Diffusion and solubility of hydrogen and water in periclase

Cylinders of synthetic periclase single crystals were annealed at 0.15–0.5 GPa and 900–1200 °C under water-saturated conditions for 45 min to 72 h. Infrared spectra measured on the quenched products show bands at 3,297 and 3,312 cm^?1 indicating V _OH ^? centers (OH-defect stretching vibrations in a half-compensated cation vacancy) in the MgO structure as a result of proton diffusion into the crystal. For completely equilibrated specimens, the OH-defect concentration, expressed as H₂O equivalent, was calculated to 3.5 wt ppm H₂O at 1,200 °C and 0.5 GPa based on the calibration method of Libowitzky and Rossmann (Am Min 82:1111–1115, 1997). This value was confirmed via Raman spectroscopy, which shows OH-defect-related bands at identical wavenumbers and yields an H₂O equivalent concentration of about 9 wt ppm using the quantification scheme of Thomas et al. (Am Min 93:1550–1557, 2008), revised by Mrosko et al. (Am Mineral 96:1748–1759, 2011). Results of both independent methods give an overall OH-defect concentration range of 3.5–9 (+4.5/?2.6) ppm H₂O. Proton diffusion follows an Arrhenius law with an activation energy E _a = 280 ± 64 kJ mol^?1 and the logarithm of the pre-exponential factor logD_o (m² s^?1) = ?2.4 ± 1.9. IR spectra taken close to the rims of MgO crystals that were exposed to water-saturated conditions at 1,200 °C and 0.5 GPa for 24 h show an additional band at 3,697 cm^?1, which is related to brucite precipitates. This may be explained by diffusion of molecular water into the periclase, and its reaction with the host crystal during quenching. Diffusion of molecular water may be described by logD_H2O (m² s^?1) = ?14.1 ± 0.4 (2σ) at 1,200 °C and 0.5 GPa, which is ~ 2 orders of magnitude slower than proton diffusion at identical P-T conditions.     

Luminescence spectroscopy and microscopy applied to study gem materials: a case study of C centre containing diamonds

The methods of luminescence spectroscopy and microscopy are widely used for the analysis of gem materials. This paper gives an overview of the most important applications of the analysis of laser and UV excited luminescence by spectroscopy and visually by microscopy with emphasis on diamond, and specifically natural type Ib diamond, little studied so far. Luminescence based techniques are paramount to the gemmological analysis of diamond, in order to determine whether it is natural, treated or synthetic. The great sensitivity of luminescence helps detect some emitting centres that are undetectable by any other analytical method. Hence, especially for diamond, luminescence is an enabling technology, as illustrated by its pioneering use of imagery for the separation of natural and synthetic diamond, and of spectroscopy for the detection of High Pressure–High Temperature treatment. For all other gemstones the applications are at the moment less numerous, but nevertheless they remain highly important. They provide quickly information on the identification of a gem material, and its treatment. Besides the study of broad band emissions caused by various colour centres, the typical PL-causing trace elements (amongst others) are chromium, manganese, uranium and rare earth elements. In pearls the study of broad band luminescence can be useful, and particularly the study of pink to red porphyrin luminescence in pearls from certain species such as Pinctada and Pteria and others can help identify the pearl-producing mollusc, or if a pearl has been dyed or not. Type Ib diamonds are representative of the importance and complexity of the analysis of luminescence by microscopy and spectroscopy. They show a wide range of sometimes very complex emissions that result in luminescence colours from green to yellow to orange or red. These emissions show generally very inhomogeneous distribution. They are caused by a range of defects, however only a few of them are well characterized.     

Hydrogeochemical transport modeling of the infiltration of tertiary treated wastewater in a dune area, Belgium

Managed artificial recharge (MAR) is a well-established practice for augmentation of depleted groundwater resources or for environmental benefit. At the St-André MAR site in the Belgian dune area, groundwater resources are optimised through re-use of highly treated wastewater by means of infiltration ponds. The very high quality of the infiltration water sets this system apart from other MAR systems. The low total dissolved solid (TDS) content in the infiltration water (less than 50 mg/L) compared to the dune aquifer (500 mg/L) triggers a number of reactions, increasing the TDS through soil-aquifer passage. Multi-component reactive transport modelling was applied to analyse the geochemical processes that occur. Carbonate dissolution is the main process increasing the TDS of the infiltration water. Oxic aquifer conditions prevail between the infiltration ponds and the extraction wells. This is driven by the high flow velocities, leaving no time to consume O₂ between the ponds and extraction wells. Cation exchange is important when infiltration water is replaced by native dune water or when significant changes in infiltration-water quality occur. The seasonal variation of O₂ and temperature in the infiltration water are the main drivers for seasonal changes in the concentration of all major ions.     

