Observations of OH maser lines at an 18-cm wavelength in 9P/Temper1 and Lulin C/2007 N3 comets with RT-22 at the Crimean Astrophysical Observatory

Investigations on OH maser lines in comets have been performed with the RT-22 at CrAO. The results of observations of 9P/Temper1 and Lulin C/2007 N3 comets in the OH molecule line at a wavelength of 18 cm are presented. An original technique for observation data analysis has been developed. The gas production rate of OH molecules in these comets is estimated.     

The role of prior model calibration on predictions with ensemble Kalman filter

This paper, based on a real world case study (Limmat aquifer, Switzerland), compares inverse groundwater flow models calibrated with specified numbers of monitoring head locations. These models are updated in real time with the ensemble Kalman filter (EnKF) and the prediction improvement is assessed in relation to the amount of monitoring locations used for calibration and updating. The prediction errors of the models calibrated in transient state are smaller if the amount of monitoring locations used for the calibration is larger. For highly dynamic groundwater flow systems a transient calibration is recommended as a model calibrated in steady state can lead to worse results than a noncalibrated model with a well-chosen uniform conductivity. The model predictions can be improved further with the assimilation of new measurement data from on-line sensors with the EnKF. Within all the studied models the reduction of 1-day hydraulic head prediction error (in terms of mean absolute error [MAE]) with EnKF lies between 31% (assimilation of head data from 5 locations) and 72% (assimilation of head data from 85 locations). The largest prediction improvements are expected for models that were calibrated with only a limited amount of historical information. It is worthwhile to update the model even with few monitoring locations as it seems that the error reduction with EnKF decreases exponentially with the amount of monitoring locations used. These results prove the feasibility of data assimilation with EnKF also for a real world case and show that improved predictions of groundwater levels can be obtained.     

Bildung bromhaltiger Desinfektionsnebenprodukte nach Chlorung von Bodenseewasser in Abhängigkeit von Aufbereitungsschritten und der Bromidkonzentration

Formation of Brominated Disinfection By-products after Chlorination of Water from Lake Constance Depending on Treatment Steps and Bromide Concentration The formation of halogenated disinfection by-products (DNP) (trihalomethanes (THM), haloacetic acids (HES), haloacetonitriles (HAN), haloketones (HKE) and chloropicrin (TCNM)) was studied after chlorination (0.5 mg/L) of raw water and drinking water from Lake Constance. The objectives of this study were to investigate the effect of bromide ion on the distribution of DNP-species resulting from chlorination and to draw up a bromide mass-balance. The treatment of water from Lake Constance with ozone decreased the formation of DNP about 35% and of total organic halogens (AOX) about 45%. This decline in DNP-formation is mainly due to the formation of chloroform, dichloro- and trichloroacetic acid. Though there is only a small amount of bromide (6.2 μg/L) in water from Lake Constance, about 32% of THM, 16% of HES, and 30% of HAN contained bromine after chlorination of treated water. The addition of bromide ion (up to 1 mg/L) shifted the DNP-composition to more brominated species. The distribution of the DNP-species depends on the initial molar bromide-to-chlorine ratio. A mathematic model showed the same pattern of DNP-species depending on the initial molar bromide-to-chlorine ratio that was observed experimentally in microstrained raw water and drinking water from Lake Constance. After chlorination of microstrained raw water, 27% of the bromide were incorporated in known DNP, 34% in unknown substances, and about 39% of bromide were not converted to organic bromine. After chlorination of treated water, only 16% of the bromide were incorporated in unknown substances, whereas 34% were found in known DNP. About 50% were found as bromide again. After addition of bromide (up to 25 μg/L) to ozonated and treated water from Lake Constance, between 60 and 72% of the bromide that had reacted after chlorination were found in analyzed low-molecular DNP.     

Archaeal Communities of Frozen Quaternary Sediments of Marine Origin on the Coast of Western Spitsbergen

Izvestiya, Atmospheric and Oceanic Physics - The archaeal composition of permafrost samples taken during the drilling of frozen marine sediments in the area of the Barentsburg coal mine on the east...     

