Separating contributions from natural and anthropogenic sources in atmospheric methane from the Black Sea region,Romania

The Danube Delta-Black Sea region of Romania is an important wetland, and this preliminary study evaluates the significance of this region as a source of atmospheric CH₄. Measurements of the mixing ratio and δ¹³C in CH₄ are reported from air and water samples collected at eight sites in the Danube Delta. High mixing ratios of CH₄ were found in air (2500–14,000 ppb) and dissolved in water samples (∼1–10 μmol L⁻¹), demonstrating that the Danube Delta is an important natural source of CH₄. The intercepts on Keeling plots of about −62‰ show that the main source of CH₄ in this region is microbial, probably resulting primarily from acetate fermentation. Atmospheric CH₄ and CO data from the NOAA/ESRL (National Oceanic and Atmospheric Administration/Earth System Research Laboratory) were used to make a preliminary estimate of biogenic CH₄ at the Black Sea sampling site at Constanta (BSC). These data were used to calculate ratios of CH₄/CO in air samples, and using an assumed CH₄/CO anthropogenic emissions ratio of 0.6, fossil fuel emissions at BSC were estimated. Biogenic CH₄ emissions were then estimated by a simple mass balance approach. Keeling plots of well-mixed air from the BSC site suggested a stronger wetland source in summer and a stronger fossil fuel source in winter.     

RXTE spectroscopy of GRS 1915+105

The galactic superluminal motion source GRS 1915+105 has been extensively observed with the RXTE satellite over the last two years. More than 250 RXTE pointings have been performed until mid-May 1998 with more than 1.5 Msec exposure time on roughly a weekly basis. Here we report on first results of our spectral analysis of a major part of these pointed RXTE observations. We establish the existence of at least 5 spectral components and present the changes of these components over the last two years.     

Conditions and timing of high-pressure Variscan metamorphism in the South Carpathians, Romania

High-pressure (HP) metamorphic rocks, including garnet peridotite, eclogite, HP granulite, and HP amphibolite, are important constituents of several tectonostratigraphic units in the pre-Alpine nappe stack of the Getic–Supragetic (GS) basement in the South Carpathians. A Variscan age for HP metamorphism is firmly established by Sm–Nd mineral–whole-rock isochrons for garnet amphibolite, 358±10 Ma, two samples of eclogite, 341±8 and 344±7 Ma, and garnet peridotite, 316±4 Ma.

A prograde history for many HP metamorphic rocks is documented by the presence of lower pressure mineral inclusions and compositional zoning in garnet. Application of commonly accepted thermobarometers to eclogite (grt+cpx±ky±phn±pg±zo) yields a range in “peak” pressures and temperatures of 10.8–22.3 kbar and 545–745 °C, depending on tectonostratigraphic unit and locality. Zoisite equilibria indicate that activity of H₂O in some samples was substantially reduced, ca. 0.1–0.4. HP granulite (grt+cpx+hb+pl) and HP amphibolite (grt+hbl+pl) may have formed by retrogression of eclogites during high-temperature decompression. Two types of garnet peridotite have been recognized, one forming from spinel peridotite at ca. 1150–1300 °C, 25.8–29.0 kbar, and another from plagioclase peridotite at 560 °C, 16.1 kbar.

The Variscan evolution of the pre-Mesozoic basement in the South Carpathians is similar to that in other segments of the European Variscides, including widespread HP metamorphism, in which P–T–t characteristics are specific to individual tectonostratigraphic units, the presence of diverse types of garnet peridotite, diachronous subduction and accretion, nappe assembly in pre-Westphalian time due to collision of Laurussia, Gondwana, and amalgamated terranes, and finally, rapid exhumation, cooling, and deposition of eroded debris in Westphalian to Permian sedimentary basins.