Assessing groundwater storage changes in the Nubian aquifer using GRACE data

Gravity Recovery and Climate Experiment (GRACE) level two (L2) data is used in estimating the groundwater storage changes (GWSC) in the Nubian Sandstone Aquifer System (NSAS). This set of data consists of spherical harmonics coefficients with specific degree and order. The GRACE data is de-correlated using a sixth degree polynomial in order to reduce the effect of the noise error resulting from the correlation between the spherical harmonics coefficients with the same degree parity. The GRACE estimates of GWSC are smoothed using Gaussian filter with half width of 1000 km. This half width is chosen in order to maximize the correlation between the GRACE estimates of GWSC and previous modeling results of the NSAS. The loss in groundwater storage occurring in each of the four countries sharing the NSAS is calculated to assess the sustainability of using the NSAS as a water resource in each country. The overarching finding in this study is that NSAS is losing its groundwater storage at a very high rate. Also, it is found that Egypt is the fastest in losing its groundwater storage from the NSAS. This loss of groundwater storage in Egypt may not necessarily be resulting from in-country extractions because of the trans-boundary nature of this aquifer. The GRACE-based estimates are found to be close to available data and previous modeling results of the NSAS.     

Pressure-temperature and evolution of fluid compositions of Al2SiO5-bearing rocks,Mica Creek,B.C., in light of fluid inclusion data and mineral equilibria

Metamorphosed pelitic rocks from Mica Creek, British Columbia contain sillimanite, kyanite with minor fibrolite and andalusite-bearing quartz pods. Mineral equilibria were used to infer peak P-T conditions and fluid compositions in equilibrium with the solid phases. Fluid inclusions in three schist samples appear to be good indicators of conditions affecting those rocks during and after peak metamorphic conditions. In samples from two localities, fluid inclusions from schist and quartz-rich segregations have densities appropriate to the peak metamorphic conditions. The observed compositions for these fluids (low salinity with 12 mole % dissolved CO₂) agree with calculated values of 0.84 to 0.85, based upon paragonite-quartz-albite-Al₂SiO₅ equilibria. The fluids unmixed as the schists were uplifted and cooled; fluid inclusions trapped during this stage outline a solvus in the CO₂-H₂O-NaCl system. A later influx of fluids containing CH₄ and N₂ accompanied formation of andalusite-bearing plagioclaserich segregations. The restricted association of andalusite-bearing pods and low density fluids suggest a localized but pervasive fluid influx during uplift. Preservation of high density fluid inclusions during uplift and erosion, coupled with evidence for unmixing of H₂O- and CO₂-rich fluids on the solvus, provide constraints on the P-T uplift path.     

Polarization in spectral lines

The general formalism, presented in a previous paper of this series (Landi Degl'Innocenti, 1983a), is particularized to deduce the radiative transfer equations for polarized radiation and the statistical equilibrium equations for a multi-level atom in the zero-magnetic field, collisionless regime. The formulae are developed both in the standard representation and in the representation of the statistical tensors. For resonance scattering in a two-level atom, in the limiting case of complete depolarization of the ground level, we recover the classical results for Rayleigh scattering and we derive the expression of the phase matrix in terms of ordinary rotation matrices. The law of scattering is then generalized to take properly into account the influence of the anisotropy of the radiation field on the atomic polarization of the ground level (depopulation pumping).     

Seismic model of the lithosphere of the East European Platform beneath the Baltic Sea-Black Sea profile

This paper presents the results of seismic measurements along the Baltic Sea-Black Sea profile. The basic wave groups recorded up to distances of 900 km are characterized. The main elements of a lithospheric model of the southwestern part of the Precambrian East European Platform are given. The thickness of the Earth's crust is about 45 km and the mean velocity of the crust is about 6.3 km/s. At a depth of 65 km, the velocity increases from 8.2 to 8.5 km/s. In the depth interval 110 to 135 km, there is a series of layers with low and high velocities. The lower boundary of the lithosphere is probably defined by the boundary at a depth of 110 km.     

Die Bedeutung der Versumpfung für die Entstehung von Hochmooren in Deutschland

Zusammenfassung Es ist nur bei Gebirgsmooren zulässig, von Versumpfungsmooren zu reden. Die als solche erscheinenden Hochmoore des Flachlandes dürften in der Mehrzahl der Fälle keine Versumpfungsmoore im engeren Sinne sein, sondern nur durch Versumpfugserscheinungen in ihrer Ausbreitung geförderte Hochmoore, die ursprünglich als Hochmoore auf eutrophen und mesotrophen Moorschichten begannen (sogen. kombinierte Profile).Das Vorhandensein von Hochmooren des Flachlandes, die wirklich durch Versumpfung ins Leben gerufen worden sind, ist erst noch zu beweisen.     

