Small-scale heterogeneities below the Gräfenberg array, Germany from seismic wavefield fluctuations of Hindu Kush events

Small-scale elastic heterogeneities (<5  km) are found in the upper lithosphere underneath the Gräfenberg array, southeast Germany. The results are based on the analysis of broadband recordings of 17 intermediate-depth (201–272  km) events from the Hindu Kush region. The wavefront of the first P arrival and the following 40  s coda are separated into coherent and incoherent (scattered) parts in the frequency range from 0.05 to 5  Hz. The frequency-dependent intensities of the mean and fluctuation wavefields are used to describe the scattering characteristics of the lithosphere underneath the receivers. It is possible to discriminate a weak-fluctuation regime of the wavefield in the frequency range below approximately 1.5–2.5  Hz and a strong-fluctuation regime starting at 2.0–2.5  Hz and continuing to higher frequencies. In order to explain the observed wavefield fluctuations, an approach with seismic scattering at random media-type structures is proposed. The preferred model contains heterogeneities with 3–7 per cent perturbations in seismic velocity and correlation lengths of 0.6–4.8  km in the crust. This is compatible with models from active seismic experiments. Scattering in the lithospheric mantle is not required, but cannot be excluded at weak velocity contrasts (<3 per cent).     

Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.     

The atmospheric heat budget over the western part of the Tibetan plateau during Monex, 1979

The atmospheric heat source strength over western Tibet has been computed for the period beginning with the last ten days in May, 1979 and extending through August, 1979. Our results show a significantly smaller heat source than that obtained by other authors. The discrepancy is mainly due to adjustments in the dray, coefficient suggested by observations and numerical modeling experiments. We subdivided western Tibet into northern and southern parts. In the north sensible heating, SH, provides the dominant input into the atmospheric heat source, whereas in the southern part latent heat, LP, offers a significant contribution after the start of the rainy season.Detailed heat budget calculations were also carried out over limited regions of southwestern Tibet which hau good station coverage. During periods with area-averaged rainfall ≤1 mm/day an atmospheric heat source maximum was located over southwestern Tibet near the 500 hPa level, while a heat sink dominated the upper troposphere in a layer of subsidence. When rainfall exceeded 4 mm/day, ascending motions and heal sources prevailed throughout the troposphere with maxima near 400 hPa. Time series analyses of the heat sourcs components show that the total atmospheric heat source is strongly modulated by the release of latent heat. Atmospheric radiational cooling reveals a phase shift in its relation with precipitation. During the first part of the observation period a correlation of that cooling exists mainly with the net radiation at the top of the atmosphere, during the last part with the net radiation at the ground.     

40Ar-39Ar Ages of Types 3 and 4, L and H Chondrites from Antarctica

Abstract— This is a report on ⁴⁰Ar-³⁹Ar studies of 7 low petrographic type L and H chondrites from Antarctica. From petrographic similarities it has been argued that the L3 chondrites ALHA77015, ?77167, ?77249, and ?77260 are pieces from a common fall (McKinley et al., 1981). Our results now confirm this supposition: The four meteorites have identical characteristic Ar-degassing patterns, very similar K, Ca, Cl, and ³⁶Ar_trapped contents, and similar ⁴⁰Ar-³⁹Ar ages of <4 Ga which are rather unusual for ordinary chondrites and might be due to shock. The undulating age patterns could be due to weathering or to ³⁹Ar recoil. The L4 chondrite ALHA77230 shows no age plateau and only a lower limit for the time of a severe degassing, 4.0 Ga, can be given. ALHA77226 and RKPA78002, two H4 chondrites, exhibit reasonably well defined age plateaus at about 4.3 and 4.4 Ga. Two individual chondrules from RKPA78002 have the same age as the whole rock sample.     

