Oil and gas in offshore tracts: Bias in estimates of reserves

Two independent data sets show that current means of estimating reserves of oil and gas in offshore fields are biased. The bias which is established here is that small fields (with less than about 10 million barrels of oil equivalent) are overestimated, and larger fields (at least up to 200 MMBOE) are underestimated. This systematic bias occurs with or without a significant overall bias, and in addition to a large scatter. Because bias (as opposed to scatter) has serious implications for national energy policy, and in particular for conduct of offshore lease sales, these results indicate that evaluation methods should be revised, or that ad hoc adjustments (based on historical data) should be applied.     

Dispersive O+ conics observed in the plasma-sheet boundary layer with CRRES/LOMICS during a magnetic storm

We present initial results from the Low-energy magnetospheric ion composition sensor (LOMICS) on the Combined release and radiation effects satellite (CRRES) together with electron, magnetic field, and electric field wave data. LOMICS measures all important magnetospheric ion species (H⁺, He⁺⁺, He⁺, O⁺⁺, O⁺) simultaneously in the energy range 60 eV to 45 keV, as well as their pitch-angle distributions, within the time resolution afforded by the spacecraft spin period of 30 s. During the geomagnetic storm of 9 July 1991, over a period of 42 min (0734 UT to 0816 UT) the LOMICS ion mass spectrometer observed an apparent O⁺ conic flowing away from the southern hemisphere with a bulk velocity that decreased exponentially with time from 300 km/s to 50 km/s, while its temperature also decreased exponentially from 700 to 5 eV. At the onset of the O⁺ conic, intense low-frequency electromagnetic wave activity and strong pitch-angle scattering were also observed. At the time of the observations the CRRES spacecraft was inbound at L\approx7.5 near dusk, magnetic local time (MLT), and at a magnetic latitude of -23°. Our analysis using several CRRES instruments suggests that the spacecraft was skimming along the plasma sheet boundary layer (PSBL) when the upward-flowing ion conic arrived. The conic appears to have evolved in time, both slowing and cooling, due to wave-particle interactions. We are unable to conclude whether the conic was causally associated with spatial structures of the PSBL or the central plasma sheet.     

Chloride retention in forest soil by microbial uptake and by natural chlorination of organic matter

Inorganic chlorine (i.e. chloride; Cl_in) is generally considered inert in soil and is often used as a tracer of soil and ground water movements. However, recent studies indicate that substantial retention or release of Cl_in can occur in soil, but the rates and processes responsible under different environmental conditions are largely unknown. We performed ³⁶Cl tracer experiments which indicated that short-term microbial uptake and release of Cl_in, in combination with more long-term natural formation of chlorinated organic matter (Cl_org), caused Cl_in imbalances in coniferous forest soil. Extensive microbial uptake and release of Cl_in occurred over short time scales, and were probably associated with changes in environmental conditions. Up to 24% of the initially available Cl_in within pore water was retained by microbial uptake within a week in our experiments, but most of this Cl_in was released to the pore water again within a month, probably associated with decreasing microbial populations. The natural formation of Cl_org resulted in a net immobilization of 4% of the initial pore water Cl_in over four months. If this rate is representative for the area where soil was collected, Cl_org formation would correspond to a conversion of 25% of the yearly wet deposition of Cl_in. The study illustrates the potential of two Cl_in retaining processes in addition to those previously addressed elsewhere (e.g. uptake of chloride by vegetation). Hence, several processes operating at different time scales and with different regulation mechanisms can cause Cl_in imbalances in soil. Altogether, the results of the present study (1) provide evidence that Cl_in cannot be assumed to be inert in soil, (2) show that microbial exchange can regulate pore water Cl_in concentrations and (3) confirm the controversial idea of substantial natural chlorination of soil organic matter.     

