Experimental constraints on the origin and evolution of mildly alkalic basalts from the Kerguelen Archipelago, Southeast Indian Ocean

This experimental study examines the role of clinopyroxene fractionation on major element trends and alkalinity variations in mildly alkalic basalts from the Kerguelen Archipelago, Southeast Indian Ocean. Equilibrium crystallization experiments were carried out on a natural basalt (MgO=5 wt.%, alkalinity index=0.10) over a range of pressures (0–1.43 GPa) and water contents (nominally dry to hydrous, 1.2 wt.% H₂O) under relatively oxidizing conditions (Δlog FMQ=+1 to +2) at 0 GPa and relatively reducing conditions (Δlog FMQ=0 to –2) at all higher pressures. The hydrous experiments at 0.93 GPa closely reproduce most of the compositional variations in the 24–25 Ma mildly alkalic lavas from the archipelago, which supports a major role for high-Al clinopyroxene fractionation (5–9 wt.% Al₂O₃) at pressures corresponding to the base of the Northern Kerguelen Plateau (15–20 km). However, clinopyroxene fractionation at depth fails to produce important changes in the alkalinity of the residual melts. The transition from tholeiitic to mildly alkalic basalts on the Kerguelen Archipelago thus reflects primarily changes in melting conditions (lower extents of partial melting at higher pressures), which is related to crustal and lithospheric thickening as distance from the Southeast Indian Ridge increased over time from 43 to 24 Ma.     

Electrokinetic control of nitrate movement in soil

Nitrate contamination of surface and groundwater has become a serious concern in many agricultural areas throughout the world. Nitrate fertilization is widely used to increase crop yields and quality, but nitrates are highly soluble in water with low retention by soils. Appropriate nitrate application practices can minimize losses, but untimely rainfall can foil management intent. A small dc electrical input has previously been reported to influence nitrate movement in wet soil. Two sets of lysimeter experiments were conducted to evaluate the effect of parallel electrodes on pH and nitrate distribution in field soils subjected to an electrical input. In one experiment, drip irrigation with injected nitrate application was used to grow Sudan grass; in the other, nitrate distribution in wet soil was observed after application of varying levels of electrical current. Increased nitrate concentration, reduced sodium and calcium concentration and lower pH values near the anode, the expected results, were not attained consistently in the test soils with an electrical input of 100–700 mA. The evaluation is being continued with simpler, more controlled conditions in soil column laboratory experiments.     

Partitioning of lanthanides and Y between immiscible silicate and fluoride melts, fluorite and cryolite and the origin of the lanthanide tetrad effect in igneous rocks

Some F-rich granitic rocks show anomalous, nonchondritic ratios of Y/Ho, extreme negative Eu anomalies, and unusual, discontinuous, segmented chondrite-normalised plots of rare earth elements (REE). The effects of F-rich fluids have been proposed as one of the explanations for the geochemical anomalies in the evolved granitic systems, as the stability of nonsilicate complexes of individual rare earths may affect the fluid-melt element partitioning. The lanthanide tetrad effect, related to different configurations of 4f-electron subshells of the lanthanide elements, is one of the factors affecting such complexing behaviour. We present the first experimental demonstration of the decoupling of Y and Ho, and the tetrad effect in the partitioning of rare earths between immiscible silicate and fluoride melts. Two types of experiments were performed: dry runs at atmospheric pressure in a high-temperature centrifuge at 1100 to 1200°C, and experiments with the addition of H₂O at 700 to 800°C and 100 MPa in rapid-quench cold-seal pressure vessels. Run products were analysed by electron microprobe (major components), solution-based inductively coupled plasma mass spectrometry (ICP-MS) (REE in the centrifuged runs), and laser ablation ICP-MS (REE and Li in the products of rapid-quench runs). All the dry centrifuge runs were performed at super-liquidus, two-phase conditions. In the experiments with water-bearing mixtures, minor amounts of aqueous vapour were present in addition to the melts. We found that lanthanides and Y concentrated strongly in the fluoride liquids, with two-melt partition coefficients reaching values as high as 100-220 in water-bearing compositions. In all the experimental samples, two-melt partition coefficients of lanthanides show subtle periodicity consistent with the tetrad effect, and the partition coefficient of Y is greater than that of Ho. One of the mixtures also produced abundant fluorite (CaF₂) and cryolite (Na₃AlF₆) crystals, which enabled us to study fluorite-melt and cryolite-melt REE partitioning. REE concentrations in fluorite are high and comparable to those in the fluoride melt. However, fluorite-melt partition coefficients appear to depend mostly on ionic radii and show neither significant tetrad anomalies, nor differences in Y and Ho partitioning. In contrast, REE concentrations in cryolite are low (∼5-10 times lower than in the silicate melt), and cryolite-melt REE partitioning shows very strong tetrad and Y-Ho anomalies. Our results imply that Y-Ho and lanthanide tetrad anomalies are likely to be caused mainly by aluminofluoride complexes, and the tetrad REE patterns in natural igneous rocks can result from fractionation of F-rich magmatic fluids.     

