sensors at low incidence angles (<35 ). This configuration, which enables an estimated moisture accuracy greater than 6% is possible several times a month taking into account all the current and future sensors. Concerning soil roughness, it is best mapped using three classes (smooth, moderately rough, and rough). Such mapping requires high‐incidence data, which is possible with certain current sensors (RADARSAT‐1 and ASAR both in band C). When L‐band sensors (ALOS) become available, this mapping accuracy should improve because the sensitivity of the radar signal to Soil Surface Characteristics (SSC) increases with wavelength. Finally, the polarimetric mode of certain imminent sensors (ALOS, RADARSAT‐2, TerraSAR‐X, etc.), and the possibility of acquiring data at very high spatial resolution (metre scale), offer great potential in terms of improving the quality of SSC mapping. Copyright © 2007 John Wiley & Sons, Ltd.     

Experimental modelling of shallow magma emplacement: Application to saucer-shaped intrusions

Saucer-shaped dolerite and sandstone intrusions are common in sedimentary basins world-wide. We have conducted a series of scaled experiments simulating the process of magma emplacement in sedimentary basins, with particular attention on the formation of saucer-shaped sills. The model materials were (1) cohesive fine-grained silica flour, representing brittle crust; and (2) molten low-viscosity oil, representing magma. The experiments were performed in both homogeneous and layered models. In all the experiments, oil injection resulted in doming of the surface. In the homogeneous models, the injected oil formed cone sheets and sub-vertical dykes. Cone sheets formed for shallow injection (1–3 cm), and vertical dykes formed for deeper injection (4–5 cm). In layered models, the injected oil always formed saucer-shaped intrusions. Our experimental results show that (1) sill intrusion results in the formation of a dome, with melt erupting at the rim; (2) layering controls the formation of sills and saucer-shaped sills; (3) saucer-shaped sills are fed from the bottom and the fluid flows upward and outward; and (4) the diameter of saucer-shaped sills increase with increasing emplacement depth. The systematic relation between domes and sills and the depth-dependence of sill diameters show that saucer-shaped intrusions result from the interaction between a growing flat-lying shallow sill and doming of the free surface. We conclude that saucer-shaped intrusions represent fundamental geometries formed by shallow magma intrusion in stratified basins.     

Hydraulic conductivity distribution in crystalline rocks, derived from inflows to tunnels and galleries in the Central Alps, Switzerland

Inflow data from 23 tunnels and galleries, 136 km in length and located in the Aar and Gotthard massifs of the Swiss Alps, have been analyzed with the objective (1) to understand the 3-dimensional spatial distribution of groundwater flow in crystalline basement rocks, (2) to assess the dependency of tunnel inflow rate on depth, tectonic overprint, and lithology, and (3) to derive the distribution of fracture transmissivity and effective hydraulic conductivity at the 100-m scale. Brittle tectonic overprint is shown to be the principal parameter regulating inflow rate and dominates over depth and lithology. The highest early time inflow rate is 1,300 l/s and has been reported from a shallow hydropower gallery intersecting a 200-m wide cataclastic fault zone. The derived lognormal transmissivity distribution is based on 1,361 tunnel intervals with a length of 100 m. Such interval transmissivities range between 10^?9 and 10^?1 m²/s within the first 200–400 m of depth and between 10^?9 and 10^?4 m²/s in the depth interval of 400–1,500 m below ground surface. Outside brittle fault zones, a trend of decreasing transmissivity/hydraulic conductivity with increasing depth is observed for some schistous and gneissic geological units, whereas no trend is identified for the granitic units.