Log-uniform distribution of gold deposits along major Archean fault zones

The location of potentially unrecognized gold deposits in the close vicinity of the Cadillac–Larder Lake Fault Zone in the Archean Abitibi Subprovince (Canada) is predicted by applying a stochastic approach to the distribution of known gold deposits. The methodology uses the distances between neighboring orogenic gold deposits along the fault trace. The cumulative distribution of the curvilinear inter-distances along the fault zone, are adequately represented by a log-uniform model. The average inter-distance is 1.95 km, and an upper inter-distance of 5.6 km is observed. The same distribution pattern appears along the Destor–Porcupine Fault Zone (Abitibi). This log-uniform distribution shows that the spatial distribution of gold deposits is regionally controlled by the major crustal shear zone. Lithologies and structures only seem to exert a local influence at the deposit scale. The log-uniform spacing could be interpreted as the result of the crustal failure locations induced by hydraulic overpressure along mechanically independent segments on the main fault.     

Spatial differences in denitrification and bacterial community structure of streams: relationships with environmental conditions

In streams, benthic bacterial communities are integral to multiple aspects of ecosystem function, including carbon and nitrogen cycles. Variation both in terms of bacterial community structure (based on taxonomic and/or functional genes) and function can reveal potential drivers of spatiotemporal patterns in stream processes. In this study, the abundance and diversity of 16S rRNA genes and abundance of nosZ genes, encoding for nitrous oxide reductase, were related to denitrification and environmental conditions. Denitrification rates varied among the three streams examined, and within a given stream there were significant longitudinal differences. Likewise, bacterial community structure based on analysis of the 16S rRNA gene also differed significantly among streams. However, variation in denitrification rate was not well correlated with environmental or biological variables measured. In addition, relatively large numbers of denitrifiers occurred when denitrification rates were low. In conclusion, although the streams differed in environmental conditions as well as bacterial community structure, these differences did not explain much of the spatial variation in denitrification rates.     

Multibeam bathymetry and sidescan imaging of the Rivera Transform–Moctezuma Spreading Segment junction, northern East Pacific Rise: New constraints on Rivera–Pacific relative plate motion

To better understand the recent motion of the Pacific plate relative to the Rivera plate and to better define the limitations of the existing Rivera–Pacific plate motion models for accurately predicting this motion, total-field magnetic data, multibeam bathymetric data and sidescan sonar images were collected during the BART and FAMEX campaigns of the N/O L'Atalante conducted in April and May 2002 in the area surrounding the Moctezuma Spreading Segment of the East Pacific Rise, located offshore of Manzanillo, Mexico, at 106°16′W, between 17.8°N and 18.5°N. Among the main results are: (1) the principle transform displacement zone of the Rivera Transform is narrow and well defined east of 107o15′W and these azimuths should be used preferentially when deriving new plate motion models, and (2) spreading rates along the Moctezuma Spreading Segment should not be used in plate motion studies as either seafloor spreading has been accommodated at more than one location since the initiation of seafloor spreading in the area of the Moctezuma Spreading Segment, or this spreading center is not a Rivera–Pacific plate boundary as has been previously assumed. Comparison of observed transform azimuths with those predicted by the best-fit poles of six previous models of Rivera–Pacific relative motion indicate that, in the study area, a significant systematic bias is present in the predictions of Rivera–Pacific motion. Although the exact source of this bias remains unclear, this bias indicates the need to derive a new Rivera–Pacific relative plate motion model.     

Analysis of snow-vegetation interactions in the low Arctic-Subarctic transition zone (northeastern Canada)

Abstract

Recent studies have shown that northern vegetation has been growing in relation to a warming climate over the last four decades, especially across the transition zone between tundra and taiga. Shrub growth affects snow properties and the surface energy budget, which must be better studied to quantify shrub-snow-climate feedbacks. The objective of this research is to improve the characterization of the impact of shrubs on snow evolution, from its accumulation to its melt, using in-situ and satellite measurements. The research is presented for the Umiujaq site, Nunavik, representative of the low Arctic–Subarctic transition zone. Snow depth, measured along numerous transects spanning different land cover types is found to increase by a factor 2.5–3 between tundra and forest, while snow density decreases. This illustrates the trapping effect of vegetation well. Complementary, continuous snow depth measurements using weather stations from two sites (tundra with low shrubs and a small clearing with shrubs within the forest) show different site-dependent behaviors. Spatial analysis from high-resolution Pleiades images combined with Landsat (Normalized Difference Snow Index) and MODIS (Fractional Snow Cover) images suggest a slight delay in melt over open and dense forest areas compared to tundra and dense high shrubs.     

