Elastic modulus and internal friction in enstatite,forsterite and peridotite at seismic frequencies and high temperatures

Spectra of internal friction between 2 and 8 Hz were studied in a single crystal of enstatite, in a polycrystal of synthetic forsterite and in several samples of natural peridotite. Measurements of Q^?1 and μ were performed in vacuum (10^?6 torr), from room temperature up to 1100°C. For these experimental conditions no peak was observed in the polycrystalline undeformed forsterite, but the background attenuation irregularly increased from 5 · 10^?3 to 10^?2.A peak Q^?1 = 7 · 10^?2 appears in a deformed peridotite at 930°C. It is reduced of 60% after 5 h of annealing at 1100°C. But the background attenuation persists. In the single crystal of enstatite, a peak is observed at 760°C (Q^?1 = 6 · 10^?2). A mechanism involving dislocations is suggested as a possible explanation for the peak obtained with the peridotite samples. If this hypothesis is right, the observed effect would be diffusion controlled so that one can expect pressure to translate it towards higher temperature. This mechanism could therefore appear in the upper mantle. Background attenuation could be the result of intergranular thermal losses.     

Cyclic activity of the H2O maser emission towards NGC 2071

A catalog of maser spectra in the 1.35-cm water-vapor line towards the maser source NGC 2071 in a region of massive star formation is presented for 1994–2010. The observations were carried out using the 22-m antenna of the Pushchino Radio Astronomy Observatory with a spectral resolution of 0.101 km/s (0.0822 km/s after the end of 2005). Based on the data throughout the monitoring since 1980, two very different cycles of maser activity were found. The first (1980–1992) is characterized by high activity within a broad range of radial velocities. Emission at velocities near 7 km/s predominated in 1980–1986, and emission near 14–16 km/s, in 1987–1992. In 1997–2008, the maser intensity was appreciably lower than in the first activity cycle. Numerous flares of individual emission features were observed. Identifications based on VLA data show that strong flares took place in both maser sources, IRS1 and IRS3. Both sources demonstrated a low level of maser activity during essentially the same epochs (1977, 1995–1997, and the close of 2009 through the beginning of 2010), although the sources are separated by at least 2000 AU.     

Vapour transport of rare earth elements (REE) in volcanic gas: Evidence from encrustations at Oldoinyo Lengai

Fumarolic encrustations and natrocarbonatite lava from the active crater of Oldoinyo Lengai volcano, Tanzania, were sampled and analysed. Two types of encrustation were distinguished on the basis of their REE content, enriched (~ 2800–5600 × [REE_chondrite]) and depleted (~ 100–200 × [REE_chondrite]) relative to natrocarbonatite (1700–1900 × [REE_chondrite]. REE-enriched encrustations line the walls of actively degassing fumaroles, whereas REE-depleted encrustations occur mainly along cracks in and as crusts on cooling natrocarbonatite lava flows; one of the low REE encrustation samples was a stalactite from the wall of a possible fumarole. The encrustations are interpreted to have different origins, the former precipitating from volcanic gas and the latter from meteoric/ground water converted to steam by the heat of the overlying lava flow(s). REE-profiles of encrustations and natrocarbonatite are parallel, suggesting that there was no preferential mobilization of specific REE by either volcanic vapour or meteoric water vapour. The elevated REE-content of the first group of encrustations suggests that direct REE-transport from natrocarbonatite to volcanic vapour is possible. The REE trends observed in samples precipitating directly from the volcanic vapour cannot be explained by dry volatility based on the available data as there is no evidence in the encrustation compositions of the greatly enhanced volatility predicted for Yb and Eu. The observed extreme REE-fractionation with steep La/Sm slopes parallel to those of the natrocarbonatite reflects solvation and complexation reactions in the vapour phase that did not discriminate amongst the different REE or similar transport of REE in both the natrocarbonatite magma and its exsolving vapour. The low concentrations of REE in the encrustations produced by meteoric vapour suggest that the temperature was too low or that this vapour did not contain the ligands necessary to permit significant mobilization of the REE.     

