Discovery of Precambrian rocks in New Zealand: Age relations of the Greenland Group and Constant Gneiss,West Coast,South Island

Rb-Sr whole-rock analyses yield a Cambro-Ordovician (495 ± 11 m.y.) sedimentation age for the supposed Precambrian Greenland Group and a late Precambrian age, 680 ± 21 m.y., for parts of the Constant Gneiss, the first confirmation of Precambrian rocks in New Zealand. A Precambrian age for the Greenland Group is thus unlikely and the large area of Upper Cambrian-Lower Ordovician rocks now established can be considered as a lateral equivalent of the fossiliferous Lower Palaeozoic succession of northwest Nelson to the east. The Greenland Group, especially in the Paparoa Range has been affected subsequently by a thermal metamorphic overprint about 360 m.y. ago during the Tuhuan Orogeny. Although the Constant Gneiss must form the local basement to the Greenland Group in north Westland, the former does not appear to be the source of the sediments and the true provenance must lie elsewhere.     

The effects of heating on low-temperature susceptibility and hysteresis properties of basalts

The variation of the low-field susceptibility of basalts down to liquid-nitrogen temperature always falls into one of three types that depend on the composition and grain size of the titanomagnetite grains present. Group 1 basalts contain predominantly unoxidised, multidomain homogeneous titanomagnetites having x 0.3. Group 2 basalts contain predominantly titanomagnetite grains with many exsolved ilmenite lamallae that subdivide the grains so that they act similarly to single domains. Group 3 basalts contain predominantly multidomain magnetite or magnetite-rich titanomagnetite having x 0.15. After repeated heating to 615°C, the group 1 basalts gradually oxidise above 300°C to produce the characteristics of group 2 basalts, owing to the exsolution of ilmenite. On the other hand, both group 2 and 3 basalts are stable to oxidation until at least 500°C. They are therefore the most useful material for palaeointensity studies.     

Fluids in the lithosphere, 2. Experimental constraints on CO2 transport in dunite and quartzite at elevated P-T conditions with implications for mantle and crustal decarbonation processes

In a series of experiments at 0.5–1.3 GPa and 1050–1200°C we have monitored the transport, via crack propagation, of CO₂ into well-annealed olivine and quartz aggregates. The objectives were to determine (1) the extent and rate of fluid penetration; (2) the effect of varying both P-T conditions and microstructure; and (3) the fluid penetration pathways. Experiments on CO₂ penetration into dunite annealed in the absence of MgO indicate rapid and pervasive fluid transport on a grain-dimension scale, but a limited penetration distance ( 1 mm). Additional experiments on dunite annealed in the presence of MgO (either dispersed or present at both ends), however, resulted in CO₂ penetration that was both pervasive on the scale of individual grains and almost always completely through the 5 mm long samples. The abundance of fine (10 μm) grains in the MgO-free dunite, in contrast to the much larger grain sizes of the samples annealed with MgO present, suggests the difference in fluid penetration behavior may arise because the strength variation in dunite scales with the grain size. Effects arising from changes in olivine point defect chemistry, however, are an additional possibility. The response of synthetic quartzite to CO₂ overpressure is distinct from that of dunite: Quartzite experiences rapid and complete penetration of CO₂, via a macroscopically visible system of transgranular fractures, over the range of P-T conditions investigated.The small amount of porosity ( 2–3%) present in most rock samples fabricated for this study, lacks three-dimensional connectivity, thus precluding any enhanced fluid penetration via porous flow. Pores could possibly enhance fluid penetration as the result of a small reduction in resistance to fracture, but the probable abundance of strength-controlling flaws in natural rocks is likely to produce similar behavior.The results of our experiments on olivine and olivine + MgO suggest that the transport of pressurized CO₂ in very olivine-rich mantle environments will be pervasive on the scale of individual grains and its extent may be dependent on rock microstructure and/or crystal chemical effects. Such pervasive fluid transport, perhaps associated with magma decarbonation, may have interesting implications for both magma transport and local LREE enrichment of adjacent mantle wall-rock. The ease with which quartzite is penetrated by CO₂ at the conditions of our experiments underscores the possible role of decarbonation reactions in crustal permeability-enhancement processes.     