Velocity and abundance precisions for future high‐resolution spectroscopic surveys: A study for 4MOST

In preparation for future, large‐scale, multi‐object, high‐resolution spectroscopic surveys of the Galaxy, we present a series of tests of the precision in radial velocity and chemical abundances that any such project can achieve at a 4 m class telescope. We briefly discuss a number of science cases that aim at studying the chemo‐dynamical history of the major Galactic components (bulge, thin and thick disks, and halo) – either as a follow‐up to the Gaia mission or on their own merits. Based on a large grid of synthetic spectra that cover the full range in stellar parameters of typical survey targets, we devise an optimal wavelength range and argue for a moderately high‐resolution spectrograph. As a result, the kinematic precision is not limited by any of these factors, but will practically only suffer from systematic effects, easily reaching uncertainties <1km s^–1. Under realistic survey conditions (namely, considering stars brighter than r = 16 mag with reasonable exposure times) we prefer an ideal resolving power of R ∼20 000 on average, for an overall wavelength range (with a common two‐arm spectrograph design) of [395;456.5] nm and [587;673] nm. We show for the first time on a general basis that it is possible to measure chemical abundance ratios to better than 0.1 dex for many species (Fe, Mg, Si, Ca, Ti, Na, Al, V, Cr, Mn, Co, Ni, Y, Ba, Nd, Eu) and to an accuracy of about 0.2 dex for other species such as Zr, La, and Sr. While our feasibility study was explicitly carried out for the 4MOST facility, the results can be readily applied to and used for any other conceptual design study for high‐resolution spectrographs. (© 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

High albedo dune features suggest past dune migration and possible geochemical cementation of aeolian sediments on Mars

High albedo features are identified in association with barchan dunes in an equatorial inter-crater dune field on Mars using images from the MRO mission. This paper describes the morphometric properties of these features and their association with the present barchan dune field. We propose that these features are cemented aeolian deposits that form at the foot of the dune avalanche face. A possible terrestrial analog exists at White Sands National Monument, in south-central New Mexico, USA. The presence of these features suggests past episodes of dune migration in inter-crater dunefields and liquid water in the near sub-surface in sufficient quantity to cause the cementation of aeolian dune sediment.     

Jiddat al Harasis 422: A ureilite with an extremely high degree of shock melting

The Jiddat al Harasis (JaH) 422 ureilite was found in the Sultanate of Oman; it is classified as a ureilitic impact melt breccia. The meteorite consists of rounded polycrystalline olivine clasts (35%), pores (8%), and microcrystalline matrix (57%). Clasts and matrix have oxygen isotopic values and chemical compositions (major and trace elements) characteristic of the ureilite group. The matrix contains olivine (Fo_83–90), low‐Ca pyroxene (En_84–92Wo_0–5), augite (En_71–56Wo_20–31), graphite, diamond, Fe‐metal, sulfides, chromite, and felsic glass. Pores are partly filled by secondary Fe‐oxihydroxide and desert alteration products. Pores are surrounded by strongly reduced silicates. Clasts consist of fine‐grained aggregates of polygonal olivine. These clasts have an approximately 250 μm wide reaction rim, in which olivine composition evolves progressively from the core composition (Fo_79–81) to the matrix composition (Fo_84–87). Veins crossing the clasts comprise pyroxene, Fe‐oxihydroxide, C‐phases, and chromite. Clasts contain Ca‐, Al‐, and Cr‐rich glass along olivine grain boundaries (<1 μm wide). We suggest that a significant portion of JaH 422, including olivine and all the pyroxenes, was molten as a result of an impact. In comparison with other impact‐melted ureilites, JaH 422 shows the highest melt portion. Based on textural and compositional considerations, clasts and matrix probably originated from the same protolith, with the clasts representing relict olivine that survived, but was recrystallized in the impact melt. During the melt stage, the high availability of FeO and elevated temperatures controlled oxygen fugacity at values high enough to stabilize olivine with Fo_～83–87 and chromite. Along pores, high Mg# compositions of silicates indicate that in a late stage or after melt crystallization FeO became less available and fO₂ conditions were controlled by C?CO + CO₂.     