Factors controlling the adsorption of acid blue 113 dye from aqueous solution by dried <Emphasis Type="Italic">C. edulis</Emphasis> plant as natural adsorbent

Contamination of surface water and groundwater by organic pollutants is a serious problem due to their persistence, bioaccumulation and biomagnification through food webs. Since the removal of dyes from wastewater is considered an environmental challenge and government legislation requires textile wastewater to be treated, therefore there is a constant need to have an effective process that can efficiently remove these dyes. The aim of the present study is to evaluate the potentiality of dried Carpobrotus edulis plant as low-cost adsorbent for the removal of the industrial acid blue 113 dye from aqueous solutions using the batch equilibration technique. The effects of different physicochemical parameters such as adsorbent dose, contact time, initial dye concentration, solution pH and temperature on adsorption rate of anionic AB113 dye on microparticles of dried C. edulis plant were investigated. The experimental data were analyzed by using mathematical models to determine the thermodynamic parameters. The negative values of free energy change indicated the spontaneous nature of the adsorption and negative value of enthalpy change suggested the exothermic nature of the adsorption process. These results indicate that dried C. edulis plant as an environmentally friendly adsorbent could be potentially used for the removal of anionic dyes from aqueous solutions.     

Determination of the Rare-Earth Elements and Yttrium In 37 International Silicate Reference Materials By Inductively Coupled Plasma-Atomic Emission Spectrometry

The rare-earth elements (REE) and yttrium have been determined in 37 international rock and mineral reference materials. Samples were prepared using conventional rock-dissolution techniques, and the REE and yttrium were separated from the other constituents using cation-exchange chromatography. The REE (La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Yb, Lu) and yttrium were determined simultaneously by inductively coupled plasma-atomic emission spectrometry (ICP-AES). Results for four well-characterised USGS standard rocks agree favourably with "recommended" values and with REE determinations made previously by workers using ICP-AES, isotope dilution mass spectrometry, instrumental neutron activaton analysis and X-ray fluorescence spectrometry.
Les éléments de terres rares (TR) et yttrium ont été dosés dans 37 échantillons internationaux de réféence. Les échantillons ont été décomposés par dissolution acide et les TR séparés par résine échangeuse de cations. Les TR (La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Yb, Lu) et yttrium ont été dosés simultanément par la spectrométrie d'émission-plasma inductif. Les résultats obtenus pour quatre échantillons de référence bien charactérisés de I'USGS se comparent favorablement avec ceux obtenus par la spectrométrie d'émission-plasma, la dilution isotopique, I'activation neutronique et par la spectrométrie d'é fluorescence-X.     

REDUCTION OF HARMONIC DISTORTION IN VIBRATORY SOURCE RECORDS*

Due to non-linear effects, the swept frequency signals (sweeps) transmitted into the subsurface by vibrators are contaminated by harmonics. Upon correlation of the recorded seismograms, these harmonics lead to noise trains which are particularly disturbing in the case of down-sweeps. The method described in this paper—which can be regarded as a generalization of Sorkin's approach to the suppression of even order harmonics—allows elimination, from the final vibratory source seismogram, of harmonics of the sweep up to any desired order. It requires that not one single signal but rather a series of M signals is employed where each signal has an initial phase differing from that of the previous one of the series by the phase angle 2πM. Prior to stacking, the seismograms generated with the different signals have to be brought into the form they would have if they had been generated with the same signal. The method seems also to be capable of reducing the correlation noise if sign-bit recording techniques are used.     

Hydrodynamic coefficients of a monolithic circular offshore structure

Expressions for both the rectilinear and rotational inertial and damping coefficients for a circular monolithic tower of uniform radius are derived. The analysis matches the fluid velocity, derived from potential theory, with the structural velocity in sway. That is, the motions of the tower are assumed to be in a vertical plane. The analysis is then applied to a tower composed of (lumped-mass) elements, where the expressions for the added-mass and damping coefficients are shown to be functions of wave number. The added-mass is shown to be a product of two wave systems: a travelling wave system, which is responsible for the radiation damping, and a standing wave system, called the evanescent system, which is attached to the structure. The added-mass of the evanescent system is negative for small wave numbers, while that of the travelling waves is positive. The negative sign simply means that the inertial force of the evanescent waves is 180° out of phase with that of the travelling system. Furthermore, it is shown that the contributions of the two wave systems to the total added-mass of the structure counteract each other, resulting in a total added-mass which varies gradually with the wave number. Finally, the analysis is applied to an experiment, and results of the analysis and the experiment are found to agree rather well.     

UV camera measurements of fumarole field degassing (La Fossa crater,Vulcano Island)

The UV camera is becoming an important new tool in the armory of volcano geochemists to derive high time resolution SO₂ flux measurements. Furthermore, the high camera spatial resolution is particularly useful for exploring multiple-source SO₂ gas emissions, for instance the composite fumarolic systems topping most quiescent volcanoes. Here, we report on the first SO₂ flux measurements from individual fumaroles of the fumarolic field of La Fossa crater (Vulcano Island, Aeolian Island), which we performed using a UV camera in two field campaigns: in November 12, 2009 and February 4, 2010. We derived ~ 0.5 Hz SO₂ flux time-series finding fluxes from individual fumaroles, ranging from 2 to 8.7 t d^?1, with a total emission from the entire system of ~ 20 t d^?1 and ~ 13 t d^?1, in November 2009 and February 2010 respectively. These data were augmented with molar H₂S/SO₂, CO₂/SO₂ and H₂O/SO₂ ratios, measured using a portable MultiGAS analyzer, for the individual fumaroles. Using the SO₂ flux data in tandem with the molar ratios, we calculated the flux of volcanic species from individual fumaroles, and the crater as a whole: CO₂ (684 t d^?1 and 293 t d^?1), H₂S (8 t d^?1 and 7.5 t d^?1) and H₂O (580 t d^?1 and 225 t d^?1).