Coulometric TCO2 analyses for marine studies; an introduction

Progress in the introduction of coulometry for the analysis of total carbon dioxide (TCO₂) in marine waters is described. An extractor—stripper removes CO₂ that is measured coulometrically by the quantity of electricity (coulombs) used to electrogenerate OH^? ions for the titration of the acid formed by the reaction of CO₂ and ethanolamine. The equivalence point is detected photometrically with thymolphthalein as the indicator, and Faraday's Law relates coulombs to equivalents of titrant generated and CO₂ determined so that there are no standard curves needed or titrants to standardize or store. Accuracy was determined by adding gelatin capsules containing 100–1500 μg C of pure CaCO₃ into the stripper, and accuracies of better than ± 1 μg C were achieved. The best precision for natural seawater (± 1 standard error) of ± 0.5 μmol l^?1 was found for 17 samples of Bermuda coastal waters having a mean TCO₂ of 2007.2 μmol l^?1 (0.05% CV). Sources of error and precautions are discussed. This method, which has been used successfully at sea, can be used to study a variety of marine phenomena involving TCO₂.     

Kinetic studies of lead(II) uptake by the seagrass Zostera muelleri in water by radiotracing,atomic absorption spectrometry and electrochemical techniques

Evidence was found that uptake of lead from seawater in both model and natural systems by the leaves of the seagrass Zostera muelleri does occur for live, dead and scraped leaves at all the lead concentrations tested. Positive uptake of lead was measured using the three analytical techniques of radio-tracer, differential pulse anodic stripping voltammetry and atomic absorption spectrometry; similar uptake profiles were obtained for each technique. Profiles always showed an initial rapid uptake phase followed by a gradual transition to a plateau phase at which an approximate equilibrium between lead attached to seagrass and free ionic lead in seawater was reached. The presence of active lead uptake processes was indicated in experiments which attempted to remove lead from leaves by a chelating agent.     

Chronology and evolution of the northern Iceland Plateau

New aeromagnetic data, K-Ar age determinations of dredged marine igneous rocks, as well as other geophysical evidence have shed light on the chronology, nature and evolution of the northern Iceland Plateau. Correspondence between seismic refraction profiles taken on the Jan Mayen Ridge and westward through Jan Mayen Island, suppressed aeromagnetic anomalies, earthquake surface wave studies, and ages of dredged igneous rocks suggest these strata may form an extended region of thickened crust, possibly of Caledonian age, extending westward toward the Kolbeinsey Ridge and northwest to the south wall of the Jan Mayen Fracture Zone.     

Characterization of soil's structural crust by spectral reflectance in the SWIR region (1.2–2.5 μm)

Structural crust is a thin layer formed on the soil surface after a rainstorm. The crust is the result of a physical segregation and rearrangement of soil particles in a way that affects some of the soil properties, such as infiltration, runoff and soil erosion. In practice, there is no rapid, in situ method for monitoring, assessing and mapping crust intensity and quality. In this study, a controlled spectral investigation of the structural crust across the NIR–SWIR spectral region was conducted on three selected Israeli soils, to study the potential of reflectance radiation to detect structural crust in soils. Two major factors served as the driving forces for this study: (1) there is no valid method for in situ assessment of the crust's characteristics in the agriculture field, and (2) the crust might bias thematic remote sensing of soils, because the thin layer of crust blocks photon–matter interaction, which represents the relevant soil body. Through the use of a laboratory rainfall simulator and a sensitive spectrometer, it was revealed that for three selected soils, significant spectral differences occurred between the crust and its bulk soil. The spectral information was found to be related to changes in particle size distribution and texture at the surface of the soil. This conclusion was based on indications of absorption of OH in clay lattice, OH in adsorbed water and CO₃ in carbonates. It was concluded that the structural crust is a phenomenon that should not be ignored by remote-sensing users. In fact, in the field of agriculture, the spectral properties of crust can be used as tools for estimating the crust's intensity.     

About Darcy's law in non-Galilean frame

This paper is aimed towards investigating the filtration law of an incompressible viscous Newtonian fluid through a rigid non-inertial porous medium (e.g. a porous medium placed in a centrifuge basket). The filtration law is obtained by upscaling the flow equations at the pore scale. The upscaling technique is the homogenization method of multiple scale expansions which rigorously gives the macroscopic behaviour and the effective properties without any prerequisite on the form of the macroscopic equations. The derived filtration law is similar to Darcy's law, but the tensor of permeability presents the following remarkable properties: it depends upon the angular velocity of the porous matrix, it verifies Hall–Onsager's relationship and it is a non-symmetric tensor. We thus deduce that, under rotation, an isotropic porous medium leads to a non-isotropic effective permeability. In this paper, we present the results of numerical simulations of the flow through rotating porous media. This allows us to highlight the deviations of the flow due to Coriolis effects at both the microscopic scale (i.e. the pore scale), and the macroscopic scale (i.e. the sample scale). The above results confirm that for an isotropic medium, phenomenological laws already proposed in the literature fails at reproducing three-dimensional Coriolis effects in all types of pores geometry. We show that Coriolis effects may lead to significant variations of the permeability measured during centrifuge tests when the inverse Ekman number Ek⁻¹ is 𝒪(1). These variations are estimated to be less than 5% if Ek⁻¹<0.2, which is the case of classical geotechnical centrifuge tests. We finally conclude by showing that available experimental data from tests carried out in centrifuges are not sufficient to determining the effective tensor of permeability of rotating porous media. Copyright © 2004 John Wiley & Sons, Ltd.     

Deep-ocean vertical noise directionality

The structure of beam noise measured at the output of a vertical array in a range dependent ocean basin was investigated using the modified wide-angle parabolic equation (PE). Noise sources were distributed throughout the basin, and the field due to each noise source at an array located in the midbasin was calculated. The response of the array to the superposition of the noise sources was found by beamforming. An efficient and direct approach that superimposes the noise sources on the PE field as the field is marched toward the array was developed. Downslope calculations of the midbasin vertical directionality were made between 50 and 400 Hz with this technique. Use of a geoacoustic model shows that the bottom behaves as a low-pass filter     

Inverted echo sounder measurement of dynamic height through an ENSOcycle in the central equatorial Pacific

A four-year record from an inverted echo sounder deployed near Palmyra Island at 6°N in the central Pacific Ocean is compared with a simultaneous record of subsurface pressure from this island lagoon. A factor m, converting round-trip acoustic travel time to surface dynamic height relative to a deep pressure level, was estimated from the ratio of the spectra of the two records in the energetic synoptic oscillation band. Year-to-year variation in m was not statistically significant. For the overall record, m was found to be -70±8 dynamic m/s, where the error bounds represent a 90% confidence interval. This is consistent with first-baroclinic-mode excitation