Investigating the effect of data quality on time domain electromagnetic discrimination

Using field data and numerical simulations we investigate the effect of data quality on time domain electromagnetic discrimination. Data quality decreases when measurements contain responses not accounted for by our mathematical modelling. This can include instrument noise, inaccurately reported position and orientation information, geologic contributions to the signal, and loss of validity of the forward modelling. Survey design is critical to data quality in order to have sufficient sampling of data anomalies, and also to ensure that each target is illuminated such that both the axial and transverse components of the polarization can be excited and measured. For dipole model based discrimination algorithms, success is contingent upon the accuracy with which the components of the polarization tensor can be estimated. Field data from different survey modes are analysed to identify noise sources and provide quantitative estimates of the noise in each survey. Inversion results show that increased noise levels lead to greater spread in recovered parameters. Monte Carlo simulations are performed in order to investigate the importance of other data quality factors. Analysis of inversion results from the simulations show that anomaly size, signal to noise ratio, positioning error, line spacing and station spacing all play a role in the spread of recovered parameters. Through the analysis of our simulation results we propose a figure of merit as a means of quantifying different data quality factors with a single number and relate this number to the accuracy with which parameters can be estimated.     

S-33 constraints on the seawater sulfate contribution in modern seafloor hydrothermal vent sulfides

Sulfide sulfur in mid-oceanic ridge hydrothermal vents is derived from leaching of basaltic-sulfide and seawater-derived sulfate that is reduced during high temperature water rock interaction. Conventional sulfur isotope studies, however, are inconclusive about the mass-balance between the two sources because ³⁴S/³²S ratios of vent fluid H₂S and chimney sulfide minerals may reflect not only the mixing ratio but also isotope exchange between sulfate and sulfide. Here, we show that high-precision analysis of S-33 can provide a unique constraint because isotope mixing and isotope exchange result in different Δ³³S (≡δ³³S-0.515 δ³⁴S) values of up to 0.04‰ even if δ³⁴S values are identical. Detection of such small Δ³³S differences is technically feasible by using the SF₆ dual-inlet mass-spectrometry protocol that has been improved to achieve a precision as good as 0.006‰ (2σ).Sulfide minerals (marcasite, pyrite, chalcopyrite, and sphalerite) and vent H₂S collected from four active seafloor hydrothermal vent sites, East Pacific Rise (EPR) 9-10°N, 13°N, and 21°S and Mid-Atlantic Ridge (MAR) 37°N yield Δ³³S values ranging from −0.002 to 0.033 and δ³⁴S from −0.5‰ to 5.3‰. The combined δ³⁴S and Δ³³S systematics reveal that 73 to 89% of vent sulfides are derived from leaching from basaltic sulfide and only 11 to 27% from seawater-derived sulfate. Pyrite from EPR 13°N and marcasite from MAR 37°N are in isotope disequilibrium not only in δ³⁴S but also in Δ³³S with respect to associated sphalerite and chalcopyrite, suggesting non-equilibrium sulfur isotope exchange between seawater sulfate and sulfide during pyrite precipitation. Seafloor hydrothermal vent sulfides are characterized by low Δ³³S values compared with biogenic sulfides, suggesting little or no contribution of sulfide from microbial sulfate reduction into hydrothermal sulfides at sediment-free mid-oceanic ridge systems. We conclude that ³³S is an effective new tracer for interplay among seawater, oceanic crust and microbes in subseafloor hydrothermal sulfur cycles.     

Can we spot a neighborhood from the air? Defining neighborhood structure in Accra, Ghana

Slums are home to a large fraction of urban residents in cities of developing nations, but little attempt has been made to go beyond a simple slum/non-slum dichotomy, nor to identify slums more quantitatively than through local reputation. We use census data from Accra, Ghana, to create an index that applies the UN-Habitat criteria for a place to be a slum. We use this index to identify neighborhoods on a continuum of slum characteristics and on that basis are able to locate the worst slums in Accra. These do include the areas with a local reputation for being slums, lending qualitative validation to the index. We show that slums also have footprints that can be identified from data classified from satellite imagery. However, variability among slums in Accra is also associated with some variability in the land cover characteristics of slums.     

