The certified Maine North Woods, where money grows from trees

Beginning in the 1990s, private ownership in Maine forestland shifted from a number of corporate owners to a patchwork of timber investment management organizations (TIMOs) and real estate investment trusts (REITs). This transformation reflected restructuring trends in the paper and pulp industry. During this same period, forest certification increased to levels that today make Maine one of the most certified states in the United States with nearly 8 million acres certified by one of a number of certifying entities. This paper examines the contradictory tensions of these trends. Specifically, the conservation goals of certification are undercut by increased investment in timber resources characterized by new financial instruments focused on return on investments. The increased use of first-party, industry-based certification suggests that the antagonisms between capital and conservation are being resolved in ways that undermine the purported conservation goals of forest certification standards.     

Oxygen isotope fractionation in synthetic magnesian calcite

Mg-bearing calcite was precipitated at 25°C in closed system free-drift experiments from solutions containing NaHCO₃, CaCl₂ and MgCl₂. The chemical and isotope composition of the solution and precipitate were investigated during time course experiments of 24-h duration. Monohydrocalcite and calcite precipitated early in the experiments (<8 h), while Mg-calcite was the predominant precipitate (>95%) thereafter. Solid collected at the end of the experiments displayed compositional zoning from pure calcite in crystal cores to up to 23 mol% MgCO₃ in the rims. Smaller excursions in Mg were superimposed on this chemical record, which is characteristic of oscillatory zoning observed in synthetic and natural solid-solution carbonates of differing solubility. Magnesium also altered the predominant morphology of crystals over time from the {104} to {100} and {110} growth forms.The oxygen isotope fractionation factor for the magnesian-calcite-water system (as 10³lnα_Mg-cl-H2O) displayed a strong dependence on the mol% MgCO₃ in the solid phase, but quantification of the relationship was difficult due to the heterogeneous nature of the precipitate. Considering only the Mg-content and δ¹⁸O values for the bulk solid, 10³lnα_Mg-cl-H2O increased at a rate of 0.17 ± 0.02 per mol% MgCO₃; this value is a factor of three higher than the single previous estimate (Tarutani T., Clayton R.N., and Mayeda T. K. (1969) The effect of polymorphims and magnesium substitution on oxygen isotope fractionation between calcium carbonate and water. Geochim. Cosmochim. Acta 33, 987-996). Nevertheless, extrapolation of our relationship to the pure calcite end member yielded a value of 27.9 ± 0.02, which is similar in magnitude to published values for the calcite-water system. Although no kinetic effect was observed on 10³lnα_Mg-cl-H2O for precipitation rates that ranged from 10^3.21 to 10^4.60 μmol · m⁻² · h⁻¹, it was impossible to disentangle the potential effect(s) of precipitation rate and Mg-content on 10³lnα_Mg-cl-H2O due to the heterogeneous nature of the solid.The results of this study suggest that paleotemperatures inferred from the δ¹⁸O values of high magnesian calcite (>10 mol% MgCO₃) may be significantly underestimated. Also, the results underscore the need for additional experiments to accurately characterize the effect of Mg coprecipitation on the isotope systematics of calcite from a chemically homogeneous precipitate or a heterogeneous material that is analyzed at the scale of chemical and isotopic zonation.     

A comparison of selected Precambrian Brazilian chromitites: Chromite, PGE-PGM, and Re/Os as parental source indicators

