The use of acidimetric titration as a novel approach to study particulate trace metal speciation and mobility: Application to sediments of the Scheldt estuary

The study of trace metal speciation has benefited from a great deal of interest leading to the development and the diversification of sequential extraction schemes (SES), which triggered the need for harmonization by the standard, measurements and testing programme (SM & T). However, some uncertainties still persist in the application of the harmonized 3-step protocol, because of the difficulty in conceptualizing a technique that can be applied to environmental samples irrespective of their nature. The alternative method proposed in this study is based on the solubility of the sample components progressively dissolved during the course of an acidimetric titration by 1 mol L⁻¹ HCl. The major HCl-reactive mineralogical components are identified using mass balance calculation of H⁺ consumed by their dissolution together with the amount of major elements released into solution. The speciation of minor and trace elements is investigated by comparing their titrations to those of the major elements. This approach is much simpler than SES because it uses simple non-selective H⁺ at room temperature instead of a complex experimental design of so-called specific reagents. The different mineral components of the solid are no longer operationally defined and the problem of selectivity is irrelevant to the titration approach. The method was applied to several sediment samples from the Scheldt estuary and the particulate phase was further examined by Scanning Electron Microprobe and X-ray Diffraction techniques. The nearly complete consumption of H⁺ in the suspension is balanced by the total dissolution of carbonates and Fe-oxyhydroxides. In contrast to the speciation inferred from the Tessier SES, the acidimetric titration has demonstrated that the carbonate phase does not significantly contain trace metals with the exceptions of 40% of the Mn and 30% of the Co. In contrast, the Fe-oxyhydroxides seem to play a major role and account for 70% of Pb and 20% of Cr, in addition to 60% of P and additional amounts of 20% Co and 40% Mn. 70% of the Cu also occur in the oxyhydroxide phase, more likely coprecipitated with gibbsite. 90% of the Cd and 85% of Zn can be attributed to the Acid Volatile Sulfide (AVS) phase as evidenced from S titration. The acidimetric titration method not only provides information on the speciation of trace metals but also allows the quantification of their reactivity and mobility, if one considers that the titration roughly mimics pH changes that may occur as a result of chemical disequilibrium in the environment. The results demonstrate the potential of the acidimetric titration as an alternative to SES protocols in geochemical and environmental regulation studies. This method is applicable to a wide variety of environmental materials with little or minor adjustments.     

Impact of Earth radiation pressure on GPS position estimates

GPS satellite orbits available from the International GNSS Service (IGS) show a consistent radial bias of up to several cm and a particular pattern in the Satellite Laser Ranging (SLR) residuals, which are suggested to be related to radiation pressure mismodeling. In addition, orbit-related frequencies were identified in geodetic time series such as apparent geocenter motion and station displacements derived from GPS tracking data. A potential solution to these discrepancies is the inclusion of Earth radiation pressure (visible and infrared) modeling in the orbit determination process. This is currently not yet considered by all analysis centers contributing to the IGS final orbits. The acceleration, accounting for Earth radiation and satellite models, is introduced in this paper in the computation of a global GPS network (around 200 IGS sites) adopting the analysis strategies from the Center for Orbit Determination in Europe (CODE). Two solutions covering 9 years (2000–2008) with and without Earth radiation pressure were computed and form the basis for this study. In previous studies, it has been shown that Earth radiation pressure has a non-negligible effect on the GPS orbits, mainly in the radial component. In this paper, the effect on the along-track and cross-track components is studied in more detail. Also in this paper, it is shown that Earth radiation pressure leads to a change in the estimates of GPS ground station positions, which is systematic over large regions of the Earth. This observed “deformation” of the Earth is towards North–South and with large scale patterns that repeat six times per GPS draconitic year (350 days), reaching a magnitude of up to 1 mm. The impact of Earth radiation pressure on the geocenter and length of day estimates was also investigated, but the effect is found to be less significant as compared to the orbits and position estimates.     

Impacts of primary deforestation upon limestone slopes in northern Vancouver Island, British Columbia

Effects of deforestation upon slopes in limestones and in volcanic rocks in the Benson River valley, northern Vancouver Island, have been investigated quantitatively. Postlogging soil erosion and vegetal regeneration success were assessed by measuring soil depth, percent bare rock and moss cover, and the numbers and diversity of trees, shrubs, and plants on 25 sampling sites, each containing ten measuring quadrats selected at random. Sixteen sites were on the Quatsino Formation, a well-karstified limestone, and nine on the Karmutsen Formation of basaltic lavas. Eight sites were of virgin forest, 16 were logged between 1970 and 1983, and one (on limestone) was logged in 1911. Both bedrock types were significantly affected by the cutting. There was greater loss of soil and an increase in bare rock on the limestones. Erosion was increased significantly by burning on the limestones but not on the volcanics. Within-group comparisons on the limestones determined that steeper slopes and harder burned areas suffered the most and are slowest to regenerate. Volume of timber on the 1911 site was 19 percent of that in similar uncut forest sites. It appears that complete recovery on the barren limestone slopes will require at least some centuries.     

