Lang Trang Cave (Northern Vietnam): Pleistocene Mammalian Locality with Gigantopithecus Finds

Doklady Earth Sciences - Speleological, geological and paleontological characteristics of the Lang Trang cave in northern Vietnam are presented. Primates Gigantopithecus blacki von Koenigswald,...     

Die stratiforme Sulfidlagerstätte Walchen,Steiermark, Österreich: Geochemie und Genese

Zusammenfassung Die Neubearbeitung derstratiformen Sulfidlagerstätte Walchen bei Öblarn, Steiermark, offen-bart eine eisenbetonte submarin-exhalative Metallkonzentration in einem vulkano-sedimentären Rahmen. Dieser liegt heute in Form metamorpher Gesteine der untersten Grünschieferfazies vor. Mineralchemische Untersuchungen zeigen, daß die ehemalige intensivste metamorphe Überprägung der Lagerstätte im Bereich von 450°–500°C oberhalb 4 kb stattgefunden hat. Metavulkanite, vertreten durch Grünschiefer, lassen alkalibasaltische Affinität erkennen. Die vulkano-tektonische Position der Lagerstätte ist in einem intrakontinentalen Riftsystem zu sehen.

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The stratiform sulphide deposit at walchen, styria, austria: Geochemistry and genesis

Summary The Walchen deposit consists of a 1–2 m thick layer of massive to disseminated pyrite-pyrrhotite-chalcopyrite ore with an average grade of 1% Cu. It has been mined intermittently in the past. The ore horizon occurs within sericitic and quartzitic phyllites which carry intercalations with significant carbonate, garnet and graphite contents. The succession is of lower Paleozoic age and forms part of the Grauwackenzone, a volcano-sedimentary unit which separates the Central Alps from the Northern Calcareous Alps.The precursor rocks of the ore environment have been pelites and sandstones; greenschists occur in the hanging wall of the mineralization. Major and trace element analyses of greenschists reveal them as low-grade metamorphic equivalents of continental alkali basalts. Hydrothermal systems generated by volcanic activity were responsible for deposition of stratiform sulphides. The predominance of clastic sediments and the absence of stringer zones point towards a shallow depositional basin.Microprobe analyses of garnets from the ore environment reveal an increase in spessartine contents from 7 mol% in phyllites to 20 mol% in the vicinity of the ore horizon. Similar data have been reported from other stratabound base metal deposits (Broken Hill, N.S.W.; Kreuzeck Mountains, Austria; Gamsberg, South Africa); the manganese concentrations represent fossil manganese haloes.Pyrite carries minor Ni and Co (up to 0.03, respectively 0.3%), pyrrhotite averages 0.8% Ni and 0.1% Co, Fe-contents of sphalerite vary from 6.41–9.33%; Cd, In and Mn have not been recorded.Garnet-biotite pairs suggest maximum metamorphic temperatures of 450°–500°C: pressures of 4 to 5 kb have been estimated. The Walchen deposit is interpreted as the product of submarine exhalative processes in an incipient rift. It was affected by prograde metamorphism during the Variscan orogeny, and by retrograde affects during a later event. Isochemical metamorphism resulted in the preservation of a primary manganese halo.

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Organochlorine Pesticide Residues in Soils and Sediments of the Herbert and Burdekin River Regions, North Queensland – Implications for Contamination of the Great Barrier Reef

Organochlorine pesticides were widely used in the Australian sugarcane industry from the early 1950s until the late 1980s. Erosion of sugarcane soils and subsequent transport of sediment bound contaminants in river run-off to the Great Barrier Reef lagoon is a growing concern as the cane industry continues to expand. Organochlorine pesticide residues can be used as tracers to examine the worst-case scenario of the spatial extent to which currently used, though less persistent, organic agricultural pesticides might extend. The coastal alluvial flood-plains of the Herbert and Burdekin Rivers in North Queensland have sugarcane growing as the major coastal land-use. Sediment cores and surface sediment samples were collected from near-shore coastal regions of the Herbert and Burdekin Rivers. In addition, soil samples from cane-fields in the two catchments were collected. Analyses of the marine surface sediment samples and three sediment cores revealed the absence of detectable concentrations of organochlorine pesticides (<5 pg/g). However, easily detectable concentrations were found in the sugarcane soil samples (0.01–45 ng/g).     