Mineralogical and geochemical studies were carried out in chromitites belonging to the mafic–ultramafic bodies of Niquelândia, Luanga, and Campo Formoso, which are, respectively, included in the Goiás Massif and the Amazon and São Francisco cratons. The main platinum-group minerals (PGM) included or associated with chromite grains are laurite in Niquelândia and Campo Formoso and sperrylite and braggite in Luanga. The most common primary base metal sulfides (BMS) are pentlandite, chalcopyrite, and minor pyrrhotite. Also present are base metal alloys (BMA), such as awaruite, and the BMS millerite, pyrite, and copper as secondary mineral phases linked to later alteration process. The Luanga chromites display the lowest Cr₂O₃/Al₂O₃ and Cr₂O₃/FeO_t ratios. The chondrite-normalized profiles are strongly enriched in the platinum PGE subgroup (PPGE, Pt, Pd, Rh). The average Pd/Ir ratio (24.2) and ¹⁸⁷Os/¹⁸⁸Os values (0.17869–0.18584) are very high. Niquelândia chromites have higher Cr₂O₃/Al₂O₃ and Cr₂O₃/FeO_t ratios than Luanga. Its PGE contents are low and chondrite-normalized profiles depleted, mainly in the PPGE subgroup. The average Pd/Ir ratio (0.45) and ¹⁸⁷Os/¹⁸⁸Os values (0.12598–0.12777) are low. Campo Formoso chromites have the highest Cr₂O₃/Al₂O₃ and Cr₂O₃/FeO_t ratios; its average Pd/Ir ratio (0.72) and chondrite-normalized profiles (except the pronounced Ru spike) are closer to those of Niquelândia. The remarkable differences in terms of chromite bulk-composition, PGE contents and patterns, Pd/Ir ratios, and ¹⁸⁷Os/¹⁸⁸Os values associated with probable distinctions in the inferred geochemical compositions of the respective parental magmas indicate that the Luanga and Niquelândia complexes originated from distinct parental sources. Geochemical and isotopic features indicate that Luanga chromitites and associated rocks are consistent with a parental magma, either originated from an enriched mantle reservoir or strongly contaminated, whereas Niquelândia derives from a depleted mantle source, which displays a slightly positive Os anomaly.     

The interplay of geomorphic processes and soil development in an upland environment, Calabria, South Italy

Five representative soil profiles outcropping in the area around the Cecita Lake (Calabria, South Italy) were characterised by field work, chemical and mineralogical analyses, optical and scanning electron microscopy. Interactions among weathering, pedogenesis and geomorphic processes are emphasised, in an attempt to link the results obtained at different scales of observation. The important role of topography in controlling soil development or removal by erosive processes is discussed, in relation to the natural geomorphological context and the effects of human pressure. Both present-day and relict features were recognised in the studied soils, and discussed in terms of environmental conditions and climatic changes. The chemical composition of volcanoclastic components identified in some soil horizons with Andosol-like field appearance, coupled with pedogenetic features, contributed useful chronological constraints for the reconstruction of Late Quaternary geomorphic events.     

Genese des zonar gebauten Beryllpegmatits von Venturinha (Visen,Portugal) in geochemischer Sicht

We present the geologic map of the region of Venturinha (Penalva do Castelo, Viseu), located in the Hercynian Massif, where there are the following outcrops: porphyritic granite, adamellite, aplites, pegmatites with beryl, tantalite and phosphate minerals, quartz veins and alluvium. Occurring in this region, bedded in porphyritic granite, are pegmatites and aplites which are occasionally intimately associated. Pegmatites and aplites, when bedded in adamellite, are very rare and very small in dimensions. The most important pegmatite is that of Venturinha. It has a zoned structure, passing without any break to the bedding porphyritic granite. Particularly well noticeable and well limited are the wall zone, intermediate zone and core as well as the replacement bodies which are very irregular. This pegmatite was studied from the structural, mineralogical, geochemical and genetic points of view. We have quantitatively determined by X-ray spectrography K, Ca, Rb, Sr and Ba in 46 samples of potash-feldspars and albites in the Venturinha pegmatite; and also, by emission spectrography, Pb in these same samples. For all these elements we used the internal standard method. The results obtained, after being transformed into components Or, An and Ab and projected inYoder'S et al. diagram (1957) define two areas, one in the field of feldspars rich in Ab-An and the other in the field of feldspars rich in Ab-Or. Apart from K and Ca, among those elements studied, that which appears in a higher percentage is Rb, followed in decreasing order by Ba., Sr and Pb. As regards Rb we found that there is a noticeable and progressive increase from the orthoclase of the bedding porphyritic granite (480 ppm) to the core of the pegmatite where the potash-feldspars reach up to 2000 ppm of the above element. The variation of the quantity of Ba in pegmatite is much more irregular than that of Rb, although we have noticed that there is a tendency for Ba to decrease as we get nearer to the core. The percentage of Ca in potash-feldspars goes from 0,54% in porphyritic granite to the average value of 0,28% in pegmatite. We have not observed, as in the case of Rb, a gradual variation of Ca in the pegmatitic formation, whether in the potash-feldspars or in the albites, where the average contents in Ca is 0,47%. The distribution of Sr and Pb in pegmatite is very irregular. There is a close geochemical connection between K and Rb, K and Ba, and Rb and Ba in the Venturinha pegmatite. The interpretation of the results obtained by spectrography lead to the following conclusions

1. a)
   The relation K/Rb in the potash-feldspars gives us values which are much below the average (220–230) and this shows the great differentiation occurred in the Venturinha, pegmatite. The distribution of K in function of Rb defines, in accordance with the degree of differentiation attained, an area located at the right hand side of the curves of normal dispersion (Ahrens et al. 1952) altered by TAYLOR et al. (1956). The values of the relation K/Rb in the albites studied fall, most of them, within the limits of the above normal dispersion.     

