Geochemistry of Rare Earth Elements in Ferromanganese Micro- and Macronodules from the Pacific Nonproductive Zone

Ferromanganese micro- and macronodules in eupelagic clays at Site 35 of the South Basin were examined in order to check the REE distribution during the ferromanganese ore formation in nonproductive zones of the Pacific Ocean. We studied host sediments and their labile fraction, ferromanganese micronodules (fractions 50–100, 100–250, 250–500, and >500 m) from eupelagic clays (horizons 37–40, 105–110, 165–175, and 189–190 cm), and buried ferromanganese micronodules (horizons 64–68, 158–159, and 165–166 cm). Based on phase analysis data, the anomalous REE enrichment of eupelagic clays from Site 35 is related to the accumulation of rare earth elements in iron hydroxophosphates. The Ce concentration, generally linked to manganese oxyhydroxides, is governed by the oxidation of Mn and Ce in oceanic surficial waters. Micronodules (Mn/Fe = 0.7–1.6) inherit compositional features of the labile fraction of sediments. The Ce, Co, and Th concentrations depend on the micronodule dimension. The enrichment of micronodules in hydrogenic or hydrothermal substance is governed by their dimension and the dominant source of suspended oxyhydroxide material. The study of buried ferromanganese micronodules revealed general regularities in the compositional evolution of oxyhydroxide matrices of ferromanganese micro- and macronodules. The compositional variation of micro- and macronodules, relative to the labile fraction of sediments, in the Pacific nonproductive zone dramatically differs from the pattern in bioproductive zones, where micronodule compositions in larger fractions are similar to those in associated macronodules and labile fractions of the host sediment as a result of the more intense suboxidative diagenesis.     

Hydrocarbon Generation by the Rocks of the Bremer Formation in Adjacent Areas of the Nonvolcanic Passive Margins of Australia and Antarctica

This paper analyzes differences in the history of hydrocarbon (HC) generation by the rocks of the Bremer 1–6 formations in adjacent areas of the nonvolcanic passive continental margins of Australia and Antarctica. The problem is examined by the example of the numerical reconstruction of the burial and thermal history of two sedimentary sequences of approximately equal thicknesses: the section of well 19–2012 in the Bremer sub-basin of the southwestern margin of Australia and the section of pseudowell 2 in the adjacent area of the passive margin of Antarctica on seismic profile 5909 across the Mawson Sea. The asymmetry of Gondwana rifting in the region of interest resulted in asymmetry in the tectonic structure and development of adjacent areas of passive margins and, as a consequence, significantly different histories of HC generation by the rocks of the Bremer 1–6 formations in these areas. Modeling indicates that the rocks of the Bremer 1 and 2 formations are mainly gas-prone in the Bremer basin and can become oil-prone in the Mawson Sea region of the Antarctic margin. In contrast, according to modeling, the rocks of the Bremer 4 and 5 formations generate a minor amount of HC in the well 19–2012 area of the Bremer sub-basin and considerable amounts of heavy and light oil in the adjacent Antarctic margin area at pseudowell 2 in the Mawson Sea.     

Structure formation in the rift zones and in the tranvers offset of the spreading axes: Results of physical modeling

The paper presents the results of experimental modeling of the specific features in the structure formation within the rift zones and also within lateral displacements of the spreading axes such as transform faults and nontransform displacements. The experiments were conducted on materials consisting of liquid and solid hydrocarbons; the similarity conditions were taken into account.     

Determination of the platinum-group elements and gold in ferromanganese nodule reference material NOD-A-1

The concentrations of Ru, Pd, Ir, Pt, and Au were determined in a ferromanganese nodule reference sample NOD-A-1 by inductively coupled plasma mass-spectrometry. Sample preparation procedures include acid digestion and anion exchange preconcentration. Standard addition method was used to eliminate losses of the analyte during the chromatographic separation. The results are in agreement with previously published data. The low level of intermediate precision for Au between different subsamples of the same sample probably originates from the heterogeneous distribution of Au in ferromanganese nodules. The accumulation of PGE in ferromanganese nodules was studied using international reference samples.