Combination of multi-mission altimetry data along the Mekong River with spatio-temporal kriging

River water-level time series at fixed geographical locations, so-called virtual stations, have been computed from single altimeter crossings for many years. Their temporal resolution is limited by the repeat cycle of the individual altimetry missions. The combination of all altimetry measurements along a river enables computing a water-level time series with improved temporal and spatial resolutions. This study uses the geostatistical method of spatio-temporal ordinary kriging to link multi-mission altimetry data along the Mekong River. The required covariance models reflecting the water flow are estimated based on empirical covariance values between altimetry observations at various locations. In this study, two covariance models are developed and tested in the case of the Mekong River: a stationary and a non-stationary covariance model. The proposed approach predicts water-level time series at different locations along the Mekong River with a temporal resolution of 5 days. Validation is performed against in situ data from four gauging stations, yielding RMS differences between 0.82 and 1.29 m and squared correlation coefficients between 0.89 and 0.94. Both models produce comparable results when used for combining data from Envisat, Jason-1, and SARAL for the time period between 2002 and 2015. The quality of the predicted time series turns out to be robust against a possibly decreasing availability of altimetry mission data. This demonstrates that our method is able to close the data gap between the end of the Envisat and the launch of the SARAL mission with interpolated time series.     

Global fossil energy markets and climate change mitigation – an analysis with REMIND

We analyze the dynamics of global fossil resource markets under different assumptions for the supply of fossil fuel resources, development pathways for energy demand, and climate policy settings. Resource markets, in particular the oil market, are characterized by a large discrepancy between costs of resource extraction and commodity prices on international markets. We explain this observation in terms of (a) the intertemporal scarcity rent, (b) regional price differentials arising from trade and transport costs, (c) heterogeneity and inertia in the extraction sector. These effects are captured by the REMIND model. We use the model to explore economic effects of changes in coal, oil and gas markets induced by climate-change mitigation policies. A large share of fossil fuel reserves and resources will be used in the absence of climate policy leading to atmospheric GHG concentrations well beyond a level of 550 ppm CO₂-eq. This result holds independently of different assumptions about energy demand and fossil fuel availability. Achieving ambitious climate targets will drastically reduce fossil fuel consumption, in particular the consumption of coal. Conventional oil and gas as well as non-conventional oil reserves are still exhausted. We find the net present value of fossil fuel rent until 2100 at 30tril.US$ with a large share of oil and a small share of coal. This is reduced by 9 and 12tril.US$ to achieve climate stabilization at 550 and 450 ppm CO₂-eq, respectively. This loss is, however, overcompensated by revenues from carbon pricing that are 21 and 32tril.US$, respectively. The overcompensation also holds under variations of energy demand and fossil fuel supply.     

Sub-B″ layering in the Southern Caribbean: The Aruba Gap and Venezuela Basin

Multichannel seismic data in the Aruba Gap region near JOIDES/DSDP Site 153 verify the presence of a deep sub-B″ reflection. One multichannel seismic line trends NE-SW on and along the edge of Beata Ridge and passes within 1 km of Site 153, and another line runs N-S across the entire Aruba Gap with the drill site 4 km east from its northern end. Closely spaced velocity analyses indicate the presence of deep primary reflection events and enable calculation of interval velocities between the A″-B″ marker horizons. Deconvolved, true amplitude, normal incidence profiles sharply delineate the A″-B″ marker horizons and indicate the presence of the sub-B″ reflection event. On the NE-SW line, this deep reflector is best described as a “diffuse” discontinuous zone, relatively horizontal, lying about 0.8 seconds of two-way travel time below the B″ reflector, with an interval velocity of approximately 5.0 km/s between Horizon B″ and this reflection. The N-S line is more complex since the sub-B′' reflection event is masked by a strong internal multiple from the A″-B″ interval. In the central and western Venezuela Basin, deep primary reflections beneath Horizon B″ are also observed on the northern and western sides of what appears to be a major fault zone. This fault zone separates the smooth B″ and sub-B″ reflectors on the northern and western sides of this fault zone from what appears to be typical oceanic basement. The widespread presence of sub-B″ reflections yielding high interval velocities for the section between these events and Horizon B″ suggest that this material is probably igneous in origin.