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871.
Silicate and sulfide melt inclusions from the andesitic Farallón Negro Volcanic Complex in NW Argentina were analyzed by laser ablation ICPMS to track the behavior of Cu and Au during magma evolution, and to identify the processes in the source of fluids responsible for porphyry-Cu-Au mineralization at the 600 Mt Bajo de la Alumbrera deposit. The combination of silicate and sulfide melt inclusion data with previously published geological and geochemical information indicates that the source of ore metals and water was a mantle-derived mafic magma that contained approximately 6 wt.% H2O and 200 ppm Cu. This magma and a rhyodacitic magma mixed in an upper-crustal magma chamber, feeding the volcanic systems and associated subvolcanic intrusions over 2.6 million years. Generation of the ore fluid from this magma occurred towards the end of this protracted evolution and probably involved six important steps: (1) Generation of a sulfide melt upon magma mixing in some parts of the magma chamber. (2) Partitioning of Cu and Au into the sulfide melt (enrichment factor of 10,000 for Cu) leading to Cu and Au concentrations of several wt.% or ppm, respectively. (3) A change in the tectonic regime from local extension to compression at the end of protracted volcanism. (4) Intrusion of a dacitic magma stock from the upper part of the layered magma chamber. (5) Volatile exsolution and resorption of the sulfide melt from the lower and more mafic parts of the magma chamber, generating a fluid with a Cu/Au ratio equal to that of the precursor sulfide. (6) Focused fluid transport and precipitation of the two metals in the porphyry, yielding an ore body containing Au and Cu in the proportions dictated by the magmatic fluid source. The Cu/S ratio in the sulfide melt inclusions requires that approximately 4,000 ppm sulfur is extracted from the andesitic magma upon mixing. This exceeds the solubility of sulfide or sulfate in either of the silicate melts and implies an additional source for S. The extra sulfur could be added in the form of anhydrite phenocrysts present in the rhyodacitic magma. It appears, thus, that unusually sulfur-rich, not Cu-rich magmas are the key to the formation of porphyry-type ore deposits. Our observations imply that dacitic intrusions hosting the porphyry–Cu–Au mineralization are not representative of the magma from which the ore-fluid exsolved. The source of the ore fluid is the underlying more mafic magma, and unaltered andesitic dikes emplaced immediately after ore formation are more likely to represent the magma from which the fluids were generated. At Alumbrera, these andesitic dikes carry relicts of the sulfide melt as inclusions in amphibole. Sulfide inclusions in similar dykes of other, less explored magmatic complexes may be used to predict the Au/Cu ratio of potential ore-forming fluids and the expected metal ratio in any undiscovered porphyry deposit.Editorial handling: B. Lehmann 相似文献
872.
This study uses radiometric analysis (210Pb and 137Cs) of short sediment cores with high-resolution sampling (1-cm interval) to trace sedimentation rates in the Nile Delta lagoons,
particularly since completion of the Aswan High Dam in 1964. A declining trend in 210Pbex as calculated by the CIC model is clearly identified in about 10 cm of the upper-core sediments from the lagoons of Manzala
and Edku, accompanied by two spikes of 137Cs in cores from the lagoons of Burullus and Edku. These findings illustrate average post-dam sedimentation rates ranging
from 0.22 to 0.27 cm a−1 in the lagoons, in contrast with those found previously based on low-resolution sampling. The lower sedimentation rates in
the lagoons are a consequence of a dramatic reduction in riverine sediment load to the coastal area as a result of the damming.
Although widespread erosion occurs along the open estuarine coast, the lagoon setting remains calmer than before due to coastal
diking and freshwater regulation in the delta plain in the past decades. This provides the possibility of continuously preserved
radiometric records in the less-bioturbated lagoon sediments. Dating individual layers using the CRS model has revealed increasing
sedimentation rates in Manzala and Burullus since the 1980s, which can largely be explained as a consequence of the reduction
in lagoon area due to intensifying reclamation. The post-dam sedimentation in the shrinking lagoons may have some adverse
ecological consequences due to finer sediment’s affinity with pollutants. These findings would shed light on the environmental
conservation and socioeconomic development in the Nile Delta region. 相似文献
873.