New U-Pb ages of zircons in the Owk Shale (Kurnool Group) with reflections on proterozoic porcellanites in India

Felsic tuff beds with some presumed sedimentary components were reported from the Owk Shale (Kurnool Group; bearing Neoproterozoic fossils) in the upper part of the sedimentary succession in the Cuddapah basin in India by Saha and Tripathy (2012a). Our optical and SEM petrographic study of three thin sections, however, indicates that the parent samples are sandy mudstones with variable amounts of a felsic volcaniclastic component. New highquality U-Pb (SHRIMP and LA-MC-ICPMS) ages of 133 detrital zircon grains from a sample show that one grain is ca. 1880 Ma, one grain is ca. 3300 Ma, and the ages of the remaining 131 grains fall between 2690 Ma and 2429 Ma, the population averaging 2522 ± 36 Ma. The data indicate that the zircons are detrital grains derived from the ca. 2.5 Ga granitic/gneissic/greenstone basement of the Dharwar cratons that also host minor older Archean enclaves. The single 1880 Ma grain could have come from a ca. 1.9 Ga LIP. In the absence of any younger magmatic zircon, the absolute age of the Owk Shale remains elusive.     

Co-diagenesis of iron and phosphorus in hydrothermal sediments from the southern East Pacific Rise: Implications for the evaluation of paleoseawater phosphate concentrations

We present a detailed study of the co-diagenesis of Fe and P in hydrothermal plume fallout sediments from ∼19°S on the southern East Pacific Rise. Three distal sediment cores from 340-1130 km from the ridge crest, collected during DSDP Leg 92, were analysed for solid phase Fe and P associations using sequential chemical extraction techniques. The sediments at all sites are enriched in hydrothermal Fe (oxyhydr)oxides, but during diagenesis a large proportion of the primary ferrihydrite precipitates are transformed to the more stable mineral form of goethite and to a lesser extent to clay minerals, resulting in the release to solution of scavenged P. However, a significant proportion of this P is retained within the sediment, by incorporation into secondary goethite, by precipitation as authigenic apatite, and by readsorption to Fe (oxyhydr)oxides. Molar P/Fe ratios for these sediments are significantly lower than those measured in plume particles from more northern localities along the southern East Pacific Rise, and show a distinct downcore decrease to a depth of ∼12 m. Molar P/Fe ratios are then relatively constant to a depth of ∼35 m. The Fe and P speciation data indicate that diagenetic modification of the sediments is largely complete by a depth of 2.5 m, and thus depth trends in molar P/Fe ratios can not solely be explained by losses of P from the sediment by diffusion to the overlying water column during early diagenesis. Instead, these sediments are likely recording changes in dissolved P concentrations off the SEPR, possibly as a result of redistribution of nutrients in response to changes in oceanic circulation over the last 10 million years. Furthermore, the relatively low molar P/Fe ratios observed throughout these sediments are not necessarily solely due to losses of scavenged P by diffusion to the overlying water column during diagenesis, but may also reflect post-depositional oxidation of pyrite originating from the volatile-rich vents of the southern East Pacific Rise. This study suggests that the molar P/Fe ratio of oxic Fe-rich sediments may serve as a proxy of relative changes in paleoseawater phosphate concentrations, particularly if Fe sulfide minerals are not an important component during transport and deposition.     

Possible forerunners of droughts in agricultural areas of Russia

Considered is the regional index of anticyclonic circulation IpH taking account of the percentage of the area occupied by the significant positive anomalies of the geopotential at the level of 500 hPa for the main agricultural areas of Russia. Analyzed are the variations of the index in the 20th and 21st centuries using the NCEP/NCAR reanalysis data and the outputs of model experiments with the ECHAM5 climate model (Germany). Discussed is the possibility of revealing the drought forerunners using the combination of indices of anticyclonic circulation, quasi-biennial cyclicity in the wintertime equatorial stratosphere, and teleconnections.