文县天池环境调查

根据文县天池首次实地科学考察资料，本文从自然地理，物理化学、生物及旅游诸方面论述了天池的基本特。     

The combined effect of F and H2O on interdiffusion between peralkaline dacitic and rhyolitic melts

The effective binary diffusion coefficient (EBDC) of silicon has been measured during the interdiffusion of peralkaline, fluorine-bearing (1.3 wt% F), hydrous (3.3 and 6 wt% H₂O), dacitic and rhyolitic melts at 1.0 GPa and temperatures between 1100°C and 1400°C. From Boltzmann-Matano analysis of diffusion profiles the diffusivity of silicon at 68 wt% SiO₂ can be described by the following Arrhenius equations (with standard errors): $$\begin{gathered} {\text{with 1}}{\text{.3 wt\% F and 3}}{\text{.3\% H}}_{\text{2}} {\text{O:}} \hfill \\ {\text{D}}_{{\text{Si}}} = \begin{array}{*{20}c} { + {\text{3}}{\text{.59}}} \\ {{\text{3}}{\text{.66}} \times {\text{10}}^{ - {\text{9}}} } \\ { - {\text{1}}{\text{.86}}} \\ \end{array} {\text{exp}}\left( {{{ - {\text{86}}{\text{.1}} \pm {\text{8}}{\text{.9}}} \mathord{\left/ {\vphantom {{ - {\text{86}}{\text{.1}} \pm {\text{8}}{\text{.9}}} {{\text{RT}}}}} \right. \kern-\nulldelimiterspace} {{\text{RT}}}}} \right) \hfill \\ {\text{with 1}}{\text{.3 wt\% F and 6}}{\text{.0\% H}}_{\text{2}} {\text{O:}} \hfill \\ {\text{D}}_{{\text{Si}}} = \begin{array}{*{20}c} { + {\text{3}}{\text{.59}}} \\ {{\text{3}}{\text{.51}} \times {\text{10}}^{ - {\text{8}}} } \\ { - {\text{1}}{\text{.77}}} \\ \end{array} {\text{exp}}\left( {{{ - {\text{109}}{\text{.5}} \pm {\text{8}}{\text{.9}}} \mathord{\left/ {\vphantom {{ - {\text{109}}{\text{.5}} \pm {\text{8}}{\text{.9}}} {{\text{RT}}}}} \right. \kern-\nulldelimiterspace} {{\text{RT}}}}} \right) \hfill \\ \end{gathered} $$ where D is in m²s^?1 and activation energies are in kJ/mol. Diffusivities measured at 64 and 72 wt% SiO₂ are only slightly different from those at 68 wt% SiO₂ and frequently all measurements are within error of each other. Silicon, aluminum, iron, magnesium, and calcium EBDCs were also calculated from diffusion profiles by error function inversion techniques assuming constant diffusivity. With one exception, silicon EBDCs calculated by error function techniques are within error of Boltzmann-Matano EBDCs. Average diffusivities of Fe, Mg, and Ca were within a factor of 2.5 of silicon diffusivities whereas Al diffusivities were approximately half those of silicon. Alkalies diffused much more rapidly than silicon and non-alkalies, however their diffusivities were not quantitatively determined. Low activation energies for silicon EBDCs result in rapid diffusion at magmatic temperatures. Assuming that water and fluorine exert similar effects on melt viscosity at high temperatures, the viscosity can be calculated and used in the Eyring equation used to determine diffusivities, typically to within a factor of three of those measured in this study. This correlation between viscosity and diffusivity can be inverted to calculate viscosities of fluorine- and water-bearing granitic melts at magmatic temperatures; these viscosities are orders of magnitude below those of hydrous granitic melts and result in more rapid and effective separation of granitic magmas from partially molten source rocks. Comparison of Arrhenius parameters for diffusion measured in this study with Arrhenius parameters determined for diffusion in similar compositions at the same pressure demonstrates simple relationships between Arrhenius parameters, activation energy-E_a, kJ/mol, pre-exponential factor-D_o, m²s^?1, and the volatile, X=F or OH^?, to oxygen, O, ratio of the melt {(X/X+O)}: $$\begin{gathered} {\text{E}}a = - {\text{1533\{ }}{{\text{X}} \mathord{\left/ {\vphantom {{\text{X}} {\left( {{\text{X}} + {\text{O}}} \right)}}} \right. \kern-\nulldelimiterspace} {\left( {{\text{X}} + {\text{O}}} \right)}}{\text{\} }} + {\text{213}}{\text{.3}} \hfill \\ {\text{D}}_{\text{O}} = {\text{2}}{\text{.13}} \times {\text{10}}^{ - {\text{6}}} {\text{exp}}\left[ { - {\text{6}}{\text{.5\{ }}{{\text{X}} \mathord{\left/ {\vphantom {{\text{X}} {\left( {{\text{X}} + {\text{O}}} \right)}}} \right. \kern-\nulldelimiterspace} {\left( {{\text{X}} + {\text{O}}} \right)}}{\text{\} }}} \right] \hfill \\ \end{gathered} $$ These relationships can be used to estimate diffusion in various melts of dacitic to rhyolitic composition containing both fluorine and water. Calculations for the contamination of rhyolitic melts by dacitic enclaves at 800°C and 700°C provide evidence for the virtual inevitability of diffusive contamination in hydrous and fluorine-bearing magmas if they undergo magma mixing of any form.     