Alfredo Gallego Virginia L. Gemini Susana L. Rossi Carlos E. Gómez Gustavo D. Bulus Rossini Sonia E. Korol 《洁净——土壤、空气、水》2011,39(8):774-780
An indigenous bacterial strain of Delftia sp. capable of degrading 2,4‐dicholorophenol and an indigenous bacterial community that degrades 2,4,6‐trichlorophenol (TCP) were employed to inoculate continuous down‐flow fixed‐bed reactors. Continuous‐reactors were constructed from PVC employing hollow PVC cylinders as support material. Synthetic wastewater was prepared by dissolving the corresponding chlorophenol in non‐sterile groundwater. Biodegradation was evaluated by spectrophotometry, chloride release, GC, and microbial growth. Detoxification was evaluated by using Daphnia magna as test organism. Delftia sp. was able to remove an average of 95.6% of DCP. Efficiency in terms of chemical oxygen demand (COD) was of 88.9%. The indigenous bacterial community that degrades TCP reached an average efficiency of 96.5 and 91.6% in terms of compound and COD removal, respectively. In both cases stoichiometric removal of chloride and detoxification was achieved. When synthetic wastewater feed was cut off for 7 days, both reactors showed a fast recovery after inflow restarting, reaching average outlet concentration values within 36 h. The promising behavior of the microorganisms and the low cost of the reactors tested allow us to suggest their possible application to remediation processes. 相似文献
874.
The results of mass balance observations of the ice dome and measurements of the active layer thickness on the Fildes Peninsula, King George (Waterloo) Island, Western Antarctica are presented for the period of 2007 to 2019. The dynamics of the main meteorological parameters affecting the active layer thickness is determined. The numerical experiments based on the mathematical model are performed to determine the effects of various parameters on the active layer thickness. The calculated and measured values of the active layer thickness are compared. The thermal instability of permafrost in the study area in some years with high (above the means) summer air temperature is demonstrated. The climate cooling which started in the region in the recent years has increased the number of years with the positive ice mass balance. However, the positive ice mass balance has not yet become a dominant factor against a background of the negative balance in the previous years. 相似文献
875.
A geochemical evaluation of Niger Delta organic matter was carried out using supercritical fluid extraction (SFE) sample preparation
procedure. Comparison of geochemical significance of gas chromatographic data of rock extracts of SFE with those of Soxhlet
extraction method from previous studies was made in order to establish the usefulness of SFE in geochemical exploration. The
assessment of geochemical character of the rock samples from the comparison and interpretation of other geochemical parameters
were used to give more insights into understanding the source rocks characteristics of onshore and shelf portions of the Niger
Delta Basin. The results of the gas chromatographic (GC) analysis of the rock extracts across the lithostratigraphic units
show that Pr/Ph, Pr/nC17, Pr/nC18, CPI and odd/even preference ranged from 0.07 to 12.39, 0.04 to 6.66, 0.05 to 13.80, 0.12 to 8.4 and 0.06 to 8.12, respectively.
The Rock-Eval pyrolysis data and geochemical ratios and parameters calculated from the GC data showed that most of the samples
are mature and have strong terrestrial provenance while a few samples have strong marine provenance. The few marine source
rocks are located in the deeper depth horizon. Pr/Ph and standard geochemical plots indicate that most of samples were derived
from organic matter deposited in less reducing conditions, i.e. more of oxidizing conditions while a few samples have predominantly
influence of reducing conditions. The results of trace metal analysis of older samples from Agbada Formation also indicate
marine and mixed organic matter input deposited in less reducing conditions. The results obtained in this study are comparable
with those obtained from previous studies when Soxhlet extraction method was used and also indicated the presence of more
than one petroleum systems in the Niger Delta. 相似文献
876.
Ryoko Tokeshi Kaoru Ichikawa Satoshi Fujii Kenji Sato Shoichiro Kojima 《Journal of Oceanography》2007,63(4):711-720
A method to extract geostrophic current in the daily mean HF radar data in the Kuroshio upstream region is established by
comparison with geostrophic velocity determined from the along-track altimetry data. The estimated Ekman current in the HF
velocity is 1.2% (1.5%) and 48° (38°)-clockwise rotated with respect to the daily mean wind in (outside) the Kuroshio. Furthermore,
additional temporal smoothing is found necessary to remove residual ageostrophic currents such as the inertial oscillation.
After removal of the ageostrophic components, the HF geostrophic velocity agrees well with that from the altimetry data with
rms difference 0.14 (0.12) m/s in (outside) the Kuroshio. 相似文献
877.