Evaluation of unconfined aquifer parameters from flow to partially penetrating wells in Tailan River basin, China

Effective evaluation, management and abstraction of groundwater resources of any aquifer require accurate and reliable estimates of its hydraulic parameters. This study, therefore, looks at the determination of hydraulic parameters of an unconfined aquifer using both analytical and numerical approaches. A long-duration pumping test data obtained from an unconfined aquifer system within the Tailan River basin in Xinjiang Autonomous Region in the northwest of China is used, in this study, to investigate the best method for estimating the parameters of the aquifer. The pumping test was conducted by pumping from a radial collector well and measuring the response in nine observation wells; all the wells used in the test were partially penetrating. Using two well-known tools, namely AquiferTest and MODFLOW, as an aid for the analytical and numerical approaches, respectively, the parameters of the aquifer were determined and their outputs compared. The estimated horizontal hydraulic conductivity, vertical hydraulic conductivity, and specific yield for the analytical approach are 38.1–50.30 m/day, 3.02–9.05 m/day and 0.204–0.339, respectively, while the corresponding numerical estimates are 20.50–35.24 m/day, 0.10–3.40 m/day, and 0.27–0.31, respectively. Comparing the two, the numerical estimates were found to be more representative of the aquifer in the study area since it simulated the groundwater flow conditions of the pumping test in the aquifer system better than the analytical solution.     

Phantom without ghost

The Nine-Year WMAP results combined with other cosmological data seem to indicate an enhanced favor for the phantom regime, comparing to previous analyses. This behavior, unless reversed by future observational data, suggests to consider the phantom regime more thoroughly. In this work we provide three modified gravitational scenarios in which we obtain the phantom realization without the appearance of ghosts degrees of freedom, which plague the naive approaches on the subject, namely the Brans-Dicke type gravity, the scalar-Einstein-Gauss-Bonnet gravity, and the F(R) gravity, which are moreover free of perturbative instabilities. The phantom regime seems to favor the gravitational modification instead of the universe-content alteration.     

Reply to J.J. Muñoz-Perez et al. Comments on “Confirmation of beach accretion by grain-size trend analysis: Camposoto beach, Cádiz, SW Spain” by E. Poizot et al. (2013) Geo-Marine Letters 33(4)

In a novel finding for a beach environment, Poizot et al. (2013) identified an FB+ trend (sediments becoming finer, better sorted and more positively skewed upshore) on a well-developed swash bar on the upper foreshore of the Camposoto beach of Cádiz in SW Spain. In their Discussion of that paper, Muñoz-Perez et al. (2014) provide some supporting arguments and also report grain-size, beach profile and other data from nearby beaches which differ from those of Poizot and colleagues for Camposoto beach, pointing out that a trend observed on one beach may not apply to a neighbouring beach. However, even though the absolute values differ, the overall trends actually do show the same general behaviour. In our Reply to their comments, we also address some difficulties in comparing granulometric datasets generated by different analytical techniques.     

Inundation extent as a key parameter for assessing the magnitude and return period of flooding events in southern Iceland

Abstract

River flow conditions in many watersheds of Iceland are particularly disturbed during winter by the formation, drifting and accumulation of river ice, whose impact on water encroachment and extent of inundations is not reflected in the discharge records. It is therefore necessary to use river discharge with great caution when assessing the magnitude of past inundations in Iceland, and to give attention to other flood magnitude parameters. A GIS-based methodology is presented that focuses on inundation extent as an alternative parameter for the assessment and ranking of the magnitude of past flooding events in the Ölfusá-Hvítá basin, known as one of the most dangerous flood-prone river complexes in Iceland. Relying ultimately on a macro-scale grid, the method enabled the reconstruction of the extent of inundations, the delineation of the flood plain, and, finally, some estimation of the likelihood of flooding of exposed areas that include marine submergences and river floods for both open water and ice conditions.

Citation Pagneux, E., Gísladóttir, G. & Snorrason, Á. (2010) Inundation extent as a key parameter for assessing the magnitude and return period of flooding events in southern Iceland. Hydrol. Sci. J. 55(5), 704–716.     

Energy fluxes and melt rate of a seasonal snow cover in the Moroccan High Atlas

ABSTRACT

In this study, we used an energy balance model and two simple methods based on readily available data to identify the processes driving the point-scale energy and mass balance of the snowpack. Data were provided from an experimental site located at 3200 m. All models were evaluated by comparing observed and modelled snow water equivalents. Performances are variable from one season to the next and the energy balance model gives better results (mean of root mean square error, RMSE = 25 mm and r² = 0.90) than the two simplified approaches (mean of RMSE = 54 mm and r² = 0.70). There are significant amounts of snow sublimation but they are highly variable from season to season, depending on wind conditions (between 7 and 20% of the total). While the main source of energy for melting is net radiation, the amount of heat brought by sensible heat flux is significant for two of the most windy snow seasons.

Editor Z.W. Kundzewicz Associate editor not assigned     

SELF: Semantically Enriched Line simpliFication

Linear features are represented on paper or digital maps with polyline geometries. Sampling, discretization, and generalization processes result in polylines of a length smaller than that of the actual features. In addition, semantics associated to the original line features may be lost. This becomes more significant for coarse sampling and/or high degree of generalization. This paper introduces a data structure that can alleviate this problem, by preserving the attributes and semantic characteristics associated to the original features in cartographic representation. The structure can handle both linear features and polygon outlines. Various compression methods have been examined. The structure has been implemented and tested with both synthetic and real datasets. Extensions to spatiotemporal features, like trajectories, have also been considered.