Some observations on the ignimbrites,lava domes and lava flows of M. Cimino (Central Italy)

Cimino Volcano, in Northern Latium, is one of the most characteristic centers of the early Quaternary acid post-orogenetic volcanism in Central Italy. Three stages in the volcanic activity are distinguished: extrusion of several lava domes; ignimbrite cruptions; effusion of more or less differentiated lava flows. Ignimbrites, that form a shield of over 300 sq. km, show characters of welding variable with the distance from the source area and, in a single section, with the level in the sheet. Most part of the Cimino volcanics (domes and ignimbrites) have a quartzlatite composition. The olivine-trachyte (selagite) inclusions in the domes and ignimbrites, and the dark quartz-latite to olivine-trachyte lava flows, could be the products of a pneumatolitic differentiation in the various stages of the magmatic cycle.     

Asymmetric measures of association, closed data, and multivariate analysis

The association between constant-sum variables X_i and X_j expressed as percentages can be calculated as a product-moment correlation between X_i and X_j/(100 – X_i ) and a correlation between X_j and X_i/(100 – X_j ). An asymmetric, square matrix may be formed from these coefficients, and multivariate analysis performed by two methods: singular value decomposition and canonical decomposition. Either analysis avoids problems in the interpretation of correlation coefficients determined from closed arrays, and provides information about dependencies among the variables beyond that obtained from the usual correlation coefficient between X_i and X_j.Two examples show the canonical decomposition to have the greater usefulness.     

Oxidation of fugitive methane in ground water linked to bacterial sulfate reduction

When fugitive methane migrates upward along boreholes of oil and gas wells, it may migrate into shallow ground water or pass through overlying soil to the atmosphere. Prior to this study, there was little information on the fate of fugitive methane that migrates into ground water. In a field study near Lloydminster, Alberta, Canada, we found hydrogeochemical evidence that fugitive methane from an oil well migrated into a shallow aquifer but has been attenuated by dissimilatory bacterial sulfate reduction at low temperature ( approximately 5 degrees C) under anaerobic conditions. Evidence includes spatial and temporal trends in concentrations of methane and sulfate in ground water and associated trends in concentrations of bicarbonate and sulfide. Within 10 m of the oil well, sulfate concentrations were low, and sulfate was enriched in both 34S and 18O. Sulfate concentrations had a strong positive correlation with delta13C values of bicarbonate, and sulfide was depleted in 34S compared to sulfate. These data indicate that bacterial sulfate reduction occurred near the production well. Near the oil well, elevated concentrations of bicarbonate were observed, and the bicarbonate was depleted in 13C. Modeling indicates that the main source of this excess 13C-depleted bicarbonate is oxidized methane. In concert with the sulfate concentration and isotope data, these results support an interpretation that in situ bacterial oxidation of methane has occurred, linked to bacterial sulfate reduction. Bacterial sulfate reduction may play a major role in bioattenuation of fugitive natural gas in ground water in western Canada.     

The magmatic- and hydrothermal-dominated fumarolic system at the Active Crater of Lascar volcano,northern Chile

Low-to-high temperature fumaroles discharging from the Active Crater of Lascar volcano (northern Chile) have been collected in November 2002, May 2005 and October 2006 for chemical and isotopic analysis to provide the first geochemical survey on the magmatic-hydrothermal system of this active volcano. Chemical and isotopic gas composition shows direct addition of high-temperature fluids from magmatic degassing, mainly testified by the very high contents of SO₂, HCl and HF (up to 87,800, 29,500 and 2,900 μmol/mol) and the high R/Ra values (up to 7.29). Contributions from a hydrothermal source, mainly in gas discharges of the Active Crater rim, has also been detected. Significant variations in fluid chemistry, mainly consisting of a general decrease of magmatic-related compounds, i.e. SO₂, have affected the fumarolic system during the period of observation, indicating an increase of the influence of the hydrothermal system surrounding the ascending deep fluids. The chemical composition of Active Crater fumaroles has been used to build up a geochemical model describing the main processes that regulate the fluid circulation system of Lascar volcano to be utilized in volcanic surveillance.     

Fluid geochemistry of the Mondragone hydrothermal systems (southern Italy): water and gas compositions vs. geostructural setting

International Journal of Earth Sciences - The geochemistry of natural thermal fluids discharging in the Mondragone Plain has been investigated. Thermal spring emergences are located along the...     

Aquifer vulnerability and potential risk assessment: application to an intensely cultivated and densely populated area in Southern Italy

The use of indices, describing aquifer vulnerability and the risk of groundwater pollution, is a basic tool for the implementation of a sound water management plan, especially in densely populated and intensely cultivated areas. In this study, the groundwater contamination risk of the Caserta Plain (Southern Italy) was assessed through the integration of hazards defined on the basis of the different land uses, of the intrinsic vulnerability calculated by applying the SINTACS model and of the groundwater value evaluated by considering water wells density. In order to evaluate the evolution of the risk of groundwater pollution, the proposed methods were applied in the study area for both 2001 and 2009. The resulting specific vulnerability (SINTACS-L) and the risk (GRA) maps, created in a GIS environment, were validated by the comparison with the nitrate concentration distribution. The application of the proposed approach to the study area highlighted the strengths and weaknesses of each method and, at the same time, showed that their combination can provide an overall view of the threats posed to groundwater resources by the human activities affecting the territory. Considering both the benefits and the issues of the proposed approach, overall, the groundwater risk map is thought to be a robust tool to support water managers in defining future plans for water resources exploitation and land use.     

Dartmoor's overlooked glacial legacy

Traditionally regarded as a relict permafrost and periglacial landscape that lay beyond the limits of Pleistocene glaciation, the granite uplands of northern Dartmoor in south‐west England in fact contain geomorphological evidence for the former existence of a plateau ice cap, making the area the location of the southernmost independent glacier mass in the British Isles. In addition to weakly U‐shaped valleys, the most prominent evidence comprises arcuate and linear bouldery ridges and hummocky valley floor drift, which are interpreted as latero‐frontal moraines deposited by the outlet glacier lobes of a plateau ice cap. Inset sequences of these depositional landforms, in association with meltwater channels, demarcate the receding margins of the glacier lobes. A numerical model of ice cap development shows that a predominantly thin plateau icefield type glaciation is required in order to produce significant ice flow into surrounding valleys. The highest and most extensive plateau areas were occupied by ice for the longest cumulative period of time throughout the Pleistocene, thereby explaining: (1) the lack of tors in such areas as the product of ‘average’ glacial conditions preferentially removing tors or dampening their production rates, (2) the survival of high relief tors during glaciation if they occupied summits too narrow to develop thick and erosive glacier ice, and (3) the survival of subdued tors in areas glaciated less regularly during the Pleistocene.     

Suffer a Sea Change? Contrasting perspectives towards urban policy and migration in coastal Australia

Has the notion of ‘sea change’ and its considerable implications for non-metropolitan coastal Australia been exaggerated? In this article alternative perspectives of ‘sea change’ in Australia are reviewed, and the policy implications of each assessed. One perspective regards migration to coastal areas beyond the capital cities as incidental to continued metropolitan primacy and unlikely to affect or change Australia's overall urban or economic structure. The other considers the movement as a significant and enduring process with major environmental and socio-economic repercussions. With reference to research conducted for the National Sea Change Taskforce, the article finds partial support for both positions, leading to a more revealing understanding of ‘sea change’ in Australia. A set of policy responses, sensitive to the particular qualities of Australian coastal environments and communities, are proposed for consideration by all three tiers of government.