Temporal and geochemical evolution of the Cenozoic intraplate volcanism of Zealandia

In order to constrain better the distribution, age, geochemistry and origin of widespread Cenozoic intraplate volcanism on Zealandia, the New Zealand micro-continent, we report new ⁴⁰Ar/³⁹Ar and geochemical (major and trace element and Sr–Nd–Hf–Pb isotope) data from offshore (Chatham Rise, Campbell and Challenger Plateaus) and onland (North, South, Auckland, Campbell, Chatham and Antipodes Islands of New Zealand) volcanism on Zealandia. The samples include nephelinite, basanite through phonolite, alkali basalt through trachyte/rhyolite, and minor tholeiite and basaltic andesite, all of which have ocean island basalt (OIB)-type trace element signatures and which range in age from 64.8 to 0.17 Ma. Isotope ratios show a wide range in composition (⁸⁷Sr/⁸⁶Sr = 0.7027–0.7050, ¹⁴³Nd/¹⁴⁴Nd = 0.5128–0.5131, ¹⁷⁷Hf/¹⁷⁶Hf = 0.2829–0.2831, ²⁰⁶Pb/²⁰⁴Pb = 18.62–20.67, ²⁰⁷Pb/²⁰⁴Pb = 15.54–15.72 and ²⁰⁸Pb/²⁰⁴Pb = 38.27–40.34) with samples plotting between mid-ocean-ridge basalts (MORB) and Cretaceous New Zealand intraplate volcanic rocks.Major characteristics of Zealandia's Cenozoic volcanism include longevity, irregular distribution and lack of age progressions in the direction of plate motion, or indeed any systematic temporal or spatial geochemical variations. We believe that these characteristics can be best explained in the context of lithospheric detachment, which causes upwelling and melting of the upper asthenospheric mantle and portions of the removed lithosphere. We propose that a large-scale seismic low-velocity anomaly, that stretches from beneath West Antarctica to Zealandia at a depth of > 600 km may represent a geochemical reservoir that has been in existence since the Cretaceous, and has been supplying the upper mantle beneath Zealandia with HIMU-type plume material throughout the Cenozoic. In addition, the sources of the Cenozoic intraplate volcanism may be at least partially derived through melting of locally detached Zealandia lower lithosphere.     

Oxidative pre-treatment in thiosulphate leaching of sulphide gold ores

A diagnostic leaching showed that partial oxidation of the sulphide minerals in a gold ore was beneficial for thiosulphate leaching of gold. A pre-treatment process with oxidative ammoniacal solution enhanced the thiosulphate leaching of the sulphide ore, while the thiosulphate consumption was substantially reduced. The sulphide minerals partially decomposed in the pre-treatment process, exposing gold to the leach solution. Oxygen input by air bubbling and a longer contact time enhanced the oxidative ammonia pre-treatment process and hence accelerated subsequent thiosulphate leaching of the sulphide ore. Gold extraction in 0.8 M ammonia and 0.1 M thiosulphate solution after 24 h increased from 69% without pre-treatment to 81%, 84%, 90% and 94% respectively after 1, 3, 7 and 22 h pre-treatment. The consumption of sodium thiosulphate was 2.37 kg/t after 24 h leaching without pre-treatment, but was negligible after over 1 h oxidative ammonia pre-treatment. A counter-current leaching process was conducted in the leaching of the sulphide ore. The fresh leachant still gave higher leaching rates in contact with the pre-leached ore, while the pre-used leachant had significantly lower leaching kinetics and overall gold extraction in contact with the fresh ore. This 2-step counter-current leaching process proved that the leachant, other than the passivation, was the determinant factor causing the gold leaching rates to decrease after a certain time of leaching. The findings enable the thiosulphate leaching of high sulphide containing gold ores to be more efficient at lower thiosulphate consumption following the oxidative ammoniacal pre-treatment.     