Evaluation of urban thermal environments in commercial and residential spaces in Okayama City, Japan, using the wet-bulb globe temperature index

We estimated wet-bulb globe temperature (WBGT) using measured meteorological data to understand the bioclimates of human living spaces during the summer season. Our research focused on commercial and residential areas of Okayama City, Japan (population ～700,000). The commercial spaces (CO) mainly consisted of multi-story office buildings, whereas the residential spaces (RE) consisted of one- or two-story residential buildings. On a fine day with southeast winds, the spatially averaged WBGT measured in the CO was higher than that in the RE. The difference was statistically significant and would have caused noticeable discomfort and a high risk of heat disorder for occupants of the CO over the long term. For instance, at 1900 Japan Standard Time (JST), the maximum difference in the WBGT between the CO and RE sites was 2.0°C (23.5°C for the CO and 21.5°C for the RE). From 1800 to 1900 JST, the wet-bulb temperature in the CO was still 1.5–2.0°C higher than that in the RE, even though both areas had the same dry-bulb temperature. This indicates that the CO retained greater amounts of water vapor for longer periods compared to the RE. The wet-bulb temperature in the CO increased rapidly at most observation points when the southeast sea breeze arrived. In contrast, in the RE, the wet-bulb temperature decreased until evening. This difference was caused by moist air transported from a river about 1 km upwind from the CO. The moist air forced an increase in the WBGT and elevated the risk of heat disorder in the CO. The spatially averaged globe temperature of the CO at 1500 JST was 6.2°C lower than that at the RE, causing the WBGT of the CO to decrease. The results suggest that the higher WBGT in the CO was caused by higher wet-bulb temperatures. On a day with southwest winds, the CO and RE showed no difference in WBGT because the river was not included in the upwind source area.     

Stratified unbounded flow past of obstacles

We studied the surface perturbations of a two-layer ideal fluid induced by a flow past a submerged obstacle (simulated by a point dipole) in the vicinity of the density-jump layer. It is shown that the formation of two different types of surface waves is possible behind the flowed past obstacle in the real conditions of the open sea. The comparison of the amplitudes of the surface perturbations induced by the obstacle located above and below the density jump revealed their significant differences, which seems to be important for the use of this effect in practical problems.     

Determination of evaporation from integrated profiles of humidity and temperature over an inhomogeneous surface

In this study a moderate-sized alfalfa field was downwind of a large dry region. Measured vertical profiles of temperature, humidity and wind at upwind and downwind sides of the field were used to calculate the short-term evaporation rate, as well as the contribution of horizontally transported or advected heat energy to the evaporation. The vertical profiles must be measured at least to the height at which air is modified by the new surface. In this case that height was as large as 18 m over a several hundred meter long traverse.Evaporation rates calculated by such an approach were in very close agreement to surface fluxes measured by an eddy correlation system near the surface. The difference between calculated and measured values averaged 9.5%. The reduction in sensible heat content of the air of the control volume was substantial during passage over the field. If all this energy was assumed to have been used in evaporation, then the advection of heat contributed from 35 to 86% of the total evaporation rate.It appears that for an inhomogeneous surface, knowledge of the distortion of some properties of local boundary layers can yield reliable estimates of local evaporation. The approach has little empiricism as it is based on simple conservation laws.     

Compression studies of gibbsite and its high-pressure polymorph

Various X-ray diffraction methods have been applied to study the compression behavior of gibbsite, Al(OH)₃, in diamond cells at room temperature. A phase transformation was found to take place above 3 GPa where gibbsite started to convert to its high-pressure polymorph. The high-pressure (HP) phase is quenchable and coexists with gibbsite at the ambient conditions after being unloaded. This HP phase was identified as nordstrandite based on the diffraction patterns obtained at room pressure by angle dispersive and energy dispersive methods. On the basis of this structural interpretation, the bulk modulus of the two polymorphs, i.e., gibbsite and nordstrandite, could be determined as 85 ± 5 and 70 ± 5 GPa, respectively, by fitting a Birch-Murnaghan equation to the compression data, assuming their K_o ^′ as 4. Molar volume cross-over occurs at 2 GPa, above which the molar volume of nordstrandite is smaller than that of gibbsite. The differences in the molar volume and structure between the two polymorphs are not significant, which accounts for the irreversibility of the phase transition. In gibbsite, the axial compressibility behaves as c/c _o > a/a _o > b/b _o. This is due to the fact that the dioctahedral sheets along the c-axis are held by the relatively weak hydrogen bonding, which results in the greater compressibility along this direction. In nord- strandite, the axial compressibility is b/b _o > c/c _o > a/a _o, which can also be interpreted as resulting from the the existence of hydrogen bonds along the b-axis. Received: 28 September 1998 / Revised, accepted: 22 December 1998     

A note on estimating the vertical eddy diffusion coefficient from LANDSAT imagery

Boundary-Layer Meteorology - The vertical eddy diffusion coefficient (K z) for five smoke plumes entrapped in a stable marine layer is estimated from the published LANDSAT imagery data sets of...