A new approach to interpreting Rock-Eval S2 and TOC data for kerogen quality assessment

A simple method for application in source potential mapping is used to assess the original oil and gas potentials in source rock horizons based upon Rock-Eval potential (S₂) and total organic carbon (TOC) values. The method assumes that kerogens consist of mixtures of end-members with assigned hydrogen index values. Based on suggested algorithms, the average amounts of oil-prone, gas-prone and inert organic material over source rock intervals are determined in TOC units. The method uses regression lines from plots of remaining hydrocarbon potentials (S₂) versus total organic carbon (TOC), and “quick-look” transparent overlays are used to read the appropriate kerogen mixture.Mineral matrix effects during pyrolysis, when strong, can cause erroneous results. This effect which occurs for oil-prone kerogens and adsorptive minerals can cause problems particularly for lean samples (S₂ = 0–3 mg HC/g rock) whilst the errors for richer samples are less.The method is applied on three sections of Upper Jurassic organic-rich rocks from the Danish North Sea sector, which are at different maturity stages. One of these sections is dominated by gas-prone material, one is dominated by oil-prone material and the third section contains a mixture of oil- and gas-prone material.The method has been compared with other methods that split kerogens in oil and gas generating potential and has given reasonable results.Experience using the method and a presented example suggest that sedimentological, system tract information may be derived from S₂ to TOC cross-plots. A constructed modelling example suggests that the end-member concept used in this approach may be used in forward type source rock prediction models when combined with sedimentological models. The resulting S₂–TOC plots can be used in order to check the forward modelling results against observed values.     

Single-grain and multigrain luminescence dating of on-ice and lake-bottom deposits at Lake Hoare,Taylor Valley,Antarctica

The large radiocarbon (¹⁴C) reservoir effect in Antarctica varies regionally and with settings. Luminescence sediment dating has potential as an alternate geochronometer. Extending our earlier tests of the effectiveness of resetting of photon-stimulated-luminescence (PSL) that employed only multi-aliquot analyses of fine-silt grains, we applied single-aliquot multigrain, and single-grain-quartz (SGQ) PSL procedures to a variety of samples from on and under the meters-thick perennial ice cover at Lake Hoare. These procedures yielded quartz sand age estimates for ice-surface sand (the source of the lake-bottom sand) of 10–80 a. Sand within a small dune on the perennial lake ice in front of Canada Glacier gave an SGQ age estimate of 48 ± 23 a. These methods produced realistic age estimates in lake-bottom short cores that are at least 5–20 times younger than comparable (uncorrected-for-reservoir) ¹⁴C results. Near-core-top PSL age estimates ranged from zero to ～500 a, depending on the core site. Four of the 7 short cores revealed clear linear age-depth trends for the upper few cm of core. These results demonstrate that for such lake-core deposits, single-aliquot and single-grain PSL dating can replace ¹⁴C dating, at least in Lake Hoare, because PSL dating lacks a significant ‘zero-point’ offset such as the ¹⁴C reservoir effect, and because PSL dating of quartz is applicable to samples as old as ～150 ka under normal sedimentary conditions. Moreover, these results imply that isolated paleo-lake-bottom deposits (e.g., microbial-mat sand mounds above present lake levels) throughout the McMurdo Dry Valleys can now be dated directly.     

六元体系Li-Na-K-Mg-Cl-SO4-H2O多温相平衡预测

采用基于扩展UNIQUAC模型的AQSOL027软件针对水盐体系Li-Na-K-Mg-Cl-SO_4-H_2O的六个五元子体系进行相平衡理论计算,首次报道了多个五元子体系在多个温度条件下的相图,将计算相图与已有实验相图以及基于其它热力学模型的计算相图进行了比较。结果表明:AQSOL027在相图计算中具有较好的准确性和可靠性。AQSOL027是一款基于Excel、用于计算复杂多温水—盐体系Li-Na-K-Mg-Ca-H-Cl-(HSO_4/SO_4)-(CO_2/HCO_3/CO_3)-(H_3BO_3/B_4O_7/BO_2)-OH-H_2O的计算机软件,集成了扩展UNIQUAC模型和相平衡算法,该软件可结合SysCAD和Aspen过程模拟器,实现盐田工艺过程的计算机辅助设计。     

Macroalgal distribution patterns in a shallow, soft-bottom lagoon, with emphasis on the nonnativeGracilaria vermiculophylla andCodium fragile