Modulation of tropical ocean surface chlorophyll by the Madden–Julian Oscillation

The MJO modulation of sea surface chlorophyll-a (Chl) examined initially by Waliser et al. in Geophys Res Lett, (2005) is revisited with a significantly longer time-series of observations and a more systematic approach to characterizing the possible mechanisms underlying the MJO-Chl relationships. The MJO composite analysis of Chl and lead-lag correlations between Chl and other physical variables reveal regional variability of Chl and corresponding indicative temporal relationships among variables. Along the path of the MJO convection, wind speed—a proxy for oceanic vertical turbulent mixing and corresponding entrainment—is most strongly correlated with Chl when wind leads Chl by a few days. Composite Chl also displays MJO influences away from the path of the MJO convection. The role of wind speed in those regions is generally the same for Chl variability as that along the path of the MJO convection, although Ekman pumping also plays a role in generating Chl variability in limited regions. However, the wind forcing away from the MJO convection path is less coherent, rendering the temporal link relatively weak. Lastly, the potential for bio-physical feedbacks at the MJO time-scale is examined. The correlation analysis provides tantalizing evidence for local bio-feedbacks to the physical MJO system. Plausible hypothesis for Chl to amplify the MJO phase transition is presented though it cannot be affirmed in this study and will be examined and reported in a future modeling study.     

The buckling of plastic oblate hemi-ellipsoidal dome shells under external hydrostatic pressure

The paper presents a theoretical and an experimental investigation into the buckling of seven oblate hemi-ellipsoidal dome shells under external hydrostatic pressure. Four of the shells were made in glass reinforced plastic and three were made from a thermosetting plastic called solid urethane plastic. All the vessels were tested to destruction. The theoretical study was made with the aid of a non-linear finite element solution, where both geometrical and material non-linearity were allowed for. Good agreement was found between experiment and theory for all the vessels. The very oblate domes failed axisymmetrically. Theoretical convergence was good for the more oblate domes but it was not as good as for the less oblate domes. This may have been because the less oblate domes did not fail in a classical axisymmetric manner as was expected. This work is of much importance in ocean engineering.     

Volcano-tectonic controls and emplacement kinematics of the Iriga debris avalanches (Philippines)

Mt Iriga in southeastern Luzon is known for its spectacular collapse scar that was possibly created in 1628 ad by a 1.5-km³ debris avalanche. The debris avalanche deposit (DAD) covered 70?km² and dammed the Barit River to form Lake Buhi. The collapse has been ascribed to a non-volcanic trigger related to a major strike-slip fault under the volcano. Using a combination of fieldwork and remote sensing, we have identified a similar size, older DAD to the southwest of the edifice that originated from a sector oblique to the underlying strike-slip fault. Both deposits cover wide areas of low, waterlogged plains, to a distance of about 16?km for the oldest and 12?km for the youngest. Hundreds of metre-wide and up to 50-m-high hummocks of intact conglomerate, sand and clay units derived from the base of the volcano show that the initial failure planes cut deep into the substrata. In addition, large proportions of both DAD consist of ring-plain sediments that were incorporated by soft-sediment bulking and extensive bulldozing. An ignimbrite unit incorporated into the younger DAD forms small (less than 5?m high) discrete hummocks between the larger ones. Both debris avalanches slid over water-saturated soft sediment or ignimbrite and spread out on a basal shear zone, accommodated by horst and graben formation and strike-slip faults in the main mass. The faults are listric and flatten into a well-developed basal shear zone. This shear zone contains components from the substrate and has a diffuse contact with the intact substrata. Long, transport-normal ridges in the distal parts are evidence of compression related to deceleration and bulldozing. The collapse orientation and structure on both sectors and DAD constituents are consistent with collapse being a response to combined transtensional faulting and gravity spreading. Iriga can serve as a model for other volcanoes, such as Mayon, that stand in sedimentary basins undergoing transtensional strike-slip faulting.     

Magma yield stress and permeability: Insights from multiphase percolation theory

Magmas often contain multiple interacting phases of embedded solid and gas inclusions. Multiphase percolation theory provides a means of modeling assemblies of these different classes of magmatic inclusions in a simple, yet powerful way. Like its single phase counterpart, multiphase percolation theory describes the connectivity of discrete inclusion assemblies as a function of phase topology. In addition, multiphase percolation employs basic laws to distinguish separate classes of objects and is characterized by its dependency on the order in which the different phases appear. This paper examines two applications of multiphase percolation theory: the first considers how the presence of bubble inclusions influences yield stress onset and growth in a magma's crystal network; the second examines the effect of bi-modal bubble-size distributions on magma permeability. We find that the presence of bubbles induces crystal clustering, thereby 1) reducing the percolation threshold, or critical crystal volume fraction, ?_c, at which the crystals form a space-spanning network providing a minimum yield stress, and 2) resulting in a larger yield stress for a given crystal volume fraction above ?_c. This increase in the yield stress of the crystal network may also occur when crystal clusters are formed due to processes other than bubble formation, such as heterogeneous crystallization, synneusis, and heterogeneity due to deformation or flow. Further, we find that bimodal bubble size distributions can significantly affect the permeability of the system beyond the percolation threshold. This study thus demonstrates that larger-scale structures and topologies, as well as the order in which different phases appear, can have significant effects on macroscopic properties in multiphase materials.     

