A ROBUST PLS PROCEDURE

A robust partial least squares(PLS)regression algorithm is developed.This is achieved by substitutionof the univariate regression steps in the iterative PLS2 algorithm by a robust alternative.The anglebetween loading vectors from both perturbed and unperturbed solutions is used as a measure ofrobustness.By means of a perturbation study on a structure-activity data set,it is demonstrated thatthe stability of the robust method is superior to standard PLS.     

Antioxidant efficiency and detoxification enzymes in spotted dogfish Scyliorhinus canicula

Although elasmobranchs are widely distributed species, commonly found on sandy, gravely or muddy bottoms, several biological aspects of their metabolism still remain poorly investigated. In this work the efficiency of antioxidant system and detoxification enzymes were investigated in the coastal spotted dogfish Scyliorhinus canicula and in the red mullet Mullus barbatus for comparison with a teleost species. Organisms were sampled during a bottom trawl survey and analyzed for the biotransformation activity (EROD), levels of metallothioneins, catalase, glutathione S-transferases and total oxyradical scavenging capacity (TOSC) toward peroxyl radicals and hydroxyl radicals. EROD activity in the elasmobranchs was more than one order of magnitude lower than in the red mullets, while similar levels of metallothioneins were measured in these species. S. canicula showed significantly lower antioxidant enzymes and a more reduced efficiency in neutralizing *OH; on the other hand the scavenging capability toward ROO* was comparable in S. canicula and M. barbatus.     

Helium isotopic ratio in Vulcano island fumaroles: temporal variations in shallow level mixing and deep magmatic supply

Intensive gas emanations occur throughout the island of Vulcano, Italy. Sharp fluctuations recorded in the crater gas composition suggest the presence of two separate volcanic reservoirs and continuous mixing with another source, “crustal” waters. This mixing differs between the beach and crater fumaroles. Gas samples from three crater fumaroles with temperatures ranging from 200 to 550 ° C were sampled repeatedly over a one year period. During the same interval of time, six samples from submarine and subaerial beach fumaroles and water well gases were also sampled. Gases from one crater fumarole (F5) showed variations of (³He/⁴He)_fumarole to (³He/⁴He)_air between 5 and 6 correlated with variations of several chemical species. High ³He/⁴He ratios for the beach fluids, similar to those of crater fluids, suggest the existence of a unique large magmatic reservoir at depth feeding both the crater and beach intermediate reservoirs. However, temporal changes clearly indicate variable degrees of fluids mixing, and the geographic distribution of the ³He/⁴He ratios as well as the chemical composition of the fluids suggest the existence between the magma reservoir and the surface of two intermediate different reservoirs, independently related to crater and to beach fumaroles.     

Albedo and color contrasts on asteroid surfaces

Asteroids in general display only small or negligible variations in spectrum or albedo during a rotational cycle. Color variations with rotation are described in the literature but are usually comparable to the noise in the measurements. Twenty-four asteroids have been systematically monitored for such color changes. Only 3 Juno, 4 Vesta, 6 Hebe, 71 Niobe, 349 Dembowska, and 944 Hidalgo display color variations larger than 0.03 mag. In each of these cases the asteroid appears redder near maximum brightness. Of seven asteroids monitored polarimetrically, only 4 Vesta shows a convincing variation, attributed to an albedo change with rotation. The lightcurve can be explained by albedo differences alone; Vesta apparently has a nearly spheroidal shape. Notwithstanding the above results, the degree of uniformity of most asteroid surfaces is remarkable. If asteroids exist with large discrete domains of ferrosilicate, metallic, and/or carbonaceous material together on their surfaces, they have not yet been identified.     

A test of the plausibility of eclipsing binary asteroids

We present an analytic method for producing the lightcurve of a system of spherical bodies in circular orbit about their common center of mass and then use it to model a lightcurve of 171 Ophelia. We find that a model in which the components have a diameter ratio of 1:2.96, have equal albedos, and circle one another in a synchronous orbit (period = 13.146 hr) inclined by 15° to our line of sight provides a reasonable fit to the observed lightcurve. An expression is given for the density in terms of the model parameters. If this lightcurve of Ophelia is produced by mutual eclipses of spherical components the mean density of the system can not exceed 1.7 g cm^?3. In view of these results we conclude that it is possible for Ophelia to be a binary.     