On the Occurrence of Zellia from the Maping Limestone of Chengkung, Central Yunnan

INTRODUCTIONThe specimens described in the present paper were collected in 1939 by the late Mr. T. Y. Hsu and Mr. C. S. Pien from the Maping limestone exposed E of Tuikoshan, Chengkung district, Central Yunnan. All specimens belong to Zellia, a subgenus of Pseudoschwagerina; three forms may be referred to known subspecies while two are new.     

The development of three-dimensional current system during a magnetospheric substorm

It is suggested that the pattern of three-dimensional substorm current circuit varies significantly even during the lifetime of a single substorm. This gives rise to quite complex time variations of the magnetic field at low latitude stations even for relatively isolated substorms. To verify this, three-dimensional current models with time dependent spatial variations are used to simulate one type of complex low-latitude “substorm signature”. It is shown that the utmost care should be exercised in determining different substorm phases on the basis of such a signature. The results indicate also that, in certain longitudes in the evening sector, one should expect distinct differences in characteristics between positive bays observed on the ground and at the synchronous distance.     

Tectonics of southwestern Mexico,isotopic evidence,nuclear Central America,Late Cretaceous break up

In the paleogeographic reconstruction of Mexico and northern Central America, an ever-increasing amount of evidence shows that the entire region is a collage of suspect terranes transported from abroad, whose timing and sense of motion are now beginning to be understood. Among these, the Chortis block (nuclear Central America) and the Baja California Peninsula have been proposed as pieces of continent separated from the Pacific coast of southwestern Mexico, that have moved either southeastward by the Farallon plate or northwestward by the Kula plate. Previous studies mainly confined to the northern margin of the Chortis block, confirmed a left-lateral displacement of 130 km in Neogene time. Further studies made northwestward along the Mexican coast provided a better understanding of magmatic and metamorphic processes in the area, and suggested times of detachment increased to 30 Ma, 40 Ma, and 66 Ma. The pre-detachment westernmost position of the block has changed, depending on the model chosen, from Puerto Vallarta and beyond, to the current position. Here we show that the isotopic mineral ages from coastal granites along the coast from Puerto Vallarta, Jalisco (80 Ma) to Puerto Angel, Oaxaca (11 Ma) record systematic decrease of cooling ages from NW to SE. This pattern is interpreted to result from the progressive uplift of rocks exposed at the present-day coast in that direction, such uplift occurred in response to the development of the Middle America Trench at the newly formed continental margin when the Chortis block was sliding at an average rate of 1.5 cm/year in a sinistral sense to its present position. Our results also constrain the position of the Kula-Farallon spreading axis north of Puerto Vallarta. These observations led us to conclude that several indicators point to this time and region for the onset of strike-slip drifting of the Chortis block toward its current position. Here, we also present several view points in terms of other possilble interpretations to different tectonic, geologic and isotopic data sets published recently by different authors.     

ON THE GENERATION OF P AND S WAVE ENERGY IN CRYSTALLINE ROCKS*

A seismic source consisting of a 700 kg weight that could be dropped vertically or projected down a ramp inclined at 45° to the vertical was tested as a source of P, SV and SH waves within a crystalline rock body at Chalk River, Ontario. The seismic energy was recorded by arrays of both horizontal and vertical-component geophones at distances between 30 and 600 m from the source, which was operated over glacial overburden varying in thickness from less than a meter to a few tens of meters. Seismic energy was more efficiently generated when the overburden thickness was at least several meters. The signals identified visually as S are generally true S, though some may be the converted wave PS. The SV amplitudes are generally larger than those of P, regardless of the type of shot, while the signal frequencies are roughly 60 Hz and 90 Hz, respectively. The horizontal-component seismograms for the inclined shots showed no evidence of SH polarization, and the SH amplitudes were only rarely enhanced relative to P and SV amplitudes on changing from vertical to inclined shots. These unexpected results are attributed to the combined effect of the high velocity and density contrasts and the irregularity of the boundary between the glacial overburden and the rock body.