Glass veins in the unequilibrated eucrite Yamato 82202

The unequilibrated eucrite Yamato 82202 (Y82202) contains a network of relatively thick (up to 1 mm in width) glass veins. The host of the meteorite represents a monomict breccia composed of volcanic rock that crystallized > 4.3 Ga ago as a lava flow on the surface of 4 Vesta. The veins formed 3.90 ± 0.04 Ga ago, probably as a result of frictional melting associated with impact, under conditions of low effective oxygen fugacity and higher sulfur fugacity. The glass contains disordered structural elements characteristic of pyroxene and feldspar, reminiscent of the eucritic target lithology. The unequilibrated pyroxenes of the volcanic host and the pristine character of the glass indicate that this meteoritic material did not experience significant thermal metamorphism after initial crystallization of the lava. Hence, it was not affected by regional metamorphism caused by burial to a significant depth or by long-term contact metamorphism associated with a thick lava flow, large intrusion, or hot layer of impact ejecta. The meteorite resided at a shallow depth (though not at the surface) on 4 Vesta or on one of the vestoids until it was ejected and traveled to Earth, probably with other HED materials that have ³⁶Ar exposure ages of ∼13 Ma. These data suggest that the surface of the asteroid 4 Vesta has significant, though probably small, proportions of glass, as well as unequilibrated volcanic rock.     

Self-organized complexity in geomorphology: Observations and models

The focus of this paper is to relate fundamental statistical properties of landforms and drainage networks to models that have been developed in statistical physics. Relevant properties and models are reviewed and a general overview is presented. Landforms and drainage networks are clearly complex, but well-defined scaling laws are found. Coastlines, topography contours, and lakes are classic self-similar fractals. The height of topography along a linear track is well approximated as a Brownian walk, a self-affine fractal. This type of behavior has also been found in surface physics, for example the surface roughness of a fracture. An applicable model is the Langevin equation, the heat equation with a stochastic white-noise driver. This model also reproduces the statistics of sediment deposition. Drainage networks were one of the original examples of self-similar fractal trees. An important advance in quantifying the structure of drainage networks is the application of the Tokunaga fractal side-branching statistics. A classic problem in statistical physics is the diffusion-limited aggregation. The resulting tree like structures have been shown to also satisfy the Tokunaga statistics. A modified version of the diffusion-limited aggregation model reproduces the statistics of drainage networks. It is concluded that the models developed in statistical physics have direct applicability to the fundamental problems in geomorphology.     

