Timescales and significance of high-pressure, high-temperature metamorphism and mafic dike anatexis, Snowbird tectonic zone, Canada

New geochronological, isotopic and geochemical data for a spectacular swarm of deep crustal migmatitic mafic dikes offer important insight into processes operative during 1.9 Ga high pressure, high temperature metamorphism along the Snowbird tectonic zone in northern Saskatchewan. High-precision U–Pb zircon dates reveal anatexis of Chipman mafic dikes at 1,896.2 ± 0.3 Ma during syntectonic and synmetamorphic intrusion at conditions of 1.0–1.2 GPa, >750°C. U–Pb zircon dates of 1,894–1,891 Ma for cross-cutting pegmatites place a lower bound on major metamorphism and deformation at the currently exposed crustal levels. The persistence of elevated temperatures for ~14 m.y. following peak conditions is implied by younger U–Pb titanite dates, and by Sm–Nd whole rock isotopic data that suggest the derivation of the pegmatites by melting of a mafic source. Limited melting of the host felsic gneiss at 1.9 Ga despite high temperature is consistent with evidence for their previous dehydration by granulite facies metamorphism in the Archean. Spatial heterogeneity in patterns of mafic dike and tonalitic gneiss anatexis can be attributed to lateral peak temperature and compositional variability. We correlate 1,896 Ma Chipman mafic dike emplacement and metamorphism with substantial 1.9 Ga mafic magmatism over a minimum along-strike extent of 1,200 km of the Snowbird tectonic zone. This suggests a significant, continent-wide period of asthenospheric upwelling that induced incipient continental rifting. Extension was subsequently terminated by hinterland contraction associated with Trans-Hudson accretion and orogenesis. Little activity in the lower crust for ca. 650 m.y. prior to Proterozoic metamorphism and mafic magmatism implies an extended interval of cratonic stability that was disrupted at 1.9 Ga. This episode of destabilization contrasts with the record of long-term stability in most preserved cratons, and is important for understanding the lithospheric characteristics and tectonic circumstances that control the destruction or survival of continents.     

Early Proterozoic syn-and postcollision granites in the northern part of the Baikal fold area

Early Proterozoic granitoids are of a limited occurrence in the Baikal fold area being confined here exclusively to an arcuate belt delineating the outer contour of Baikalides, where rocks of the Early Precambrian basement are exposed. Geochronological and geochemical study of the Kevakta granite massif and Nichatka complex showed that their origin was related with different stages of geological evolution of the Baikal fold area that progressed in diverse geodynamic environments. The Nichatka complex of syncollision granites was emplaced 1908 ± 5 Ma ago, when the Aldan-Olekma microplate collided with the Nechera terrane. Granites of the Kevakta massif (1846 ± 8 Ma) belong to the South Siberian postcollision magmatic belt that developed since ～1.9 Ga during successive accretion of microplates, continental blocks and island arcs to the Siberian craton. In age and other characteristics, these granites sharply differ from granitoids of the Chuya complex they have been formerly attributed to. Accordingly, it is suggested to divide the former association of granitoids into the Chuya complex proper of diorite-granodiorite association ～2.02 Ga old (Neymark et al., 1998) with geochemical characteristics of island-arc granitoids and the Chuya-Kodar complex of postcollision S-type granitoids 1.85 Ga old. The Early Proterozoic evolution of the Baikal fold area and junction zone with Aldan shield lasted about 170 m.y. that is comparable with development periods of analogous structures in other regions of the world.     

Paleoproterozoic accretion in the Northeast Siberian craton: Isotopic dating of the Anabar collision system

Geochronological database considered in the work and characterizing the Anabar collision system in the Northeast Siberian craton includes coordinated results of Sm-Nd and Rb-Sr dating of samples from crustal xenoliths in kimberlites, deep drill holes, and bedrock outcrops. As is inferred, collision developed in three stages dated at 2200–2100, 1940–1760, and 1710–1630 Ma. The age of 2000–1960 Ma is established for substratum of mafic rocks, which probably originated during the lower crust interaction with asthenosphere due to the local collapse of the collision prism. Comparison of Sm-Nd and Rb-Sr isochron dates shows that the system cooling from ≈700 to ≈300°C lasted approximately 300 m.y. with a substantial lag relative to collision metamorphism and granite formation. It is assumed that accretion of the Siberian craton resulted in formation of a giant collision mountainous structure of the Himalayan type that was eroded by 1.65 Ga ago, when accumulation of gently dipping Meso-to Neoproterozoic (Riphean) platform cover commenced.     

Mercury speciation and mobilization in contaminated soils of the Valle del Azogue Hg mine (SE,Spain)

Hg mobilization from contaminated soils and mine wastes was the source of environmental contamination in the Valle del Azogue mining area. We researched solid-phase speciation and aqueous mobility of Hg through Scanning electron microscopy-energy dispersive X-ray spectroscopy and electron probe microanalysis analysis, solid-phase-Hg-thermo-desorption (SPTD) and laboratory column experiments. We found that in contaminated soils and mine wastes, the predominant Hg species was cinnabar (HgS), mainly formed from the weathering of Hg-rich pyrite, and metallic Hg (0) in the matrix, whereas in calcines and tailings the dominant species was metallic Hg (0). The mobilization of Hg in the aqueous phase seems to have originated from the dissolution of elemental Hg (0) present in soils and wastes, reaching concentrations of up to 67 μg l⁻¹, and showing a higher long-term environmental potential risk, in addition to atmospheric emissions.     