Paleoenvironmental proxy records from Lake Hovsgol, Mongolia, and a synthesis of Holocene climate change in the Lake Baikal watershed

Here we discuss paleoenvironmental evolution in the Baikal region during the Holocene using new records of aquatic (diatom) and terrestrial vegetation changes from Hovsgol, Mongolia's largest and deepest lake. We reconcile previous contradictory Baikal timescales by constraining reservoir corrections of AMS dates on bulk sedimentary organic carbon. Synthesis of the Holocene records in the Baikal watershed reveals a northward progression in landscape/vegetation changes and an anti-phase behavior of diatom and biogenic silica proxies in neighboring rift lakes. In Lake Baikal, these proxies appear to be responsive to annual temperature increases after 6 ka, whereas in Lake Hovsgol they respond to higher precipitation/runoff from 11 to 7 ka. Unlike around Lake Baikal, warmer summers between 6 and 3.5 ka resulted in the decline, not expansion, of forest vegetation around Lake Hovsgol, apparently as a result of higher soil temperatures and lower moisture availability. The regional climatic proxy data are consistent with a series of 500-yr time slice Holocene GCM simulations for continental Eurasia. Our results allow reevaluation of the concepts of ‘the Holocene optimum’ and a ‘maximum of the Asian summer monsoon’, as applied to paleoclimate records from continental Asia.     

Optically stimulated luminescence dating of late Holocene raised strandplain sequences adjacent to Lakes Michigan and Superior, Upper Peninsula, Michigan, USA

This study evaluates the accuracy of optically stimulated luminescence to date well-preserved strandline sequences at Manistique/Thompson bay (Lake Michigan), and Tahquamenon and Grand Traverse Bays (Lake Superior) that span the past ∼4500 yr. The single aliquot regeneration (SAR) method is applied to produce absolute ages for littoral and eolian sediments. SAR ages are compared against AMS and conventional ¹⁴C ages on swale organics. Modern littoral and eolian sediments yield SAR ages <100 yr indicating near, if not complete, solar resetting of luminescence prior to deposition. Beach ridges that yield SAR ages <2000 yr show general agreement with corresponding ¹⁴C ages on swale organics. Significant variability in ¹⁴C ages >2000 cal yr B.P. complicates comparison to SAR ages at all sites. However, a SAR age of 4280 ± 390 yr (UIC913) on ridge77 at Tahquamenon Bay is consistent with regional regression from the high lake level of the Nipissing II phase ca. 4500 cal yr B.P. SAR ages indicate a decrease in ridge formation rate after ∼1500 yr ago, likely reflecting separation of Lake Superior from lakes Huron and Michigan. This study shows that SAR is a credible alternative to ¹⁴C methods for dating littoral and eolian landforms in Great Lakes and other coastal strandplains where ¹⁴C methods prove problematic.     

Mapping the geometry of an aquifer system with a high-resolution reflection seismic profile

A high-resolution P-wave seismic reflection survey was conducted in the area of Lambro Park within the city of Milan (northern Italy). Several high permeability channel sequences were identified and the stratigraphy of the infill was accurately mapped. The seismic signature imaged a previously undefined unit and also established the lateral correlation of some depositional units within the three major aquifer groups along the survey line. The complexity of the acoustic framework and the reduced depth of the source location limited effective elastic-wave generation. The geological setting also caused propagation of strong coherent noise patterns. Further interference, observed in the recorded data, was due to the traffic noise from the nearby highway. The attenuation of the undesired events required the design of specific filters and their multistep implementation. The results of forward modelling based on borehole information and of noise tests were crucial factors in the design of the processing parameters and in the stratigraphic interpretation of the final stacked section.     

