哈萨克斯坦麦卡因矿床火山岩地球化学、U-Pb年代学和Lu-Hf同位素及意义

麦卡因大型VMS型Au-Ag-Cu-Zn-Pb矿床位于中哈萨克斯坦西北部的Baidaulet-Akbastau地区。地质剖面测量和岩石薄片研究表明,麦卡因矿区发育中基性火山岩(玄武岩和安山岩)和次火山岩(辉绿-辉长岩和辉绿岩),矿化主要与安山岩有关。对矿区火山岩地球化学分析表明,矿区岩石分为两种类型:类型Ⅰ为拉斑-钙碱性系列中基性火山岩(玄武岩和安山岩)和次火山岩(辉绿-辉长岩和辉绿岩),岩石具平坦的稀土配分模式,亏损Nb和富集Th/Yb,显示俯冲特点;类型Ⅱ为钙碱性系列安山岩,具典型的右倾型稀土配分模式,亏损Nb和富集Th/Yb,指示其形成于岛弧环境。含矿岩石为类型Ⅱ安山岩。对类型Ⅱ安山岩进行了锆石Lu-Hf同位素和SIMS U-Pb年龄分析,结果表明,锆石εHf(t)为较高的正值(+4.28~+14.84),指示其是地幔物质部分熔融的产物,锆石SIMS U-Pb年龄为459.1±4.8Ma,指示其成岩年龄属于晚奥陶世。因此,哈萨克斯坦麦卡因大型VMS型矿床含矿火山岩为钙碱性系列安山岩,形成于晚奥陶世岛弧环境。对比研究认为,哈萨克斯坦早古生代波谢库尔-成吉思斑岩型-VMS型成矿带向东延伸到我国西准噶尔沙尔布提山,沙尔布提山具有形成VMS型矿床的岩浆条件和构造环境。     

Compositional variability on the surface of 1 Ceres revealed through GRaND measurements of high‐energy gamma rays

High‐energy gamma rays (HEGRs) from Ceres’s surface were measured using Dawn's Gamma Ray and Neutron Detector (GRaND). Models of cosmic‐ray‐initiated gamma ray production predict that the HEGR flux will inversely vary with single‐layer hydrogen concentrations for Ceres‐like compositions. The measured data confirm this prediction. The hydrogen‐induced variations in HEGR rates were decoupled from the measurements by detrending the HEGR data with Ceres single‐layer hydrogen concentrations determined by GRaND neutron measurements. Models indicate that hydrogen‐detrended HEGR counting rates correlate with water‐free average atomic mass, which is denoted as <A>*. HEGR variations across Ceres’s surface are consistent with <A>* variations of ±0.5 atomic mass units. Chemical variations in the CM and CI chondrites, our closest analogs to Ceres’s surface, suggest that <A>* variations on Ceres are primarily driven by variations in the concentration of Fe, although other elements such as Mg and S could contribute. Dawn observations have shown that Ceres’s interior structure and surface composition have been modified by some combination of physical (i.e., ice‐rock fractionation) and/or chemical (i.e., alteration) processes that has led to variations in bulk surface chemistry. Locations of the highest inferred <A>* values, and thus possibly the highest Fe and least altered materials, tend to be younger, less cratered surfaces that are broadly associated with the impact ejecta of Ceres’s largest craters.     

Ambient and cold‐temperature infrared spectra and XRD patterns of ammoniated phyllosilicates and carbonaceous chondrite meteorites relevant to Ceres and other solar system bodies

Mg‐phyllosilicate‐bearing, dark surface materials on the dwarf planet Ceres have NH₄‐bearing materials, indicated by a distinctive 3.06 μm absorption feature. To constrain the identity of the Ceres NH₄‐carrier phase(s), we ammoniated ground particulates of candidate materials to compare their spectral properties to infrared data acquired by Dawn's Visible and Infrared (VIR) imaging spectrometer. We treated Mg‐, Fe‐, and Al‐smectite clay minerals; Mg‐serpentines; Mg‐chlorite; and a suite of carbonaceous meteorites with NH₄‐acetate to exchange ammonium. Serpentines and chlorites showed no evidence for ammoniation, as expected due to their lack of exchangeable interlayer sites. Most smectites showed evidence for ammoniation by incorporation of NH₄⁺ into their interlayers, resulting in the appearance of absorptions from 3.02 to 3.08 μm. Meteorite samples tested had weak absorptions between 3.0 and 3.1 μm but showed little clear evidence for enhancement upon ammoniation, likely due to the high proportion of serpentine and other minerals relative to expandable smectite phases or to NH₄⁺ complexing with organics or other constituents. The wavelength position of the smectite NH₄ absorption showed no variation between IR spectra acquired under dry‐air purge at 25 °C and under vacuum at 25 °C to ?180 °C. Collectively, data from the smectite samples show that the precise center wavelength of the characteristic ~3.05 μm v₃ absorption in NH₄ is variable and is likely related to the degree of hydrogen bonding of NH₄‐H₂O complexes. Comparison with Dawn VIR spectra indicates that the hypothesis of Mg‐saponite as the ammonium carrier phase is the simplest explanation for observed data, and that Ceres dark materials may be like Cold Bokkeveld or Tagish Lake but with proportionally more Mg‐smectite.     