The Late Cretaceous Klepa basalts in Macedonia (FYROM)—Constraints on the final stage of Tethys closure in the Balkans

The waning stage(s) of the Tethyan ocean(s) in the Balkans are not well understood. Controversy centres on the origin and life‐span of the Cretaceous Sava Zone, which is allegedly a remnant of the last oceanic domain in the Balkan Peninsula, defining the youngest suture between Eurasia‐ and Adria‐derived plates. In order to investigate to what extent Late‐Cretaceous volcanism within the Sava Zone is consistent with this model we present new age data together with trace‐element and Sr–Nd–Pb isotope data for the Klepa basaltic lavas from the central Balkan Peninsula. Our new geochemical data show marked differences between the Cretaceous Klepa basalts (Sava Zone) and the rocks of other volcanic sequences from the Jurassic ophiolites of the Balkans. The Klepa basalts mostly have Sr–Nd–Pb isotopic and trace‐element signatures that resemble enriched within‐plate basalts substantially different from Jurassic ophiolite basalts with MORB, BAB and IAV affinities. Trace‐element modelling of the Klepa rocks indicates 2%–20% polybaric melting of a relatively homogeneously metasomatised mantle source that ranges in composition from garnet lherzolite to ilmenite+apatite bearing spinel–amphibole lherzolite. Thus, the residual mineralogy is characteristic of a continental rather than oceanic lithospheric mantle source, suggesting an intracontinental within‐plate origin for the Klepa basalts. Two alternative geodynamic models are internally consistent with our new findings: (1) if the Sava Zone represents remnants of the youngest Neotethyan Ocean, magmatism along this zone would be situated within the forearc region and triggered by ridge subduction; (2) if the Sava Zone delimits a diffuse tectonic boundary between Adria and Europe which had already collided in the Late Jurassic, the Klepa basalts together with a number of other magmatic centres represent volcanism related to transtensional tectonics.     

A flood vulnerability index for coastal cities and its use in assessing climate change impacts

Worldwide, there is a need to enhance our understanding of vulnerability and to develop methodologies and tools to assess vulnerability. One of the most important goals of assessing coastal flood vulnerability, in particular, is to create a readily understandable link between the theoretical concepts of flood vulnerability and the day-to-day decision-making process and to encapsulate this link in an easily accessible tool. This article focuses on developing a Coastal City Flood Vulnerability Index (CCFVI) based on exposure, susceptibility and resilience to coastal flooding. It is applied to nine cities around the world, each with different kinds of exposure. With the aid of this index, it is demonstrated which cities are most vulnerable to coastal flooding with regard to the system??s components, that is, hydro-geological, socio-economic and politico-administrative. The index gives a number from 0 to 1, indicating comparatively low or high coastal flood vulnerability, which shows which cities are most in need of further, more detailed investigation for decision-makers. Once its use to compare the vulnerability of a range of cities under current conditions has been demonstrated, it is used to study the impact of climate change on the vulnerability of these cities over a longer timescale. The results show that CCFVI provides a means of obtaining a broad overview of flood vulnerability and the effect of possible adaptation options. This, in turn, will allow for the direction of resources to more in-depth investigation of the most promising strategies.     

Shape analysis and multispectral classification in geological remote sensing

This paper discusses the usage of mathematical morphology in image processing of remotely-sensed data for geologic interpretation. Particular attention is given to noise-reducing transformations of spectral bands before and after different methods of classification, and to the usage of textural context. The development of a viable processing strategy requires a multidisciplinary approach and expert knowledge in different areas: (a) geology, geomorphology, and vegetation in a study area, (b) properties of the sensor for imagery photointerpretation, (c) spectral/spatial properties of the digital data within an integrated dataset (remote sensing and ancillary data), and (d) data-processing tools including mathematical morphology theory. Examples of geometric characterization of Canadian LANDSAT scenes are described in which shape measurements are obtained using a PC-based hybrid image-processing and geographic information system, termed ILWIS, which was developed at ITC, in the Netherlands. Classes from supervised and unsupervised classification are compared to guide in geological mapping. Classes over individual occurrences of broad vegetation-landform units are studied to aid in environmental mapping. Field knowledge is the context necessary to construct expert procedures to drive sequences of data-processing steps toward a target result such as optimal classification, enhancement, or feature extraction. The interaction between expert rules and the image-processing steps can be based on synthetic measurements of shape to quantize the information either spatially or spectrally. Many useful geometrical transformations of spatially-distributed data are extensions or generalizations of spatial analysis functions typical of geographic information systems.     

