Implicit time integration for pseudodynamic tests

The use of unconditionally stable implicit time integration techniques for pseudodynamic tests has been recently proposed and advanced by several researchers. Inspired by such developments, a pseudodynamic test scheme based on an unconditionally stable implicit time integration algorithm and dual displacement control is presented in this paper. The accuracy of the proposed scheme is proved with error-propagation analysis. It is shown by numerical examples and verification tests that the error-correction method incorporated can eliminate the spurious higher-mode response, which can often be excited by experimental errors. The practicality of the proposed scheme lies in the fact that the implementation is as easy as that of explicit schemes and that the convergence criteria required are compatible with the accuracy limits of ordinary test apparatus.     

Determining Paleosol Topography Using Seismic Refraction

The seismic refraction reversed profiling technique has been used to investigate the topography of the last interglacial soil (paleosol S1) within the central Chinese Loess Plateau near Xifeng. The results suggest an essentially flat-lying soil at a depth which varies by only a few meters over an area of more than 10 km². In addition, the results indicate a high-velocity layer at 50-60 m depth which is thought to coincide with a layer of carbonate concretions at the base of paleosol S5. The results agree well with the local loess-paleosol stratigraphy for this area and indicate that the seismic refraction method is a rapid technique for investigating paleotopography.     

H-chondrites: Trace element clues to their origin

We have analyzed 10 H-chondrites for 20 trace elements, using RNAA. The meteorites included 4 of petrologic type 4 and 2 each of types 3, 5 and 6.The data show that H-chondrites are not isochemical. H3's are depleted by some 10% not only in Fe (Dodd, 1976), but also in the siderophiles Os, Re, Ir, Ni, Pd, Au, and Ge. Moreover, the abundance pattern of siderophiles varies systematically with petrologic type. As similar fractionations of REE have been observed by Nakamura (1974), it appears that both the proportions and compositions of the main nebular condensates varied slightly during accretion of the H-chondrites. Thus the higher petrologic types are independent nebular products, not metamorphosed descendants of lower petrologic types.Abundances of highly volatile elements (Cs, Br, Bi, Tl, In, Cd, Ar³⁶) correlate with petrologic type, declining by ≤ 10^?3 from Type 3 to Type 6. The trends differ from those for artificially heated Type 3's (Ikramuddinet al., 1977b; Herzoget al., 1979), but agree passably with theoretical curves for nebular condensation. Apparently the low volatile contents of higher petrologic types are a primary feature, not the result of metamorphic loss.The mineralogy of chondrites suggests that they accreted between 405 K (absence of Fe₃O₄) and 560 K (presence of FeS), and the abundances of Tl, Bi, and In further restrict this interval to 420–500 K. Accretion at 1070 ± 100 K, as proposed by Hutchisonet al. (1979, 1980), leads to some extraordinary problems. Volatiles must be injected into the parent body after cooling, which requires permeation of the body by 10¹¹ times its volume of nebular gas. This process must also achieve a uniform distribution of the less volatile elements (Rb, Cu, Ag, Zn, Ga, Ge, Sn, Sb, Se, F), without freezeout in the colder outer layers.Factor analysis of our data shows 3 groupings: siderophiles (Os, Re, Ir, Ni, Pd, Au, and Ge), volatiles (Ag, Br, In, Cd, Bi, and Tl) and alkalis (Rb and Cs). The remaining 5 elements (U, Zn, Te, Se, and Sb) remain unassociated.     

Eolian evidence for spatial variability of late Quaternary climates in tropical Africa

Study of the eolian fraction of late Quaternary sediments from the tropical Atlantic reveals that two modes of long-term climate variability have existed in tropical Africa during the last 150,000 yr. Tropical northwest Africa (i.e., the southwestern Sahara and Sahel) was driest during glaciations and stades, but wetter than at present during interglaciations and interstades. This may be a response to ice sheets at higher latitudes, via equatorward displacement of the westerlies and the subtropical high. In contrast, central equatorial Africa (southeast of the Sahara) was most arid during interstades and times of ice growth, and most humid during deglaciation. Wet periods in this area correspond to insolation maxima in northern hemisphere summer. A 23,000-yr precessional rhythm is suggested, supporting a direct link between African Monsoon intensity and orbitally modulated insolation. The late Holocene is the only time observed when both areas are arid during an interglacial episode. This may reflect, in part, anthropogenic disturbance of late Holocene climates.     

Variability in estimates of oil contamination in the intertidal zone of a gravel beach

Estimates of the surface cover of stranded oil on a gravel beach ranged between 25 and 51%. This variability is attributed primarily to wet weather conditions that altered the colour of the surface substrate, thus making identification of oil or oiled sediments difficult. Estimates and the observations from three surveys in wet weather ranged between 25 and 46%; whereas on a dry day the range from four surveys was only 42–51%. Within this small study area (7200 m²) the same observer provided estimates of the surface oil cover that ranged from 1800 to 3680 m². This wide variability for a small section of shoreline would probably be magnified during reconnaissance surveys where long sections of coast are surveyed to determine the degree of contamination. Surveys of beach contamination for cleanup decisions or for damage assessment should be conducted with regard to the environmental (weather) conditions and the degree of accuracy that is required from the survey.     

Structure proof and significance of stereoisomeric 28,30-bisnorhopanes in petroleum and petroleum source rocks

Two C₂₈H₄₈-pentacyclic triterpanes were isolated from Monterey shale. X-ray crystallography of a crystal containing both compounds proved their structures as 17β,18α,21α(H)-28,30-bisnorhopane and 17β,18α,21β(H)-28,30-bisnorhopane. Several differences are found between 28,30-bisnorhopanes and the regular hopanes. Unlike the regular hopane epimers, for practical purposes the three epimeric 28,30-bisnorhopanes [17α,21β(H)-, 17β,21α(H)-, and 17β,21β(H)-]cannot be distinguished by their mass spectra. Special conditions are needed to separate them by gas chromatography. The diagenetically first-formed epimer is thought to be 17α,21β(H)- because it predominates in immature shales. The order of thermodynamic stability is 17β,2lα(H) < > 17α,21β(H) > 17β,21β(H), and all three epimers are present in petroleum. 25,28,30-Trisnorhopanes can be analyzed in similar fashion and are found to have similar thermodynamic characteristics. The percent of the ring D/E cis epimer of 28,30-bisnorhopane and/or 25,28,30-trisnorhopane is a useful maturation parameter similar to the 20S/20R sterane ratio. Evidence indicates 25-demethylation of 28,30-bisnorhopane to 25,28,30-trisnorhopane during advanced stages of biodegradation. Hence, percent ring $\text{D}\text{E}$cis 25,28,30-trisnorhopane has an application to maturation assessment in heavily biodegraded oils.