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Detection of manure-derived organic compounds in rivers draining agricultural areas of intensive manure spreading

It is essential to have suitable tools able to trace the fate of manure organic matter in the environment to assess whether manure disposal on the soils of catchments could affect the organic quality of rivers. Sterol compounds – mainly expressed as C_29 + 28/C₂₇ and 5β/C₂₇ ratios – have been shown to be specific molecular tracers of pig, dairy and poultry manures in soils. The objective of this study was to measure C_29 + 28/C₂₇ and 5β/C₂₇ ratios in five Brittany rivers (Elorn, Yar, Léguer, Min Ran and Couesnon) draining agricultural catchments receiving massive annual inputs of pig, poultry and dairy manures and compare these ratios with ratios published for enriched soils and manure samples. The particulate organic fractions from the studied rivers yielded steroid signatures typical of animal manures. More specifically, a stanol compound diagnostic of pig slurry – the 5β-stanol known as coprostanol – was found to be very widespread, with particularly high concentrations in one of the rivers (Elorn). The C_29 + 28/C₂₇ and 5β/C₂₇ ratios of the particulate fractions of the rivers were compared with ratios measured directly in pig, dairy and poultry manure samples, as well as with the breeding activities on river catchments. These comparisons show that the steroid profiles of the five investigated rivers correlate closely with the types of manure (i.e. pig, poultry or dairy) spread on soils in their catchments. For instance, the C_29 + 28/C₂₇ and 5β/C₂₇ ratios in the Elorn river are similar to the values typical of pig slurry (e.g. 5β/C₂₇ > 4); compared with other catchments, the soils in this area receive by far the largest amount of pig slurry. By contrast, the Yar river drains a catchment receiving only poultry and dairy manures, and its soils exhibit C_29 + 28/C₂₇ and 5β/C₂₇ ratios similar to those of dairy and poultry manures (e.g. 5β/C₂₇ ∼ 1). Thus, this study indicates that the organic quality of rivers is modified in catchments where there is intense manure spreading on soils. It also provides evidence that rivers draining areas receiving different manure types may exhibit differences in the long-term evolution of their OM content. Indeed, two of the investigated river catchments receive dominantly dairy and poultry manure, and exhibit clear long-term upward trends in OM. On the other hand, one catchment receiving high proportions of pig slurry clearly shows a long-term downward trend in OM contents. A survey of the literature shows that the relative amount of OM and N received by soils in agricultural catchments could be the key parameter in determining the direction of the long-term OM trend of the river, rather than the absolute amount and/or type of manure that is applied to the soil. In any case, the present study suggests that sterol/stanol compounds may be of diagnostic value in determining whether a stream or a river is undergoing contamination by manure-derived organic matter.     

Kinetic Study of the Reactions of Ozone with Polycyclic Aromatic Hydrocarbons Adsorbed on Atmospheric Model Particles

In this experimental study, rate constants were measured for the reactions of ozone with 13 polycyclic aromatic hydrocarbons (PAHs) adsorbed on different types of particles. Graphite and silica were chosen to model, respectively, carbonaceous and mineral atmospheric particles. The pseudo-first order rate constants were obtained from the fit of the experimental decay of particulate PAH concentrations versus time. Second order rate constants were calculated considering the ozone gaseous concentration. At room temperature, rate constants varied, in the case of graphite particles, between (1.5 ± 0.5) × 10⁻¹⁷ and (1.3 ± 0.7) × 10⁻¹⁶ cm³ molecule⁻¹ s⁻¹ for chrysene and dibenzo[a,l]pyrene, respectively, and, in the case of silica particles, between (1.5 ± 0.3) × 10⁻¹⁷ and (1.4 ± 0.3) × 10⁻¹⁶ cm³ molecule⁻¹ s⁻¹ for fluoranthene and benzo[a]pyrene, respectively. Different granulometric parameters (particle size, pore size) and different PAH concentrations were tested in the case of silica particles. Heterogeneous reactions of ozone with particulate PAHs are shown to be more rapid than those occurring in the gas-phase, and may be competitive with atmospheric photodegradation.