Lithofacies modeling by multipoint statistics and economic evaluation by NPV volume for the early Cretaceous Wabiskaw Member in Athabasca oilsands area,Canada

The static modeling and dynamic simulation are essential and critical processes in petroleum exploration and development. In this study, lithofacies models for Wabiskaw Member in Athabasca, Canada are generated by multipoint statistics(MPS) and then compared with the models built by sequential indicator simulation(SIS). Three training images(Tls) are selected from modern depositional environments;the Orinoco River Delta estuary, Cobequid bay-Salmon River estuary, and Danube River delta environment. In order to validate lithofacies models, average and variance of similarity in lithofacies are calculated through random and zonal blind-well tests.In random six-blind-well test, similarity average of MPS models is higher than that of SIS model. The Salmon MPS model closely resembles facies pattern of Wabiskaw Member in subsurface. Zonal blind-well tests show that successful lithofacies modeling for transitional depositional setting requires additional or proper zonation information on horizontal variation, vertical proportion, and secondary data.As Wabiskaw Member is frontier oilsands lease, it is impossible to evaluate the economics from production data or dynamic simulation. In this study, a dynamic steam assisted gravity drainage(SAGD)performance indicator(SPIDER) on the basis of reservoir characteristics is calculated to build 3 D reservoir model for the evaluation of the SAGD feasibility in Wabiskaw Member. SPIDER depends on reservoir properties, economic limit of steam-oil ratio, and bitumen price. Reservoir properties like porosity,permeability, and water saturation are measured from 13 cores and calculated from 201 well-logs. Three dimensional volumes of reservoir properties are constructed mostly based on relationships among properties. Finally, net present value(NPV) volume can be built by equation relating NPV and SPIDER. The economic area exceeding criterion of US$ 10,000 is identified, and the ranges of reservoir properties are estimated. NPV-volume-generation workflow from reservoir parameter to static model provides costand time-effective method to evaluate the oilsands SAGD project.     

A potential stratotype for the regional lowermost stage of the continental Paleocene in China

Phanerozoic chronostratigraphic units can only be defined through their lower boundary stratotypes.The lowermost stage of the Paleocene of China,which mainly consists of terrestrial deposits,can only be defined through its lower boundary stratotype,i.e.the continental Cretaceous/Paleogene boundary stratotype.There is no section yet found which contains continuous terrestrial deposits and biostratigraphic records of the Cretaceous-Paleogene transition in Nanxiong,Guangdong and Jiayin,Heilongjiang,there is no evidence for establishing the continental stratotype of the Cretaceous/Paleogene boundary in either area.Therefore,both the"Shanghuan stage"and"Furaoan stage"are not good candidates for the lowermost stage of the Paleocene of China.From the viewpoint of charophytes,the outcrop section of the Dangyang,Hubei Province(Central China)contains the most continuous,abundant and diverse terrestrial biostratigraphic records of the Cretaceous-Paleogene transition,in particular the early Paleocene,known so far in the world.The biostratigraphic records of ostracods in the transition are also continuous,rich,and diverse.The Dangyang outcrop section is the only section known so far in China that is a possible candidate for a continental stratotype of the Cretaceous/Paleogene boundary in China and the section is the only potential section identified to date for establishing the regional lowermost stage of the Paleocene,Paleogene and Cenozoic in China or stratotype section for the stage.     

