The effects of light and nutrients on rates of ammonium transformation in a eutrophic river

Rates for nitrification, phytoplankton uptake of ammonium, and regeneration of ammonium were measured in the Delaware River as functions of irradiance and nutrient concentrations, using ¹⁵N labeling methods. Phytoplankton uptake increased and nitrification rates declined with increased light intensity. The irradiance level required for maximum uptake by phytoplankton was similar to that for maximal inhibition of nitrification (about 300μEm⁻² s⁻¹). Daily, water-column averaged rates, calculated by integration of the observed rate-intensity relationships, indicate that light plays a key role in regulating the balance between oxidation of NH₄⁺ by bacteria and assimilation by phytoplankton in the Delaware. The results show that uptake of ammonium by phytoplankton in the dark may exceed uptake in the light in optically thick systems.     

The structure and contemporary activity of the Intramoesian fault in northeastern Bulgaria obtained through a complex of new geological-geophysical methods

The structure of the Intramoesian fault is studied for the purpose of estimating its contemporary activity. The fault is known in the territory of Romania and Bulgaria, but it is insufficiently studied both from the geological point of view on the surface and from the geophysical point of view, from which the pattern of its deep structure can be inferred. The fault zone is the key structure for the solution of the problem of estimating the seismic hazard of the region, since the latest studies of this territory indicate the existence of traces of relatively young tectonic processes. According to some concepts the Intramoesian fault sets bounds to the tectonic plate, which is subducted under the Carpathian fold system in the region of the Vrancea Mountains. The paper under consideration presents the results of the field study of the southeastern, the Bulgarian, part of the fault with the application of a complex of geological-geomorphological and geophysical methods. On this basis, the structural segmentation of the fault is carried out and the specific features of its intersection with the disjunctives of another structural orientation are inferred. The data, which determine the degree of its geological and seismic activity, are also discussed.     

The evolution of zircon during low‐P partial melting of metapelitic rocks: theoretical predictions and a case study from Mt Stafford,central Australia

Palaeoproterozoic metasedimentary migmatite reflects the highest temperature parts of a regional aureole at Mt Stafford, central Australia, comprising rocks that experienced 500–800 °C at ≈3 kbar. Whole‐rock major element concentrations are correlated with Zr content, psammitic compositions having nearly twice the Zr content of pelitic compositions. Zirconium is concentrated in mesosome compared with leucosome. Zircon is largely detrital, mostly lacking any overgrowth contemporary with migmatite formation. Comparatively small proportions of micro‐zircon (<10 μm) in sub‐solidus rocks are mostly hosted by quartz and plagioclase. Much higher proportions (three to five times) of micro‐zircon in migmatite are hosted by prograde K‐feldspar, cordierite and biotite. T–X and P–T NCKFMASHTZr pseudosections constructed using thermocalc model the distribution of Zr between solid and silicate liquid phases. Half of the detrital zircon (~100 ppm Zr) is predicted to be dissolved into silicate liquid at ≈800 °C and all dissolved by 850 °C, if all zircon is involved in the equilibration volume. Melt segregation at relatively low temperature is predicted to enrich the residuum in Zr, consistent with the observed distribution of Zr between mesosome and leucosome. The limited development of metamorphic zircon rims or overgrowths at Mt Stafford is explained by three concurrent processes: (i) Zr liberated during prograde metamorphism formed micro‐zircon, rather than following the prediction that Zr will partition into silicate liquid; (ii) some detrital zircon was probably armoured by other rock‐forming minerals, reducing Zr content in the effective bulk rock composition; and (iii) small proportions of melt loss during migmatization removed Zr that otherwise would have been available to form metamorphic rims.     