Liquid Immiscibility and the Evolution of Basaltic Magma

This experimental study examines relationships between alternativeevolution paths of basaltic liquids (the so-called Bowen andFenner trends), and silicate liquid immiscibility. Syntheticanalogues of natural immiscible systems exhibited in volcanicglasses and melt inclusions were used as starting mixtures.Conventional quench experiments in 1 atm gas mixing furnacesproved unable to reproduce unmixing of ferrobasaltic melts,yielding instead either turbid, opalescent glasses, or crystallizationof tridymite and pyroxenes. In contrast, experiments involvingin situ high-temperature centrifugation at 1000g (g = 9·8m/s²) did yield macroscopic unmixing and phase separation. Centrifugationfor 3–4 h was insufficient to complete phase segregation,and resulted in sub-micron immiscible emulsions in quenchedglasses. For a model liquid composition of the Middle Zone ofthe Skaergaard intrusion at super-liquidus temperatures of 1110–1120°C,centrifugation produced a thin, silicic layer (64·5 wt%SiO₂ and 7·4 wt% FeO) at the top of the main Fe-richglass (46 wt% SiO₂ and 21 wt% FeO). The divergent compositionsat the top and bottom were shown in a series of static runsto crystallize very similar crystal assemblages of plagioclase,pyroxene, olivine, and Fe–Ti oxides. We infer from theseresults that unmixing of complex aluminosilicate liquids maybe seriously kinetically hampered (presumably by a nucleationbarrier), and thus conventional static experiments may not correctlyreproduce it. In the light of our centrifuge experiments, immiscibilityin the Skaergaard intrusion could have started already at thetransition from the Lower to the Middle Zone. Thus, magma unmixingmight be an important factor in the development of the Fe-enrichmenttrend documented in the cumulates of the Skaergaard LayeredSeries. KEY WORDS: liquid immiscibility; Skaergaard; layered intrusions; experimental petrology     

Potential for global mapping of development via a nightsat mission

Nightsat is a concept for a satellite system capable of global observation of the location, form and density of lighted infrastructure and development within human settlements. Nightsat’s repeat cycle should be sufficient to produce an annual cloud-free composite of surface lighting to enable detection of growth rates. Airborne and satellite imagery have been used to define the range of spatial, spectral, and detection limit options for a future Nightsat mission. Our conclusion is that Nightsat should collect data from a near-synchronous orbit in the early evening with 50–100 m spatial resolution and have detection limits of 2.5E⁻⁸ W cm⁻² sr⁻¹ μm⁻¹ or better. Multispectral low-light imaging data would be better than panchromatic data by providing valuable information on the type or character of lighting, a potentially stronger predictor of variables such as ambient population density and economic activity.     

Coarse bed load transport in an alluvial gravel bed stream,Dupuyer Creek,Montana

Coarse bed load was sampled in a gravel/cobble bed stream during two major floods in the snowmelt runoff season. The channel is characterized by high rates of bank erosion and, therefore, high rates of sediment supply and bed load flux. Peak discharge reached four times bank‐full, and bed load was sampled at flows 0·7–1·7 times bank‐full. A large aperture bed load sampler (1 m by 0·45 m) captured the largest particles in motion, and specifically targeted the coarse bed load size distribution by using a relatively large mesh (32 mm or D₂₅ of streambed surface size distribution). Bed load flux was highly variable, with a peak value of 0·85 kg/s/m for the coarse fraction above 38 mm. Bed load size distribution and maximum particle size was related to flow strength. Entrainment was size selective for particles D₇₀ and larger (88–155 mm), while particles in the range D₃₀–D₇₀ (35–88 mm) ceased to move at essentially the same flow. Bed load flux was size selective in that coarse fractions of the streambed surface were under‐represented in or absent from the bed load. Painted tracer particles revealed that the streambed surface in the riffles could remain stable even during high rates of bed load transport. These observations suggest that a large proportion of bed load sediments was sourced from outside the riffles. Repeat surveys confirmed major scour and fill in pools (up to 0·75 m), and bank erosion (>2 m), which together contributed large volumes of sediment to the bed load. Copyright © 2007 John Wiley & Sons, Ltd.