Deep‐water Corallium rubrum (L., 1758) from the Mediterranean Sea: preliminary genetic characterisation

The precious red coral Corallium rubrum (L., 1758) lives in the Mediterranean Sea and adjacent Eastern Atlantic Ocean on subtidal hard substrates. Corallium rubrum is a long‐lived gorgonian coral that has been commercially harvested since ancient times for its red axial calcitic skeleton and which, at present, is thought to be in decline because of overexploitation. The depth distribution of C. rubrum is known to range from c. 15 to 300 m. Recently, live red coral colonies have been observed in the Strait of Sicily at depths of c. 600–800 m. This record sheds new light on the ecology, biology, biogeography and dispersal mechanism of this species and calls for an evaluation of the genetic divergence occurring among highly fragmented populations. A genetic characterization of the deep‐sea red coral colonies has been done to investigate biological processes affecting dispersal and population resilience, as well as to define the level of isolation/differentiation between shallow‐ and deep‐water populations of the Mediterranean Sea. Deep‐water C. rubrum colonies were collected at two sites (south of Malta and off Linosa Island) during the cruise MARCOS of the R/V Urania. Collected colonies were genotyped using a set of molecular markers differing in their level of polymorphism. Microsatellites have been confirmed to be useful markers for individual genotyping of C. rubrum colonies. ITS‐1 and mtMSH sequences of deep‐water red coral colonies were found to be different from those found in shallow water colonies, suggesting the possible occurrence of genetic isolation among shallow‐ and deep‐water populations. These findings suggest that genetic diversity of red coral over its actual range of depth distribution is shaped by complex interactions among geological, historical, biological and ecological processes.     

Major and Trace Element Characteristics of Apatites in Granitoids from Central Kazakhstan: Implications for Petrogenesis and Mineralization

This paper presents abundances of major and trace elements of apatites in granitic rocks associated with different types of ore deposits in Central Kazakhstan on the basis of electron probe microanalysis and laser ablation inductively coupled plasma mass spectrometry. Our results demonstrate that the concentrations and ratios of elements in apatites from different granitoid rocks show distinct features, and are sensitive to magma evolution, petrogenetic and metallogenetic processes. Apatites in the rocks associated with Mo‐W deposits have high content of F and MnO, low content of Cl, which may be indicative of sedimentary sources, while apatites from a Pb‐Zn deposit show relatively high content of Cl and low F content, which possibly suggest a high water content. In these apatites, Sr contents decrease, while Mn and Y contents increase with magma evolution. This relationship reflects that these elements in apatites are related with the degree of magmatic differentiation. Four types of REE patterns in apatites are identified. Type 1 character of highest (La/Yb)_N in apatites of Aktogai porphyry Cu‐Mo deposit, Sayak‐I skarn Cu deposit and Akzhal skarn Pb‐Zn depposit is likely produced by the crystallization of heavy REE‐enriched minerals. Type 2 character of upward‐convex light REE in apatite of Aktogai porphyries likely results from La‐enriched mineral crystallization. Type 3 feature of Nd depletion in apatites of East Kounrad and Zhanet deposits both from Mo‐W deposits primarily inherits the character of host‐rock. Type 4 apatites of Aktogai deposit and Akshatau W‐Mo deposit with wide range of REE contents may suggest that apatites crystallize under a wide temperature range. Three types of apatite with distinct redox states are identified based on Eu anomaly. The Aktogai apatite with slight negative Eu anomaly displays the most oxidized state of the magma, and the apatites of other samples at Aktogai, East Kounrad and Akzhal with moderate negative Eu anomaly show moderate oxidizing condition of these rocks, while the remaining apatites with strong En anomaly indicate a moderate reductive state of these rocks.     