Diffusive Oxygen Emitters for Enhancement of Aerobic In Situ Treatment

Aerobic biodegradation can be enhanced within contaminant plumes by elevating typically low dissolved oxygen (D.O.) levels using materials or devices that passively release oxygen. We have developed passive devices that provide a uniform, steady, long-term source of oxygen by diffusion from pressurized polymeric tubing and report test results under lab and field conditions. Lab flow-through reactor tests were conducted to determine the diffusion coefficient (D) of oxygen through four readily available tubing materials. Oxygen diffusion was greatest through Tygon® 3350 platinum-cured silicone (D = 6.67 ± 10^-7 cm²/sec), followed by 2075 Ultra Chemical Resistant Tygon (1.59 ± 10^-7 cm²/sec), 2275 High Purity Tygon (5.11 ± 10^-8 cm²/sec), and low-density polyethylene (LDPE; 1.73 ± 10^-8 cm²/sec). Variable-pressure release tests with LDPE resulted in very close estimates of D, which confirmed that mass transfer is controlled by diffusion and that the concentration gradient is a valid approximation of the chemical potential driving diffusion. LDPE emitter devices were designed and installed in seven 8-inch-diameter well screens across a portion of a gasoline plume at a former service station. With the devices pressurized to 620.5 kPag (kilopascals gauge) late in the test, steady-state D.O. concentrations reached as high as 25 mg/L, comparing favorably to the value predicted using the mass-transfer coefficient estimated from the lab test (26.3 mg/L). The method can also be used to release other gases for other reasons: gaseous tracers (i.e., sulphur hexafluoride, helium, and argon), hydrogen (for reductive dechlorination), or light alkanes (for cometabolic biodegradation of methyl tertiary butyl ether [MTBE] or chlorinated solvents).     

A Simple Way to Model Nonsynchronous Generation of Oil and Gas from Kerogen

Many kinetic models for oil and gas generation use the same kinetics for generation of both oil and gas. In these models, gas is generated at precisely the same time as oil, despite agreement among geochemists that oil generation in nature largely precedes gas generation. Here we present a method for deriving separate kinetics for oil generation and gas generation from the available kinetics for total hydrocarbon generation. The method is based on published data in which oil kinetics are compiled separately from gas kinetics, but it is generalized to be applicable to any of the main kerogen types (I, IIa, IIb, or III), or to any mixtures of those types. Application of this new nonsynchronous model shows that the traditional synchronous models overpredict gas generation by about a factor of two within the oil window, and conversely severely underpredict late gas generation. The nonsynchronous model may predict gas generation several tens of million years later than does the synchronous model. The errors inherent in the synchronous models can be of significance in exploration decisions.     

Mid-Holocene Glacier Peak and Mount St. Helens We Tephra Layers Detected in Lake Sediments from Southern British Columbia Using High-Resolution Techniques

A Glacier Peak tephra has been found in the mid-Holocene sediment records of two subalpine lakes, Frozen Lake in the southern Coast Mountains and Mount Barr Cirque Lake in the North Cascade Mountains of British Columbia, Canada. The age–depth relationship for each lake suggests an age of 5000–5080 ¹⁴C yr B.P. (5500–5900 cal yr B.P.) for the eruption which closely approximates the estimated age (5100–5500 ¹⁴C yr B.P.) of the Dusty Creek tephra assemblage found near Glacier Peak. The tephra layer, which has not been reported previously from distal sites and was not readily visible in the sediments, was located using contiguous sampling, magnetic susceptibility measurements, wet sieving, and light microscopy. The composition of the glass in pumice fragments was determined by electron microprobe analysis and used to confirm the probable source of this mid-Holocene tephra layer. Using the same methods, the A.D. 1481–1482 Mount St. Helens We tephra layer was identified in sediments from Dog Lake in southeastern British Columbia, suggesting the plume drifted further north than previously thought. This high-resolution method for identifying tephra layers in lake sediments, which has worldwide application in tephrachronologic/paleoenvironmental studies, has furthered our knowledge of the timing and airfall distribution of Holocene tephras from two important Cascade volcanoes.