Burying receivers for improved time‐lapse seismic repeatability: CO2CRC Otway field experiment

4D seismic is widely used to remotely monitor fluid movement in subsurface reservoirs. This technique is especially effective offshore where high survey repeatability can be achieved. It comes as no surprise that the first 4D seismic that successfully monitored the CO₂ sequestration process was recorded offshore in the Sleipner field, North Sea. In the case of land projects, poor repeatability of the land seismic data due to low S/N ratio often obscures the time‐lapse seismic signal. Hence for a successful on shore monitoring program improving seismic repeatability is essential. Stage 2 of the CO2CRC Otway project involves an injection of a small amount (around 15,000 tonnes) of CO₂/CH₄ gas mixture into a saline aquifer at a depth of approximately 1.5 km. Previous studies at this site showed that seismic repeatability is relatively low due to variations in weather conditions, near surface geology and farming activities. In order to improve time‐lapse seismic monitoring capabilities, a permanent receiver array can be utilised to improve signal to noise ratio and hence repeatability. A small‐scale trial of such an array was conducted at the Otway site in June 2012. A set of 25 geophones was installed in 3 m deep boreholes in parallel to the same number of surface geophones. In addition, four geophones were placed into boreholes of 1–12 m depth. In order to assess the gain in the signal‐to‐noise ratio and repeatability, both active and passive seismic surveys were carried out. The surveys were conducted in relatively poor weather conditions, with rain, strong wind and thunderstorms. With such an amplified background noise level, we found that the noise level for buried geophones is on average 20 dB lower compared to the surface geophones. The levels of repeatability for borehole geophones estimated around direct wave, reflected wave and ground roll are twice as high as for the surface geophones. Both borehole and surface geophones produce the best repeatability in the 30–90 Hz frequency range. The influence of burying depth on S/N ratio and repeatability shows that significant improvement in repeatability can be reached at a depth of 3 m. The level of repeatability remains relatively constant between 3 and 12 m depths.     

Physical sedimentology experiments with sulfuric acid solutions: Implications for Mars?

Physical sedimentology experiments have shown that sulfuric acid solutions may have formed some surface features seen on Mars. Recent data returned from Mars show the presence of jarosite, sulfate salts, hematite, phyllosilicates, and opaline silica, all of which precipitate from some terrestrial sulfuric acid solutions. There is a plethora of geochemical, mineralogical, and sedimentological data indicative of past sulfuric acid systems on Mars, but there has never been a comprehensive study published regarding sulfuric acid as a physical sedimentological agent. In the laboratory, we ran liquids of various compositions over sediments in order to test how these liquids entrain, transport, and deposit sediments. Pure water and concentrated sulfuric acid solutions produced the same general features, such as channels, gullies, and alluvial fans. However, sulfuric acid solutions yielded some distinct sedimentary features not produced by pure water runs. These features, narrow, deeply incised channels of consistent widths, rounded discrete fans, and air bubble “craters”, are similar to some Martian landscape features. These experimental results indicate that acid solutions should be considered a possible sedimentological agent on Mars.     

Integration of remote sensing data into hydrological models for reservoir management

Abstract

The purpose of this paper is to present the methodology set up to derive catchment soil moisture from Earth Observation (EO) data using microwave spaceborne Synthetic Aperture Radar (SAR) images from ERS satellites and to study the improvements brought about by an assimilation of this information into hydrological models. The methodology used to derive EO data is based on the appropriate selection of land cover types for which the radar signal is mainly sensitive to soil moisture variations. Then a hydrological model is chosen, which can take advantage of the new information brought by remote sensing. The assimilation of soil moisture deduced from EO data into hydrological models is based principally on model parameter updating. The main assumption of this method is that the better the model simulates the current hydrological system, the better the following forecast will be. Another methodology used is a sequential one based on Kalman filtering. These methods have been put forward for use in the European AIMWATER project on the Seine catchment upstream of Paris (France) where dams are operated to alleviate floods in the Paris area.