High-resolution aquifer analog of fluvial–aeolian sediments of the Guarani aquifer system

The Guarani aquifer system (GAS) represents one of the biggest aquifers in the world and is the most relevant groundwater resource in South America. For the first time, by combining field and laboratory measurements, a high-resolution aquifer analog model of fluvial–aeolian sediments of the GAS in São Paulo State (Brazil) is constructed. Three parallel sections of frontal outcrops, 28 m × 5.8 m, and two parallel sections of lateral outcrops, 7 m × 5.8 m, are recorded during open-pit mining of sandy sediments and describe in detail the three-dimensional distribution of the local lithofacies and hydrofacies. Variations of hydraulic conductivity, K, and porosity, n, are resolved on the centimeter scale, and the most permeable units of the fluvial–aeolian facies association are identified. The constructed aquifer analog model shows moderate hydraulic heterogeneity and a mean K value of 1.36 × 10^?4 m/s, which is greater than the reported range of K values for the entire GAS in São Paulo State. The results suggest that the examined sedimentary unit constitutes a relevant portion of the GAS in São Paulo State in the context of groundwater extraction and pollution. Moreover, the constructed aquifer analog is considered an ideal basis for future numerical model experiments, aiming at in-depth understanding of the groundwater flow and contaminant transport patterns at this GAS portion or at comparable fluvial–aeolian facies associations.     

Abundance analysis of the γ Doradus–δ Scuti hybrid metallic line (Am) star HD 8801

Low frequency oscillation, typical for γ Doradus g‐mode type stellar core sensitive pulsation, as well as higher frequency δ Scuti type pulsation typical for p ‐modes, sensitive to the envelope, make HD 8801 a remarkable hybrid pulsator with the potential to probe a stellar structure over a wide range of radius. In addition HD 8801 is a rare pulsating metallic line (Am) star. We determined the astro‐physical fundamental parameters to locate HD 8801 in the H‐R diagram. We analyzed the element abundances, paying close attention to the errors involved, and confirm the nature of HD 8801 as a metallic line (Am) star. We also determined an upper limit on the magnetic field strength. Our abundance analysis is based on classical techniques, but uses for the final step a model atmosphere calculated with the abundances determined by us. We also discuss spectropolarimetric observations obtained for HD 8801. This object is remarkable in several respects. It is a nonmagnetic metallic line (Am) star, pulsating simultaneously in p‐ and g‐modes, but also shows oscillations with periods in between these two domains, whose excitation requires explanation. Overall, the pulsational incidence in unevolved classical Am stars is believed to be quite low; HD 8801 does not conform to this picture. Finally, about 75 % of Am stars are located in short‐period binaries, but there is no evidence that HD 8801 has a companion. (© 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Metalliferous sediments from the H.M.S. Challenger voyage (1872-1876)

The legendary cruise of H.M.S. Challenger (1872-1876) around the globe must always occupy an eminent place in the annals of oceanography, as being the first systematic attempt made on a global scale to explore the ocean. This expedition made fundamental discoveries in biology and geology which have not been surpassed by any later scientific cruise. Sediment with high content of metals (later called “metalliferous”) was among the enigmatic findings taken onboard. Although the nature of metalliferous sediments is well known today, the very first sampled sediments of this type have not been studied to date. Motivated by the historical value of Challenger’s metalliferous sediment collection we undertook an investigation addressing two questions: (1) the composition of sediments from seafloor for which we have very limited data; (2) Sr-Nd-Pb-Fe-Zn-isotope signature of these sediments collected before the substantial human impact on the ocean during the 20th century.The SE Pacific metalliferous sediments sampled by the Challenger’s explorers are of 2 types: (1) metalliferous oozes blanketing ridge crests and flanks down to the calcite compensation depth (CCD); and (2) stripped of CaCO₃ metalliferous sediments located beneath the CCD in the deeps near the mid-ocean ridges. The abiogenic part of these sediments is composed mainly of poorly-crystalline to X-ray amorphous Fe-Mn-oxyhydroxides, and an amorphous silicate phase. These sediments have geochemical features similar to those of all the other metalliferous sediments: very high Fe and Mn content (on abiogenic basis), very low Al/(Al + Fe + Mn), and high content (on abiogenic basis) of As, Ba, Be, Bi, Cd, Co, Cu, Mo, Ni, Pb, Sb, Th, Tl, U, V, W, Y, Zn and Zr. Their REE distribution patterns are similar to that of deep seawater and show weak signs of hydrothermal imprint (weak positive or no Eu anomaly).Seawater and/or terrigenous input from South America control the Sr-Nd-Pb-isotope signature of the Challenger metalliferous sediments and have almost completely obliterated any original MORB-derived hydrothermal signal. Zn isotopes are mainly contributed from seawater although other Zn sources (hydrothermal fluid and detrital aluminosilicates, barite and volcanic glass) are necessary to fully explain Zn-isotope ratios. Fe isotopes indicate relatively slow Fe²⁺ to Fe³⁺ oxidation in the non-buoyant plume, thus producing relatively lighter Fe-isotope signature of the FeOOH particles that formed the studied metalliferous sediments.     

Sodium-cadmium and sodium-zinc exchangeability in montmorillonite

A sodium montmorillonite from Ivan?ice (Czech Republic) was treated with solutions containing various molar concentrations of Zn and Cd for the purpose of determining ion exchange equilibria. The sorption isotherms for Zn and Cd exhibit a rather similar shape, which depends on pH; the maxima for Zn and Cd sorbed on Na-montmorillonite are very close to each other (e.g., 0.419?mmol/1?g and 0.440?mmol/1?g, respectively, for pH=5). It is a characteristic of both elements that a high level of sorption is reached at low concentration in solution. The leachability of Zn and Cd in deionized water from fully saturated montmorillonites is very similar, but a different results were observed for Na leached from fully saturated Na-montmorillonite. The total amount of leached Na was 21.7% (after four consecutive leaching runs). However, only 2.1% and 1.6% were found for Cd and Zn, respectively. Different quantities of Cd and Zn exchanged in Na-montmorillonite influence significantly the shape and position of maximum of the 001 XRD profile. Experimental XRD profiles of montmorillonites, fully saturated with Na, Cd and Zn, corrected for instrumental and physical factors exhibit maxima at 12.59, 14.86, and 14.77?Å, respectively. When the d ₀₀₁ spacing is determined from a corrected profile, it varies systematically with the percentage of exchanged Zn and Cd and the relationships seem to be linear for both elements. For montmorillonites, not fully saturated with one element, the peak shift and peak broadening, characteristic for mixed layered structures with random layer sequences, has been observed.     

Robust design of self-starting drains using Random Forest

Groundwater lowering is one of the most important countermeasures to avoid the risk of rainfall-triggered landslides. However, the long-term reliability of many drainage methods is often a matter of concern since the drains may easily get clogged. A new hydraulic-driven self-starting drainage method is presented in this paper. In the proposed Random Forest(RF) based robust design approach for the selfstarting drains, the datasets are generated using an automatically controlled numerical modeling technology. The deterministic analysis is carried out based on uncertain soil parameters and the specific designs selected using Uniform Design(UD). The ensemble of RF models is applied in the design process to improve computing efficiency. Safety requirements, design robustness, and cost efficiency are simultaneously considered utilizing multiobjective optimization. A straightforward and efficient framework that focuses on difficulties caused by an enormous design space is established for the robust design of the self-starting drains, and improved computation efficiency is achieved. The effectiveness of the proposed approach is illustrated with a case study, the Qili landslide in Zhejiang Province, China.