Influence of wind upon water quality in Liverpool Bay

Comprehensive distribution patterns of physical and chemical characteristics have been obtained from a series of cruises in Liverpool Bay. The marked feature of these distributions was their temporal variability, suggesting that the surface residual circulation is also temporally variable. The influence of wind stress upon the circulation pattern and hence water quality of this sea area is illustrated.     

A regional model for studies of atmosphere-ice-ocean interaction in the western Arctic

Summary Asa step in the development of a fully coupled regional model of the atmosphere-ice-ocean system, atmospheric and sea ice models have been adapted to a western Arctic domain centered on the Bering Strait. Lateral boundary conditions derived from operational analyses drive the models through simulations on grids having horizontal resolutions of 21 km and 7 km. Sensitivities to the presence of sea ice are large after only 48 hours, by which time the surface temperatures in the Bering and Chukchi Seas are 10–15°C higher without sea ice than with sea ice. The temperatures, in turn, modify the fields of sea level pressure, surface wind and precipitation. By influencing the surface wind stress through the static static stability, the surface state feeds back to the surface momentum exchange, ice/ocean transport, and the rate of formation of new ice. The results also show a resolution-dependence of the surface winds, precipitation rates and new ice formation rates, particularly in areas in which the coastal configuration and topography are spatially complex. The experiments will be augmented by the implementation of an ocean model on the same grids.With 12 Figures     

Developing a modern pollen–climate calibration data set for Norway

Bjune, A. E., Birks, H. J. B., Peglar, S. M. & Odland, A. 2010: Developing a modern pollen–climate calibration data set for Norway. Boreas, Vol. 39, pp. 674–688. 10.1111/j.1502‐3885.2010.00158.x. ISSN 0300‐9483. Modern pollen–climate data sets consisting of modern pollen assemblages and modern climate data (mean July temperature and mean annual precipitation) have been developed for Norway based on 191 lakes and 321 lakes. The original 191‐lake data set was designed to optimize the distribution of the lakes sampled along the mean July temperature gradient, thereby fulfilling one of the most critical assumptions of weighted‐averaging regression and calibration and its relative, weighted‐averaging partial least‐squares regression. A further 130 surface samples of comparable taphonomy, taxonomic detail and analyst became available as a result of other projects. These 130 samples, all from new lakes, were added to the 191‐lake data set to create the 321‐lake data set. The collection and construction of these data sets are outlined. Numerical analyses involving generalized linear modelling, constrained ordination techniques, weighted‐averaging partial least‐squares regression, and two different cross‐validation procedures are used to asses the effects of increasing the size of the calibration data set from 191 to 321 lakes. The two data sets are used to reconstruct mean July temperature and mean annual precipitation for a Holocene site in northwest Norway and a Lateglacial site in west‐central Norway. Overall, little is to be gained by increasing the modern data set beyond about 200 lakes in terms of modern model performance statistics, but the down‐core reconstructions show less between‐sample variability and are thus potentially more plausible and realistic when based on the 321‐lake data set.     

Beitrag zur quantitativen Analyse von Mineralphasen mittels Röntgendiffraktion

Zusammenfassung Bei der Durchführung quantitativer Gemenge-Analysen mit Hilfe der Röntgendiffraktionsmethode kann man den Massenschwächungskoeffizienten (^*) verwenden, den man bei der Röntgenfluoreszenzanalyse Röhrenhauptlinienverfahren vonSchroll-Stepon erhalten hat. Er wird von der Wellenlänge der Röntgenfluoreszenzstreustrahlung auf die Wellenlänge der Diffraktionsröhre transformiert. Ein Intensitäts-Konzentrationsdiagramm, in dem die Intensität der gewählten Diffraktionslinie durch das Produkt von Intensität und dem jeweiligen Wert von ^* ersetzt wird, ergibt eine allgemeingültige Eichgerade. Als Beispiel werden Messungen an Zweistoffsystemen wie Magnesit-Quarz, Albit-Quarz, Calcit-Quarz, Stilpnomelan-Quarz und Siderit-Quarz angeführt.Die vorgeschlagene Methode ist für kombinierte Diffraktions- und Röntgenfluoreszenzanalysen sehr zweckmäßig.