Modelling of longterm surface moisture and monitoring vegetation response by satellite in semi-arid Botswana

A daily surface soil moisture model described and tested previously with data from the Phoenix, AR (USA) area, has been applied now to climate data collected in semi-arid Botswana over a multi-year period. The physically based model was calibrated with observed surface moisture data from one growing season and validated with data from another. Good overall agreement (r² = .89) was found between the observed and modelled data. The seasonal variability of precipitation in this region is reflected in the simulated daily surface moisture. The response of the natural savanna vegetation as observed from monthly composites of satellite-derived Normalized Difference Vegetation Index (NDVI) is also monitored for the same period. It is seen that the NDVI peaks at different times during the rainy season from one year to the next, according not only to the total seasonal precipitation, but its temporal distribution as well. It is also seen that there is a delay in intraseasonal vegetation response. While the NDVI is poorly correlated with the current month's average soil moisture, a distinct relationship with the previous month's average soil moisture was found.     

Paläomagnetismus in den Rhombenporphyren von Oslo und in den Rhyoliten,Doleriten und Sedimenten des Estérel

Zusammenfassung Es werden einige Ergebnisse mitgeteilt über paläomagnetische Untersuchungen, die vom Mineralogisch-Geologischen Institut in Utrecht unter Mitarbeit des Königlich-Niederländischen Meteorologischen Instituts in de Bilt durchgeführt werden. Während der Entmagnetisierungsversuche zeigte es sich, daß viele Gesteinsproben neben einer ursprünglichen Magnetisierung, die wahrscheinlich während der Ablagerung entstanden ist, noch störende sekundäre magnetische Komponenten in der Richtung des heutigen Erdfeldes besitzen. Diese sekundären Komponenten kann man ganz durch teilweise Entmagnetisierung entfernen; die ursprüngliche Komponente des Magnetismus wird dabei auch kleiner, aber die Abnahme wird erst bedeutend bei Anwendung von hohen Temperaturen und sehr starken Wechselfeldern. Dadurch werden also auch diese Gesteine brauchbar für die Bestimmung des magnetischen Pols.     

The impact of the parking situation in shopping centres on store choice behaviour

The article discusses the effects of changing the parking situation in the surrounding of shopping centres on consumers store choice behaviour. To get insight into these effects a hierarchical logit model of parking lot and store choice behaviour is estimated and validated. The research is based on before-and-after data of supermarket visitors collected in a major regional shopping centre in a suburban area in The Netherlands. The model is estimated using the before data. At the level of the supermarkets the estimated hierarchical logit model performs very well. The model is less accurate at the level of parking lots but still performs satisfactory. Significant attributes are a constant representing the characteristics of the supermarket, the distance between supermarket and parking lot, the number of parking spaces per parking lot, the location of the parking lot vis-à-vis the origin of the consumer, and the availability of supermarket trolley facilities at the parking lot. Validating the model by reproducing the after data yields less satisfactory results. Especially the model does not perform very well on predicting parking lot choice. This revised version was published online in July 2006 with corrections to the Cover Date.     

Direct terrestrial-marine correlation demonstrates surprisingly late onset of the last interglacial in central Europe

An interdisciplinary study of a small sedimentary basin at Neumark Nord 2 (NN2), Germany, has yielded a high-resolution record of the palaeomagnetic Blake Event, which we are able to place at the early part of the last interglacial pollen sequence documented from the same section. We use this data to calculate the duration of this stratigraphically important event at 3400 ± 350 yr. More importantly, the Neumark Nord 2 data enables precise terrestrial-marine correlation for the Eemian stage in central Europe. This shows a remarkably large time lag of ca. 5000 yr between the MIS 5e ‘peak’ in the marine record and the start of the last interglacial in this region.