Need and opportunity for a North American caribou knowledge cooperative

The importance of migratory caribou ( Rangifer tarandus ) to northerners, the increasing pressure to extract non-living resources, and predicted global climate change have led researchers, managers and resource users alike to focus on how to improve our knowledge of this unique northern ungulate. Unprecedented threats to caribou sustainability, along with the increasingly acknowledged value of indigenous hunters'contribution to caribou research, pose the additional challenge to innovate research methods that accommodate differing cultural perspectives and facilitate communication among groups. This paper surveys the state of scientific knowledge of the eleven major northern mainland herds of North America. We recommend an approach to improve our working knowledge of barren-ground caribou in order to assess better future impacts. The transfer of knowledge gained from years of research and indigenous experience on many aspects of caribou ecology should be evaluated and, where applicable, transferred to herds with more modest databases. The establishment of a North American Caribou Monitoring and Assessment System, based on a synthesis of local knowledge and research-based science, is recommended as a tool for improved communication and collective learning.     

华北基性岩墙群的古地磁极及其哥伦比亚超大陆重建意义

从华北克拉通的中西部和东部发育的基性岩墙群获得三个精确定年的实际古地磁极位置(VGPs)。华北克拉通中西部恒山GU岩墙的斜锆石U-Pb年龄为1769±3Ma,该岩墙的古地磁给出古地磁极位置在北纬36°,东经247° (dp=2, dm=4); 华北克拉通东部DY岩墙的斜锆石U-Pb年龄为1620.8±6.9Ma, 获得的古地磁极位置为北纬6.9°东经81.9°(dp=4.31, dm=6.09); 东部另一条岩墙LW4的SHRIMP U-Pb 年龄为1157±18Ma, 获得的古地磁极位置为北纬27.1°东经162°(dp=15.8, dm=18.7)。通过将这三个从基性岩墙获得的华北克拉通古地磁极位置与加拿大地盾的中元古代视极移曲线对比,在中元古代早期（1800~1600Ma）,华北克拉通与加拿大地盾一起同属哥伦比亚超大陆,而在中元古代晚期（1600~1200Ma）,华北克拉通与加拿大地盾分离,响应哥伦比亚超大陆的最终裂解事件。     

Aluminum-dependent trace element partitioning in clinopyroxene

As technical advances have dramatically increased our ability to analyze trace elements, the need for more reliable data on the compositional dependence of trace element partitioning between minerals and melt has become increasingly important. The late-Cretaceous Carmacks Group of south central Yukon comprises a succession of primitive high-Mg ankaramitic lavas characterized by shoshonitic chemical affinities and containing large complexly zoned clinopyroxene phenocrysts. The compositional zonation of the clinopyroxene phenocrysts is characterized by relatively Fe-rich (Mg^# = Mg/(Mg + Fe) = 0.85), but mottled, cores surrounded by mantles of cyclically-zoned clinopyroxene whose Mg^# varies repeatedly between 0.9 and 0.80. These cyclically zoned clinopyroxene mantles appear to record the repeated influx and mixing of batches of primitive with more evolved magma in a deep sub-crustal (∼1.2 GPa) magma chamber(s). Laser ablation ICP-MS was used to analyze the trace element variation in these zoned clinopyroxenes. The results indicate more than a threefold variation in the absolute concentrations of Th, Zr, rare earth elements (REE), and Y within individual clinopyroxene phenocrysts, with no apparent change in the degree of REE or high field strength element (HFSE) fractionation. The variation in absolute abundances of trace elements correlates closely with the major element composition of the clinopyroxene, with the most enriched clinopyroxene having the lowest Mg^# and highest Al contents. The problem is that the amount of crystal fractionation required to explain the major element variation (∼20%) in these clinopyroxene phenocrysts cannot explain the increase in the abundance of the incompatible trace elements, which would require more than 70% crystal fractionation, if constant partition coefficients are assumed. The anomalous increase in incompatible trace elements appears to reflect an increase in their partition coefficients with increasing Al^IV in the clinopyroxene; with an increase in Al₂O₃ from 1.5 to 4.0 wt.% during ∼20% crystal fractionation over a temperature decrease of ∼100°C being associated with more that a threefold increase in the partition coefficients of Th, Zr, REE, and Y. The magnitude of these increases may indicate that the substitution of these trace elements into clinopyroxene is better modeled in some natural systems by a local charge balance model, rather than the distributed charge model that better replicates the results of annealed experiments. These findings indicate that the effect of Al on the partition coefficients of incompatible trace elements in clinopyroxene may be under appreciated in natural magmatic systems and that the application of experimentally determined clinopyroxene partition coefficients to natural systems must be done with caution.