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Summary Applicating the quantitative X-ray-diffraction-analysis für mixtures of minerals the use of the mass absorption coefficient (^*) is possible, which is received by the X-ray-fluorescence-analysis of the same sample following the method proposed by the authors. The mass absorption coefficients must be transformed to the new wave length of the X-ray-diffraction tube. In the intensity-concentration-diagram the intensity is substituted by the product of intensity and mass absorption coefficient. An uniform standard line is received, as the measurement of quartz shows in the systems of two-substances, such as magnesite-quartz, albite-quartz, calcite-quartz, stilpnomelan-quartz and siderite-quartz.The proposed method is very useful for the combined X-ray-diffraction and X-ray fluorescence analysis.

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Mit 6 Textabbildungen     

Ableitung der Magnitudengleichung für die Erdbebenstationen Wien und Graz und allgemeine Bemerkungen zur Magnitudenberechnung

Zusammenfassung Nach einer knappen Einführung in die Magnitudenberechnung wird über die Ableitung der Stationsgleichungen für Wien (12) und Graz (13) berichtet. Den Berechnungen lagen 158, bzw. 121 Erdbeben normaler Herdtiefe und von der GrößeM7,0 zugrunde. Für beide Stationskonstanten wurde der gleiche WertC=+0,15 gefunden. Die Tabelle 2 enthält 94 von beiden Stationen registrierte Erdbeben mit Angabe der UnterschiededM (=D) von Wien und Graz gegenüber denM-Werten von Pasadena.Verschiedene Schwierigkeiten, die bei der Aufstellung der maximalen Horizontalamplitude auftauchen können, werden besprochen und an Hand eines Beispieles (Tabelle 3) dargelegt. Ferner wird angedeutet, daß das letzte GliedD der Magnitudengleichung definitionsmäßig überlastet ist und daß eine Aufteilung nach den wirklich individuellen Eigenschaften und den Gruppeneigenschaften des Einzelbebens notwendig wäre. Alle Erdbeben aus einer bestimmten Region tragen gemeinsame Merkmale, jedes einzelne hat dazu einen eigenen Habitus.

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Summary After a short introduction into the computation of magnitude we show the derivation of the respective equations for Vienna (12) and Graz (13). The basis of the computations were 158, 121 respectively, teleseisms of normal depth of focus and of the magnitudeM7.0. The same value was found for both station constants, namelyC=+0.15. Table 2 contains 94 earthquakes recorded at both stations, showing the differencesdM (=D) of Vienna and Graz, in comparison with theM-values of Pasadena.Various difficulties that can arise by establishing the total horizontal amplitude, are considered and discussed by means of an example (Table 3). Further we find that the last termD of the equation of magnitude is overcharged according to the definition, and that a separation according to the really individual qualities and to the group qualities of each earthquake would be necessary. All earthquakes from a certain area have specified qualities, and in addition each one shows a special behaviour of its own.

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Résumé Après une introduction concise du calcul de magnitude on est informé sur les équations qui en dérivent et qui sont valables pour les stations de Vienne (12) et de Graz (13). Resp. 158 et 121 séismes d'une profondeur de foyer normale et de magnitudeM7.0 forment la base de ces calculs. Une valeur identiqueC=+0,15 a été trouvée comme constante des deux stations. Le tableau 2 contient 94 séismes, enregistrés par les deux stations, avec indication des différencesdM (=D) de Vienne et de Graz vis-à-vis des valeursM de Pasadena.Diverses difficultés qui peuvent surgir en établissant l'amplitude horizontale maximum, sont discutées et démontrées par un exemple (tableau 3). En outre on trouve que le dernier coefficientD de l'équation est «surchargé» selon la définition. Une distribution d'après les véritables qualités individuelles et d'après les qualités de groupe du séisme particulier serait nécessaire. Tous les séismes provenant d'une certaine région ont des propriétés communes, de plus chacun a son caractère particulier.