The reproductive cycle of the bay scallop,Argopecten irradians irradians (Lamarck), in a small coastal embayment on Cape Cod,Massachusetts

The spawning activity of the bay scallop Argopecten irradians irradians (Lamarck) was monitored from May through September in a small embayment on Cape Cod, Massachusetts and compared with changes in hydrographic conditions. Spawning activity of bay scallops began in May and continued through July with some minor activity occurring during August and September. Activity was most closely related to changes in ambient temperature and occurred predominantly before the summer maximum temperature was recorded. As temperatures declined in the late summer and early fall, increased gametogenic activity was evident. A longer period of spawning activity was observed than was previously reported for New England waters.     

Testing a model for predicting the timing and location of shallow landslide initiation in soil‐mantled landscapes

The growing availability of digital topographic data and the increased reliability of precipitation forecasts invite modelling efforts to predict the timing and location of shallow landslides in hilly and mountainous areas in order to reduce risk to an ever‐expanding human population. Here, we exploit a rare data set to develop and test such a model. In a 1·7 km² catchment a near‐annual aerial photographic coverage records just three single storm events over a 45 year period that produced multiple landslides. Such data enable us to test model performance by running the entire rainfall time series and determine whether just those three storms are correctly detected. To do this, we link a dynamic and spatially distributed shallow subsurface runoff model (similar to TOPMODEL) to an in?nite slope model to predict the spatial distribution of shallow landsliding. The spatial distribution of soil depth, a strong control on local landsliding, is predicted from a process‐based model. Because of its common availability, daily rainfall data were used to drive the model. Topographic data were derived from digitized 1 : 24 000 US Geological Survey contour maps. Analysis of the landslides shows that 97 occurred in 1955, 37 in 1982 and ?ve in 1998, although the heaviest rainfall was in 1982. Furthermore, intensity–duration analysis of available daily and hourly rainfall from the closest raingauges does not discriminate those three storms from others that did not generate failures. We explore the question of whether a mechanistic modelling approach is better able to identify landslide‐producing storms. Landslide and soil production parameters were ?xed from studies elsewhere. Four hydrologic parameters characterizing the saturated hydraulic conductivity of the soil and underlying bedrock and its decline with depth were ?rst calibrated on the 1955 landslide record. Success was characterized as the most number of actual landslides predicted with the least amount of total area predicted to be unstable. Because landslide area was consistently overpredicted, a threshold catchment area of predicted slope instability was used to de?ne whether a rainstorm was a signi?cant landslide producer. Many combinations of the four hydrological parameters performed equally well for the 1955 event, but only one combination successfully identi?ed the 1982 storm as the only landslide‐producing storm during the period 1980–86. Application of this parameter combination to the entire 45 year record successfully identi?ed the three events, but also predicted that two other landslide‐producing events should have occurred. This performance is signi?cantly better than the empirical intensity–duration threshold approach, but requires considerable calibration effort. Overprediction of instability, both for storms that produced landslides and for non‐producing storms, appears to arise from at least four causes: (1) coarse rainfall data time scale and inability to document short rainfall bursts and predict pressure wave response; (2) absence of local rainfall data; (3) legacy effect of previous landslides; and (4) inaccurate topographic and soil property data. Greater resolution of spatial and rainfall data, as well as topographic data, coupled with systematic documentation of landslides to create time series to test models, should lead to signi?cant improvements in shallow landslides forecasting. Copyright © 2003 John Wiley & Sons, Ltd.     

Review: The Yucat��n Peninsula karst aquifer, Mexico

The Yucatán Peninsula karst aquifer is one of the most extensive and spectacular karst aquifer systems on the planet. This transboundary aquifer system extends over an area of approximately 165,000? km² in México, Guatemala and Belize. The Triassic to Holocene Yucatán limestone platform is located in the vicinity of the North American/Caribbean plate boundary and has been reshaped by a series of tectonic events over its long geologic history. At the end of the Cretaceous period, the Yucatán Peninsula was hit by a large asteroid, which formed the Chicxulub impact crater. The Yucatán Peninsula karst aquifer hosts large amounts of groundwater resources which maintain highly diverse groundwater-dependent ecosystems. Large parts of the aquifer are affected by seawater intrusion. Anthropogenic pollution of the aquifer has been increasing over the past few decades, owing to relentless economic development and population growth on the Peninsula. This review summarizes the state of knowledge on the Yucatán Peninsula karst aquifer and outlines the main challenges for hydrologic research and practical groundwater-resources management on the Peninsula.     