Vesta's mineralogical composition as revealed by the visible and infrared spectrometer on Dawn

The Dawn spacecraft mission has provided extensive new and detailed data on Vesta that confirm and strengthen the Vesta–howardite–eucrite–diogenite (HED) meteorite link and the concept that Vesta is differentiated, as derived from earlier telescopic observations. Here, we present results derived by newly calibrated spectra of Vesta. The comparison between data from the Dawn imaging spectrometer—VIR—and the different class of HED meteorites shows that average spectrum of Vesta resembles howardite spectra. Nevertheless, the Vesta spectra at high spatial resolution reveal variations in the distribution of HED‐like mineralogies on the asteroid. The data have been used to derive HED distribution on Vesta, reported in Ammannito et al. (2013), and to compute the average Vestan spectra of the different HED lithologies, reported here. The spectra indicate that, not only are all the different HED lithologies present on Vesta, but also carbonaceous chondritic material, which constitutes the most abundant inclusion type found in howardites, is widespread. However, the hydration feature used to identify carbonaceous chondrite material varies significantly on Vesta, revealing different band shapes. The characteristic of these hydration features cannot be explained solely by infalling of carbonaceous chondrite meteorites and other possible origins must be considered. The relative proportion of HEDs on Vesta's surface is computed, and results show that most of the vestan surface is compatible with eucrite‐rich howardites and/or cumulate or polymict eucrites. A very small percentage of surface is covered by diogenite, and basaltic eucrite terrains are relatively few compared with the abundance of basaltic eucrites in the HED suite. The largest abundance of diogenitic material is found in the Rheasilvia region, a deep basin, where it clearly occurs below a basaltic upper crust. However, diogenite is also found elsewhere; although the depth to diogenite is consistent with one magma ocean model, its lateral extent is not well constrained.     

A probabilistic approach for the classification of earthquakes as ��triggered�� or ��not triggered��

The occurrence time of earthquakes can be anticipated or delayed by external phenomena that induce strain energy changes on the faults. ??Anticipated?? earthquakes are generally called ??triggered??; however, it can be controversial to label a specific earthquake as such, mostly because of the stochastic nature of earthquake occurrence and of the large uncertainties usually associated to stress modelling. Here we introduce a combined statistical and physical approach to quantify the probability that a given earthquake was triggered by a given stress-inducing phenomenon. As an example, we consider an earthquake that was likely triggered by a natural event: the M?=?6.2 13 Jan 1976 Kópasker earthquake on the Grímsey lineament (Tj?rnes Fracture Zone, Iceland), which occurred about 3?weeks after a large dike injection in the nearby Krafla fissure swarm. By using Coulomb stress calculations and the rate-and-state earthquake nucleation theory, we calculate the likelihood of the earthquake in a scenario that contains only the tectonic background and excludes the dike and in a scenario that includes the dike but excludes the background. Applying the Bayes?? theorem, we obtain that the probability that the earthquake was indeed triggered by the dike, rather than purely due to the accumulation of tectonic strain, is about 60 to 90?%. This methodology allows us to assign quantitative probabilities to different scenarios and can help in classifying earthquakes as triggered or not triggered by natural or human-induced changes of stress in the crust.     

Becoming a creative city: perspectives from Augustus’ Rome

The creative city discourse has been shaping cultural policy worldwide. Among the multifaceted goals highlighted by scholars, one aspect that is not thoroughly emphasized is the understanding of creative cities in terms of culture-centric approaches to foster city cohesion. In this paper, I study the value of focusing the idea of the creative city to integrate diverse communities in a historic context: the city of Rome during the reign of Augustus. The aim is to provide a broader historic frame of reference to better articulate the function of the creative city discourse. Through the analysis of primary and secondary literature in Ancient Studies, I highlight three aspects of Augustus’ remaking of Rome: integration, spectacles, and beauty. From these aspects, what emerges is the idea of a creative city as a vital and spectacular place that offers access to arts and culture involving the diversity of the population, presenting a wide range of art forms, and enhancing the beauty of the built space.     