An eruptive prominence and associated cm-mm emission outside the solar limb

We present radio maps at 22 and 44 GHz which show the emission before and after the eruption of a quiescent prominence located at the west limb. The observed radiation following the eruption is not consistent with thermal bremsstrahlung mechanism. It can be interpreted as due to gyrosynchrotron emission of nonthermal electrons. Our observations appear to be similar to the microwave radiation observed in post-flare loops; this radiation is due to nonthermal electrons trapped in the closed magnetic structures formed after the prominence eruption.     

A high-energy solar flare burst complex and the physical properties of its source region

We discuss a solar flare microwave burst complex, which included a major structure consisting of some 13 spikes of 60 ms FWHM each, observed 21 May, 1984 at 90 GHz (3 mm). It was associated with a simultaneous very hard X-ray burst complex. We suggest that the individual spikes of both bursts were caused by the same electron population: the X-bursts by their bremsstrahlung, and the microwave bursts by their gyrosynchrotron emission. This latter conclusion is based on the evidence that the radio turnover frequency was 150 GHz. It follows that the emission sources were characterized by an electron density of about 10¹¹ cm^–3, a temperature of 5 × 10⁸ K and a magnetic field of about 1400–2000 G. They had a size of about 350 km; if the energy release is caused by reconnection the sources of primary instability could have been smaller and in the form of thin sheets with reconnection speed at a fraction of the Alfvén velocity and burst-like energy injections of 10²⁷ erg during about 50 ms each. The energized plasma knots lost their injection energy by saturated convective flux (collisionless conduction) in about 30 ms.     

The simplest solar microbursts flux and circular polarization at 22 GHz

The simplest solar microwave microbursts detected with high sensitivity may be the response to the simpler energetic burst injections. Seventeen events from this category were identified in a series of more than 150 bursts recorded in 21–26 November, 1982. This first systematic study suggest that microbursts e-folding rise times concentrate into two classes of time scales, 0.05 s < t 1 s and 0.5 s t 2 s. Microbursts circular polarization present a dominant steady or slowly varying component that sets in before maximum emission. In some cases a faster component of polarization was found superimposed, which is not always well correlated in time with flux.     

The long-term variability of Changma in the East Asian summer monsoon system: A review and revisit

Changma, which is a vital part of East Asian summer monsoon (EASM) system, plays a critical role in modulating water and energy cycles in Korea. Better understanding of its long-term variability and change is therefore a matter of scientific and societal importance. It has been indicated that characteristics of Changma have undergone significant interdecadal changes in association with the mid-1970s global-scale climate shift and the mid-1990s EASM shift. This paper reviews and revisits the characteristics on the long-term changes of Changma focusing on the underlying mechanisms for the changes. The four important features are manifested mainly during the last few decades: 1) mean and extreme rainfalls during Changma period from June to September have been increased with the amplification of diurnal cycle of rainfall, 2) the dry spell between the first and second rainy periods has become shorter, 3) the rainfall amount as well as the number of rainy days during August have significantly increased, probably due to the increase in typhoon landfalls, and 4) the relationship between the Changma rainfall and Western Pacific Subtropical High on interannual time scale has been enhanced. The typhoon contribution to the increase in heavy rainfall is attributable to enhanced interaction between typhoons and midlatitude baroclinic environment. It is noted that the change in the relationship between Changma and the tropical sea surface temperature (SST) over the Indian, Pacific, and Atlantic Oceans is a key factor in the long-term changes of Changma and EASM. Possible sources for the recent mid-1990s change include 1) the tropical dipole-like SST pattern between the central Pacific and Indo-Pacific region (the global warming hiatus pattern), 2) the recent intensification of tropical SST gradients among the Indian Ocean, the western Pacific, and the eastern Pacific, and 3) the tropical Atlantic SST warming.