Relationship between Magmatic,Metamorphic, and Hydrothermal Processes within the Baikal–Muya Terrane (Eastern Siberia): Constraints from High-Precision Geochronological Study of the Kedrovskii Granitoid Massif

Doklady Earth Sciences - High-precision dating of granitoids is of key significance for age identification of the main stages of crust formation in various blocks of the continental crust. Here we...     

The Potential for Environmentally Sound Development of Marine Deposits of Potassic and Phosphatic Minerals Offshore, Southern Africa

Extensive potassium and phosphorous-rich mineralization occurs on the outer continental shelf of the southern and west coasts of South Africa and Nambia. This article reviews the potential of exploiting these deposits in an environmentally sound manner for the manufacture of fertilizer. At present, reserves of potash and phosphate fertilizer are exploited from terresterial deposits, the majority being surface mined. The use of fertilizer in South Africa has shown no growth in the past 13 years, and, in some years, usage has even declined. On average, over the last decade, South Africa has consumed 2 million Mt of fertilizer (including nitrogen) per annum, the vast majority of phosphate fertilizer being produced by FOSKOR from the Phalaborwa Igneous Complex. Potash fertilizer is imported into South Africa. Although fertilizer consumption is expected to decrease in the short-term, there are good future prospects for the domestic and international fertilizer market. Considerable research into both glauconitic (containing K 2 O) and phosphatic deposits along the southern African continental shelf indicate that these sedimentary deposits have a complex genesis and mineralization. Of the total K 2 O reserves of 1300 million Mt on the southern African margin, 1000 million Mt is located off the southern African west coast, and the remainder situated on the Agulhas Bank. The largest glauconite concentration ( ±300 million Mt K 2 O) off southern Africa lies west of Saldanha Bay, South Africa. The distribution of P 2 O 5 off southern Africa is dominated by the vast deposit between Walvis Bay and Luderitz, Nambia. This reserve is estimated to contain 1000 million Mt of greater than 5% P 2 O 5 in a relatively small area of about 10000 km2. The phosphorite deposit south of Saldanha Bay constitutes a reserve of ±3500 million Mt of apatite and the deposit on the Agulhas Bank comprises 5500 million Mt. The phosphate deposit off Saldanha Bay occurs as an extensive, low to medium grade deposit. Although vast resources of potash and phosphatic minerals occur along the southern African outer continental shelf the expensive nature of marine exploitation may render most of these deposits, especially the phosphates, subeconomic. The low price of fertilizer andextensive natureontheonland deposits, although confined to asmallnumber of countries, mean that it will not be financially viable to extract these deposits. Assuming high grade glauconitic sand with the right composition can be located, the high market price indicates good future prospects for these potash deposits.     

昔日全球环境变化的自然磁记录

沉积物的岩石磁学参量反映了它在海洋及大陆范围内沉积时的古环境及古气候条件.尽管对这种现象的认识还不彻底,但人们对于那些导致磁性增强或减弱的作用已有了很好的了解.这些作用包括可变的陆源物质沉积通量,铁磁性矿物在原地的有机及无机形成,以及这些矿物成岩过程中的分解.至少在过去的700万年间,在大量的沉积记录中观察到了磁性矿物集合体的周期性出现,这些周期性出现涉及到了标准的米兰柯维奇理论的轨道频率,证实了岩石磁学同过去全球变化间的关系.但是,磁信号的定量解译仍然处在幼年期,并且受到了信号形成过程中复杂的相互作用的干扰.