Unraveling the hidden origin and migration of plagioclase phenocrysts by in situ Sr isotopes: the case of final dome activity at Nisyros volcano,Greece

This contribution reports a detailed study on in situ Sr isotope analyses, along with textural and compositional characteristics, of plagioclase phenocrysts occurring in the rhyodacitic dome-lavas and associated mafic enclaves, erupted during the last magmatic activity at Nisyros volcano (Greece). Dome-lavas and enclaves have a paragenesis dominated by plagioclase. We recognize five different types of plagioclase based on their specific textures and composition. Dome-lava plagioclases (Type-1) are mainly large (1–5 mm), subhedral, clear, and poorly zoned crystals with low An content (An_25–35). The plagioclase phenocrysts (Type-4 and Type-5) and groundmass microlites crystallizing in the enclaves, and found in dome-lavas as xenocrysts, have high An content (An_75–95). In both dome-lavas and enclaves, two other types of plagioclase do also occur: (1) plagioclase phenocrysts with size and core composition similar to those of Type-1 having a dusty sieve zone (DSZ) at the rims (Type-2); (2) plagioclases with a DSZ affecting the entire crystal but a thin rim (Type-3). The drilled plagioclases have ⁸⁷Sr/⁸⁶Sr negatively correlated with their An content. Low An cores of Type-1 and Type-2 have quite homogeneous ⁸⁷Sr/⁸⁶Sr (0.7044–0.7046), whose values are more radiogenic than their host magmas (0.70403–0.70408) and similar to those of the previous Upper Pumice (UP) rhyolite magma (0.70438–0.70456). The DSZs of Type-2 and Type-3 show lower and scattered ⁸⁷Sr/⁸⁶Sr (0.70397–0.70426) with intermediate and variable An content. High An cores of Type-4 and Type-5 have the least radiogenic Sr isotope composition (0.70379) in equilibrium with that measured in the enclaves (0.70384–0.70389). We demonstrate that Type-1 plagioclase crystallizes in the previous UP rhyolitic magmas representing the silica-rich magma from which the dome-lava melts derived by open system evolutionary processes (e.g., mixing, mingling, and crystal migration), caused by successive refilling of mafic enclave-forming magma. The Type-2 plagioclase derives from entrainment of Type-1 into the still molten enclave magma. The DSZs originated in response to the interaction between the low An plagioclase and the enclave mafic melt in which dissolution and re-crystallization acted together as function of the interaction time. Type-1 and Type-2 plagioclases record, therefore, a long-lived timescale of events starting from their crystallization in the UP rhyolite. Instead, the different width of DSZs (Type-2 and Type-3) seems to indicate short different interaction timescales between the single crystals and the enclave melt (from few hours to some 40 days). These microanalytical data contribute to the understanding of the origin of the rhyodacitic dome-lavas at Nisyros volcano and to set robust constraints on the dynamics of mingling/mixing processes in terms of crystal exchange pathways and enclave disaggregation.     

Olivine or impact melt: Nature of the “Orange” material on Vesta from Dawn

NASA’s Dawn mission observed a great variety of colored terrains on asteroid (4) Vesta during its survey with the Framing Camera (FC). Here we present a detailed study of the orange material on Vesta, which was first observed in color ratio images obtained by the FC and presents a red spectral slope. The orange material deposits can be classified into three types: (a) diffuse ejecta deposited by recent medium-size impact craters (such as Oppia), (b) lobate patches with well-defined edges (nicknamed “pumpkin patches”), and (c) ejecta rays from fresh-looking impact craters. The location of the orange diffuse ejecta from Oppia corresponds to the olivine spot nicknamed “Leslie feature” first identified by Gaffey (Gaffey, M.J. [1997]. Icarus 127, 130–157) from ground-based spectral observations. The distribution of the orange material in the FC mosaic is concentrated on the equatorial region and almost exclusively outside the Rheasilvia basin. Our in-depth analysis of the composition of this material uses complementary observations from FC, the visible and infrared spectrometer (VIR), and the Gamma Ray and Neutron Detector (GRaND). Several possible options for the composition of the orange material are investigated including, cumulate eucrite layer exposed during impact, metal delivered by impactor, olivine–orthopyroxene mixture and impact melt. Based on our analysis, the orange material on Vesta is unlikely to be metal or olivine (originally proposed by Gaffey (Gaffey, M.J. [1997]. Icarus 127, 130–157)). Analysis of the elemental composition of Oppia ejecta blanket with GRaND suggests that its orange material has ∼25% cumulate eucrite component in a howarditic mixture, whereas two other craters with orange material in their ejecta, Octavia and Arruntia, show no sign of cumulate eucrites. Morphology and topography of the orange material in Oppia and Octavia ejecta and orange patches suggests an impact melt origin. A majority of the orange patches appear to be related to the formation of the Rheasilvia basin. Combining the interpretations from the topography, geomorphology, color and spectral parameters, and elemental abundances, the most probable analog for the orange material on Vesta is impact melt.