Spatial assessment and redesign of a groundwater quality monitoring network using entropy theory, Gaza Strip, Palestine

Using entropy theory, a methodology was developed for the evaluation and redesign of groundwater quality monitoring wells in the Gaza Strip in Palestine. Essential to the methodology is the development of a Transinformation Model (TM) which yields the amount of information transfer and the dependency between the wells as a function of distance. The TM parameters, such as the minimum transinformation and the range, were employed for evaluating the network which revealed that most of the distances between wells were less than the range. It also indicated that a high percentage of redundant information existed in the network. Therefore, the network was reduced by superimposing a square pattern over the monitored area and selecting one well per square block in a stratified pattern. The methodology was tested using the chloride data collected from 1972–2000 from 417 groundwater quality monitoring wells in the Gaza Strip. The number of the groundwater quality monitoring wells in the Gaza Strip was reduced by 53%, while there was 26% redundant information based on the minimum existing distance between wells. This methodology is meant to help monitor the groundwater quality (salinity) in the Gaza Strip.     

Mixing and differentiation in the Oruanui rhyolitic magma, Taupo, New Zealand: evidence from volatiles and trace elements in melt inclusions

Large pyroclastic rhyolites are snapshots of evolving magma bodies, and preserved in their eruptive pyroclasts is a record of evolution up to the time of eruption. Here we focus on the conditions and processes in the Oruanui magma that erupted at 26.5 ka from Taupo Volcano, New Zealand. The 530 km³ (void-free) of material erupted in the Oruanui event is comparable in size to the Bishop Tuff in California, but differs in that rhyolitic pumice and glass compositions, although variable, did not change systematically with eruption order. We measured the concentrations of H₂O, CO₂ and major and trace elements in zoned phenocrysts and melt inclusions from individual pumice clasts covering the range from early to late erupted units. We also used cathodoluminescence imaging to infer growth histories of quartz phenocrysts. For quartz-hosted inclusions, we studied both fully enclosed melt inclusions and reentrants (connecting to host melt through a small opening). The textures and compositions of inclusions and phenocrysts reflect complex pre-eruptive processes of incomplete assimilation/partial melting, crystallization differentiation, magma mixing and gas saturation. ‘Restitic’ quartz occurs in seven of eight pumice clasts studied. Variations in dissolved H₂O and CO₂ in quartz-hosted melt inclusions reflect gas saturation in the Oruanui magma and crystallization depths of ∼3.5–7 km. Based on variations of dissolved H₂O and CO₂ in reentrants, the amount of exsolved gas at the beginning of eruption increased with depth, corresponding to decreasing density with depth. Pre-eruptive mixing of magma with varying gas content implies variations in magma bulk density that would have driven convective mixing. Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users.     

Ammonium regeneration in intertidal sediments of the Yangtze estuary during air-exposure

The influences of exposure to the atmosphere on ammonium cycle in the intertidal surface sediments were in situ studied with a geochemical approach at a typical station in the Yangtze Estuary during three tidal cycles in September 2003. During an about 8-h emersion period of each diurnal tide, six high-resolution vertical profiles of adsorbed and dissolved ammonium were measured. It was observed that both adsorbed and dissolved ammonium generally had an increasing trend in sediment cores during the exposure. The rate of ammonium regeneration in sediments was estimated using the accumulation amount of ammonium including adsorbed and soluble fractions during the daytime emersion. The calculation result showed that there was relatively high ammonification rate (˜500 nmol N cm⁻³ day⁻¹), which reflected that organic nitrogen in sediments was quickly decomposed with a residence time of ˜52.7 days. Due to the dramatic temperature difference observed in sediment profiles, free convection was considered an important mechanism of regulating the efflux of produced ammonium into overlying waters. The total estimated amount of regenerated ammonium was ˜1.35×10⁵ t N year⁻¹ in the intertidal flat of the Yangtze Estuary, which occupied 7.6% of the total inorganic nitrogen annually transported to the estuarine ecosystem.     

Effect of sampling and linkage on fault length and length–displacement relationship

The power-law exponent (n) in the equation: D=cL ⁿ , with D = maximum displacement and L = fault length, would be affected by deviations of fault trace length. (1) Assuming n=1, numerical simulations on the effect of sampling and linkage on fault length and length–displacement relationship are done in this paper. The results show that: (a) uniform relative deviations, which means all faults within a dataset have the same relative deviation, do not affect the value of n; (b) deviations of the fault length due to unresolved fault tip decrease the values of n and the deviations of n increase with the increasing length deviations; (c) fault linkage and observed dimensions either increase or decrease the value of n depending on the distribution of deviations within a dataset; (d) mixed deviations of the fault lengths are either negative or positive and cause the values of n to either decrease or increase; (e) a dataset combined from two or more datasets with different values of c and orders of magnitude also cause the values of n to deviate. (2) Data including 19 datasets and spanning more than eight orders of fault length magnitudes (10⁻²–10⁵ m) collected from the published literature indicate that the values of n range from 0.55 to 1.5, the average value being 1.0813, and the peak value of n _d (double regression) is 1.0–1.1. Based on above results from the simulations and published data, we propose that the relationship between the maximum displacement and fault length in a single tectonic environment with uniform mechanical properties is linear, and the value of n deviated from 1 is mainly caused by the sampling and linkage effects.