We determined the distribution of macroalgae in Hog Island Bay, a shallow coastal lagoon in Virginia, USA, seasonally at 12 sites from 1998 to 2000 and at 3 representative sites from 2000 to 2002. We analyzed macroalgal biomass, taxonomic richness, and abundance of two non-native species, the cryptic invaderGracilaria vermiculophylla and the conspicuousCodium fragile, with respect to season, location (mainland, mid lagoon, barrier island sites), and elevation (intertidal, subtidal). Taxonomic richness, total algal biomass, and nonnative biomass peaked in the summer months when temperature and light availability were highest. A few stress tolerant and ephemeral algae dominated the algal assemblage.G. vermiculophylla constituted 74% of the entire algal biomass, was the most abundant alga in all seasons, locations, and elevation levels, and was positively correlated with taxonomic richness and abundance of filamentous species.Ulva curvata, Bryopsis plumosa, andC. fragile accounted for an additional 16% of the algal biomass. There are distinct habitats in Hog Island Bay that can be classified into low diversity-low biomass regions near the mainland and barrier islands and high diversity-high biomass regions in the open mid lagoon, where abundant shells for attachment and intermediate levels of water column nutrients and turbidity likely create better growth conditions. Taxonomic richness and biomass were higher in subtidal than intertidal zones, presumably due to lower desiccation stress. This study provides an example of how a single invasive species can dominate an entire assemblage, both in terms of biomass (being most abundant in all seasons, locations, and tidal levels) and species richness (correlating positively with epiphytic filamentous taxa). By adding hard-substratum structural complexity to a relatively homogenous soft-substratum system,G. vermiculophylla increases substratum availability for attachment and entanglement of other algal species and enhances local diversity. Without widespread and abundantG. vermiculophylla, taxa likePolysiphonia, Ceramium, Bryopsis, Ectocarpus, andChampia would likely be much less common. This study also highlights the importance of using DNA analysis of voucher specimens in monitoring programs to accurately identify cryptic invaders.     

Dating emplacement and evolution of the orogenic magmatism in the internal Western Alps: 1. The Miagliano Pluton

The Canavese Line in the Western Alps represents the position in the Alpine chain, where alkaline and calc-alkaline magmatism occur in close spatial and temporal association. In addition to available data on the alkaline Valle del Cervo Pluton, we present petrological and geochemical data on the Miagliano tonalite. The latter is of special interest, because it is located in the south-eastern side of the Canavese Line, in contrast to most Periadriatic Plutons. The dioritic to tonalitic rocks of the Miagliano Pluton represent an intermediate stage of a calc-alkaline differentiation, demonstrated by relics of two different pyroxenes as well as the texture of allanite. Hornblende barometry indicates pressures of ~0.46?GPa consistent with the presence of magmatic epidote. Field relationships between the two Plutons, the volcanic and volcaniclastic rocks of the Biella Volcanic Suite and numerous dykes cross-cutting the different units, allow reconstruction of a more refined chronology of the calc-alkaline and alkaline magmatic series. High precision zircon geochronology yields an age of 33.00?±?0.04?Ma for the central tonalitic part of the Miagliano Pluton and 30.39?±?0.50?Ma for the granitic core of the Valle del Cervo Pluton. The difference in age combined with cooling data and intrusion depth indicates dissimilar tectonic transport east and west of the Canavese Line. The earlier emplaced Miagliano Pluton has to be exhumed from an intrusion depth of ~12?C15?km, whereas the neighbouring and younger Valle del Cervo Pluton is exhumed from a depth of 5?C7?km. This tectonic scenario is related to upper crustal rigid block rotation responsible for the burial of the lowermost Rupelian paleosurface of the Sesia?CLanzo Zone. Thus, the new ages constrain the paroxysm of the orogenic magmatism in the internal Western Alps to an extremely short lapse of time in the first half of the Rupelian.     

A robust feldspar luminescence dating method for Middle and Late Pleistocene sediments

Luminescence dating is used extensively to provide absolute chronologies for Late Pleistocene sediments. Nowadays, most optical dates are based on quartz optically stimulated luminescence (OSL). However, the application of this signal is usually limited to the last ～100 ka because of saturation of the quartz luminescence signal with dose. In contrast, the feldspar infrared stimulated luminescence (IRSL) dose–response curve grows to much higher doses; this has the potential to extend the datable age range by a factor of 4–5 compared with quartz OSL. However, it has been known for several decades that this IRSL signal is unstable, and this instability often gives rise to significant age underestimation. Here we test against independent age control the recently developed feldspar post‐IR IRSL approach to the dating of sediments, which appears to avoid signal instability. A physical model explaining our observations is discussed, and the method is shown to be accurate back to 600 ka. The post‐IR IRSL signal is reduced by exposure to daylight more slowly than that from quartz and low‐temperature IRSL, preventing its general application to young (e.g. Holocene) sediments. Nevertheless, this new approach is widely applicable (feldspar of appropriate luminescence behaviour is even more ubiquitous than quartz). These characteristics make this a method of great importance for the dating of Middle and Late Pleistocene deposits.