The Epupa Metamorphic Complex constitutes the southwestern margin of the Congo Craton and is exposed in a hilly to mountainous terrain of northwestern Namibia, bordering the Kunene River and extending into southern Angola. It consists predominantly of granitoid gneisses which are migmatized over large areas. This migmatization locally led to anatexis and produced crustal-melt granites such as the Otjitanda Granite. We have undertaken reconnaissance geochemical studies and single zircon U–Pb SHRIMP and Pb–Pb evaporation dating of rocks of the Epupa Complex. The granitoid gneisses, migmatites and anatectic melts are similar in composition and constitute a suite of metaluminous to peraluminous, calc-alkaline granitoids, predominantly with volcanic arc geochemical signatures. The zircon protolith ages for the orthogneisses range from 1861 ± 3 to 1758 ± 3 Ma. Anatexis in the migmatitic Epupa gneisses was dated from a melt patch at 1762 ± 4 Ma, and the anatectic Otjitanda Granite has a zircon age of 1757 ± 4 Ma. Migmatization and anatexis therefore occurred almost immediately after granitoid emplacement and date a widespread high-temperature Palaeoproterozoic event at ∼1760 Ma which has not been recorded elswhere in northern Namibia. The Nd isotopic systematics of all dated samples are surprisingly similar and suggest formation of the protolith from a source region that probably separated from the depleted mantle about 2.4–2.0 Ga ago. A major Archaean component in the source area is unlikely. 相似文献
878.
Stable carbon isotope variations in northwest Europe during the last glacial–interglacial transition
Chris S. M. Turney David J. Beerling Douglas D. Harkness J. John Lowe E. Marian Scott 《第四纪科学杂志》1997,12(4):339-344
Stable carbon isotope data that span part of the last glacial–interglacial transition (ca. 14-9 ka 14C BP; ca. 15–11 ka cal. BP), and which derive from organ-specific plant macrofossils recovered from two lake sediment profiles in the UK and one in Norway, are compared. The recorded temporal variations show similar trends, which, over a millennial time-scale appear to parallel the main drift in δ18O as determined for the GRIP ice-core. It is postulated that some smaller scale variations in the δ13C profiles may reflect the shorter term oscillations in δ18O values evident in the GRIP record, although this is less certain. Overall, however, the results suggest that stable carbon isotope measurements based on organ-specific terrestrial plant macrofossils may provide (i) a means for establishing correlations between terrestrial successions and (ii) additional paleoenvironmental information, as the apparent ‘shadowing’ of the GRIP record indicates a common forcing mechanism for both Greenland δ18O and northwest European δ13C variations. From the evidence available we suggest that the recorded δ13C variations reflect fluctuations in air temperature and/or changes in water vapour pressure in the atmosphere. © 1997 John Wiley & Sons, Ltd. 相似文献
879.
A recently established technique for size fractionation of particulate matter in freshwaters, based on low volume filtration through Nuclepore filters in the field, has been applied to the study of Fe and Mn species in 3 freshwater lakes and a stream feeding one of the lakes. The technique has also been used in a series of laboratory experiments to provide further insight into the process of particle formation. The results are complemented with scanning electron microscope examination of the particles.The raw data are transformed into mass size distributions, which are generally unimodal, with the major part of the mass confined to a single log unit size range. These size distributions are compared and contrasted with a theoretical model of particle behaviour in a lake. The results suggest that particulate Fe and Mn behave according to particle theory. The observed size distributions represent a balance between hydraulic input/output, aggregation, and gravitational settling, as well as chemical precipitation and dissolution processes. Overall particle aggregation is shown to be a slow process in the waters examined, with a time constant of the order of days. There is evidence for a fairly stable particle regime in the 0.05–0.4 μm size range.Deviations from the unimodal distribution in the epilimnion of the lakes indicate the association of Fe, but not Mn, with phytoplankton. In the waters examined Mn was most frequently found in solution, while Fe was predominantly particulate. These findings are interpreted in terms of the differing redox behaviour of the metals. 相似文献
880.
M. C. Santos P. Vaníček W. E. Featherstone R. Kingdon A. Ellmann B. -A. Martin M. Kuhn R. Tenzer 《Journal of Geodesy》2006,80(12):691-704
Following our earlier definition of the rigorous orthometric height [J Geod 79(1-3):82–92 (2005)] we present the derivation and calculation of the differences between this and the Helmert orthometric height, which is embedded in the vertical datums used in numerous countries. By way of comparison, we also consider Mader and Niethammer’s refinements to the Helmert orthometric height. For a profile across the Canadian Rocky Mountains (maximum height of ~2,800 m), the rigorous correction to Helmert’s height reaches ~13 cm, whereas the Mader and Niethammer corrections only reach ~3 cm. The discrepancy is due mostly to the rigorous correction’s consideration of the geoid-generated gravity disturbance. We also point out that several of the terms derived here are the same as those used in regional gravimetric geoid models, thus simplifying their implementation. This will enable those who currently use Helmert orthometric heights to upgrade them to a more rigorous height system based on the Earth’s gravity field and one that is more compatible with a regional geoid model. 相似文献