Linking large-parallax Spitzer–CFHT–VLT astrometry of asteroids

We show that the new ephemeris-space multiple-address-comparison (eMAC) method solves asteroid linking problems despite large parallaxes by applying the method to astrometric asteroid observation sets obtained nearly simultaneously with the Spitzer space telescope, the Canada–France–Hawaii Telescope (CFHT), and European Southern Observatory's Very Large Telescope (VLT). For main-belt asteroids, the parallax between Spitzer and the Earth-based telescopes is approximately one degree which is large as compared to a typical parallax for solely Earth-based telescopes in the arcseconds regime. In the eMAC method, we reduce the initially huge amount of possible linkages between observation sets by comparing samples of ephemerides that have been computed separately for all sets at, say, three common dates. If the non-zero ephemeris probability densities overlap at all common dates, we try to find an orbit solution for these so-called trial linkages. If there exists an orbit which reproduces all the astrometric observations assuming predefined observational errors, we call it a linkage. Known asteroids are independently identified among Spitzer, CFHT, and VLT astrometry, and comparing the identified observations to the linkages found shows that the method found all known correct linkages present in the data. In addition, we also found five previously unpublished linkages between Spitzer astrometry and Earth-based astrometry. Based on our simulations, we found virtually all Spitzer-related linkages between two single-night observation sets, and more than 99.4% of linkages between two single-night observation sets obtained by Earth-based observatories. Virtually all correct linkages consisting of at least three single-night sets were also detected. The results show that large-parallax discovery observations made from a spacecraft can be linked to Earth-based follow-up observations to ensure that the objects are not lost. Furthermore, we compute the heliocentric and Spitzer-centric distances as well as the corresponding solar phase angles at the dates of Spitzer observations. Based on comparisons to simulated geocentric observations, we also show that, for typical nearly-simultaneous observations, the parallax reduces the distance uncertainties by several orders of magnitude.     

Thermal springs,fumaroles and gas vents of continental Yemen: Their relation with active tectonics,regional hydrology and the country’s geothermal potential

Most thermal springs of continental Yemen (about 65 emergences at 48 sampling sites) and a couple of fumaroles and boiling water pools have been sampled and analyzed for chemical and isotopic composition in the liquid phase and the associated free-gas phase. Whatever the emergence, all the water discharges have an isotopic signature of meteoric origin. Springs seeping out from high altitudes in the central volcanic plateau show a prevalent Na–HCO₃-composition, clearly affected by an anomalous flux of deep CO₂ deriving from active hydrothermal systems located in the Jurassic Amran Group limestone sequence and/or the Cretaceous Tawilah Group, likely underlying the 2000–3000 m thick volcanic suite. At lower elevations, CO₂ also affects the composition of some springs emerging at the borders of the central volcanic plateau.     

UBV lightcurves of asteroid 433 Eros

UBV photometry and lightcurves of Eros were obtained on nine dates between October 1974 and March 1975. The absolute V magnitude at photometric maximum extrapolated to a solar phase angle of zero is 10.75 while the linear phase coefficient is 0.026mag deg^?1. The mean colors at solar phase angles greater than 30° are B?V = 0.92 and U?B = 0.52mag. No significant color variations over the surface were detected.     

Rotational properties of asteroids: Correlations and selection effects

Rotational data on 321 asteroids observed as of late 1978 are analyzed. Selection effects within the sample are discussed and used to define a data set consisting of 134 main-belt, nonfamily asteroids having reliably determined periods and amplitudes based on photoelectric observations. In contrast to A. W. Harris and J. A. Burns (1979, Icarus40, 115–144) we found no significant correlation between rotational properties and compositional type. Smaller asteroids have a greater range of rotational amplitudes than the largest asteroids but are not, on the average, appreciably more elongated. While no definite relationship between asteroid size and rotation rate was found the distribution is not random. The largest asteroids have rotation periods near 7 hr compared with 10 hr for the smaller. A group of large, rapidly rotating, high-amplitude asteroids is recognized. A pronounced change in rotational properties occurs near this size range (diam = 200 ± 50 km) which also corresponds to the size at which a change of slope occurs in the size frequency distribution. We believe this size range represents a transition region between very large, rapidly rotating, low-amplitude (primordial?) objects and smaller ones having a considerably greater range of periods and amplitudes. Asteroids in this transition size range display an increase in rotational amplitude with increasing spin rate; other than this, however, there is no correlation between period and amplitude. The region of low spatial density in the asteroid belt centered near 2.9 AU and isolated from the inner and outer belt by the 2:5 and 3:7 commensurabilities is shown to be a region in which non-C or -S asteroids are overrepresented and which have marginally higher rotational amplitudes than those located in more dense regions. We attribute disagreements between our results and other studies of this type to the inclusion of non-main-belt asteroids and photographic data in the earlier analyses.