The Leonard Award Address Presented 1996 July 25, Berlin,Germany: The elemental composition of stony cosmic spherules

Abstract— Five hundred stony cosmic spherules collected from deep-sea sediments, polar ice, and the stratosphere have been analyzed for major and some minor element composition. Typical spherules are products of atmospheric melting of millimeter sized and smaller meteoroids. The samples are small and modified by atmospheric entry, but they are an important source of information on the composition of asteroids. The spherules in this study were all analyzed in an identical manner, and they provide a sampling of the solar system's asteroids that is both different and less biased than provided by studies of conventional meteorites. Volatile elements such as Na and S are depleted due to atmospheric heating, while siderophiles are depleted by less understood causes. The refractory nonsiderophile elements appear not to have been significantly disturbed during atmospheric melting and provide important clues on the elemental composition of millimeter sized meteoroids colliding with the Earth. Typical spherules have CM-like composition that is distinctively different than ordinary chondrites and most other meteorite types. We assume that C-type asteroids are the primary origin of spherules with this composition. Type S asteroids should also be an important source of the spherules, and the analysis data provide constraints on their composition. A minor fraction of the spherules are melt products of precursor particles that did not have chondritic elemental compositions. The most common of these are particles that are dominated by olivine. The observed compositions of spherules are inconsistent with the possibility that an appreciable fraction of the spherules are simply chondrules remelted during atmospheric entry.     

Geochemistry and Rb–Sr geochronology of a ductile shear zone in the Orlica-Śnieżnik dome (West Sudetes, Poland)

Amphibolite-facies orthogneisses of the Orlica-vnie™nik dome in the West Sudetes (Poland) show a local continuous transition from weakly deformed augen gneisses to finely laminated mylonites. Field evidence indicates that ductile shearing developed pre- or syntectonically to a migmatization event. Bulk-rock compositions of variably deformed samples yield no indications for deformation- and/or fluid-enhanced element mobility and redistribution. ⁸⁷Rb-⁸⁶Sr geochronology (biotite, phengite, whole rock) places time constraints on the deformation process and the post-orogenic cooling history. Phengite- and biotite-whole-rock pairs yield Rb-Sr ages of 340 to 334 Ma and 335 to 294 Ma, respectively, independent of the degree of deformation. The weighted mean of phengite-whole-rock pairs indicates an age of 337.4DŽ.3 Ma. Combining most of the biotite-whole-rock data yields a weighted mean age of 328.6dž.4 Ma. Because of their different closure temperatures for the Rb-Sr system, these differences are interpreted to date cooling after a thermal event. Direct dating of the deformation is not possible, but the cooling history record defines a minimum age for the development of ductile shearing and the last migmatization event. These time constraints provide evidence for the initiation of crustal collapse during or immediately following peak metamorphic conditions. The results of this study further document the importance of Variscan metamorphism in the Orlica-vnie™nik dome.     

Increase in Dissolved Silica of Rivers Due to a Volcanic Eruption in an Estuarine Bay (Sorsogon Bay,Philippines)

Mount Bulusan, the Philippines’ fourth most active volcano, erupted in February 21, 2011, sending volcanic ash and pyroclastic materials to its surrounding rivers. The waters drained into the estuary of harmful algal blooms plagued Sorsogon Bay. We aim to determine the impact of the 2011 volcanic eruption and the preceding volcanic ash emissions to the dissolved silica concentration of rivers draining the flanks of Mt. Bulusan and its possible implications to the phytoplankton assemblage of the bay. Six river water sampling periods from August 2010 to October 2012 overlapped with Mt. Bulusan’s active phase of volcanism. Our data shows that mean river silica from pre-eruption levels of ~?500 μM increased by more than 200% during and post-eruption. Highest Si concentration of 2270 μM was measured from Cadacan River in August 2011. Here, we argue that the sustained general increase of dissolved silica is due to the silica-containing materials from Mt. Bulusan’s eruption and that their concentration in river waters is also a function of watershed lithology and precipitation. Increase in dissolved silica and other nutrients caused a shift to diatom domination and, possibly, termination of Pyrodinium bahamense var. compressum blooms. Silica load increase in embayments is a natural process that controls the dominance of algae. Our study also highlights the importance of Philippine rivers to the global ocean silica budget as a function of high precipitation, tectonics in general, and volcanism in particular.     

Capture-zone design in an aquifer influenced by cyclic fluctuations in hydraulic gradients

Design of a groundwater pumping and treatment system for a wood-treatment facility adjacent to the tidally influenced Fraser River estuary required the development of methodologies to account for cyclic variations in hydraulic gradients. Design of such systems must consider the effects of these cyclic fluctuations on the capture of dissolved-phase contaminants. When the period of the cyclic fluctuation is much less than the travel time of the dissolved contaminant from the source to the discharge point, the hydraulic-gradient variations resulting from these cycles can be ignored. Capture zones are then designed based on the average hydraulic gradient determined using filter techniques on continuous groundwater-level measurements. When the period of cyclic fluctuation in hydraulic gradient is near to or greater than the contaminant travel time, the resulting hydraulic-gradient variations cannot be ignored. In these instances, procedures are developed to account for these fluctuations in the capture-zone design. These include proper characterization of the groundwater regime, assessment of the average travel time and period of the cyclic fluctuations, and numerical techniques which allow accounting for the cyclic fluctuations in the design of the capture zone. Electronic Publication     

The detection of binary companions to subdwarf B stars

Intermediate dispersion spectroscopy of a sample of 40 hot subdwarf B stars between 5500 and 9000Å has been obtained. The sample includes a large fraction of targets which have been studied photometrically. Seven targets show strong lines arising from the infrared Ca  ii triplet, the unequivocal signature of a cool companion. The positive Ca  ii identifications include known photometric binaries and new targets; all are associated with a photometric red excess. Assuming a canonical value for the subdwarf luminosity, all of the detected companions are overluminous compared with the main sequence. The detection procedure indicates an improved and more secure method for the measurement of the binary frequency of hot subdwarfs.     

The impact of drilling fluid and well cuttings on polychaete feeding guilds from the US northeastern continental shelf

The effect of recent drilling operations (fluid and well cuttings) on polychaete feeding guilds from the continental shelf off Atlantic City, New Jersey, was examined. Although there were some adverse effects on macrobenthos from 2160 metric tons of cuttings and mud solids discharged into the marine environment, the composition of polychaete feeding guilds remained essentially unchanged. This key trophic relationship between polychaetes and the changing environment due to the drilling operation was apparently uninterrupted. This relationship remains to be examined in other natural and perturbed habitats.     

High-frequency radar observations of the June 2013 US East Coast meteotsunami

We report here on the observation and offline detection of the meteotsunami off the New Jersey coast on June 13, 2013, using coastal radar systems and tide gauges. This work extends the previous observations of tsunamis originating in Japan and Indonesia. The radars observed the meteotsunami 23 km offshore, 47 min before it arrived at the coast. Subsequent observations showed it moving onshore. The neighboring tide gauge height reading provides confirmation of the radar observations near the shore.