Fractional Crystallization and Liquid Immiscibility Processes in the Alkaline-Carbonatite Complex of Juqui (So Paulo, Brazil)

The Juqui circular intrusion, which is Cretaceous in age (130–135Ma), crops out in the Precambrian gneissic basement in Brazilover an area of 14 km2. It consists of olivine clinopyroxen-itecumulates (with minor olivine gabbros) in the northeastern sector(74 vol.%), whereas ijolites-melteigites-urtites (4%) and nephelinesyenites with minor essexites and syenodiorites (21%) outlinesubannular concentric patterns with an Mg-carbonatite core (1%), in the southwestern part of the complex. Petrographical, bulk rock, and mineral compositional trendsindicate that the origin of the complex can be largely accountedfor by shallow-level fractional crystallization of a carbonatedbasanitic parental magma. Such a magma was generated deep inthe subcontinental lithosphere by low-degree partial meltingof a garnet-phlogopite peridotite source. Mass-balance calculations in agreement with field volume estimatespermit definition of several fractionation stages of the magmaticevolution under nearly closed-system conditions, with inwarddevelopment of zonally arranged side-wall cumulates. These stagesinvolved: (1) fractionation from basanite to essexite magma(liquid fraction F = 33–5%) by crystallization of olivineclinopyroxenite plus minor olivine alkali gabbro cumulates;(2) derivation of the least differentiated mafic nepheline syenite(F = 5–5 %) from essexitic magma by subtraction of a syenodioriteassemblage; (3) exsolution of a carbonatite liquid (5%) froma CO₂-enriched mafic nepheline syenite magma, which also underwentcontinuous fractionation giving rise to ijolite-melteigite-urtitecumulates. The proportion of cumulus clinopyroxene and biotiteand intercumulus nepheline and alkali feldspar in these lastrocks, as well as the absence of alkalis in carbonatite, maybe attributed, at least in part, to loss of alkali-rich hydrousfluids released during and after the unmixing formation of thetwo conjugate liquids. The KD values determined for Mg-carbonatite/nepheline syeniteare lower (1–4–2–9) for light rare earth elements(LREE) than for REE from Eu to Yb (4–6–7–8),in contrast to recent experimental results (Hamilton et al.,1989). A possible explanation is that Juquia Mg-carbonatiterepresents an alreadydifferentiated magma, which underwent extensivefractionation of LREE-enriched calcite. In this way, the highvariability of K₀ REE patterns observed in several alkaline-carbonatitecomplexes can also be accounted for. The remarkably constant initial ⁸⁷Sr/⁸⁶Sr ratios (mostly between0–7052 and 0–7057) support the interpretation ofthe intrusion as having been generated by fractrional crystallizationand liquid immiscibility from a common parental magma. Iligherisotopic ratios (0–7060–0–7078), found mainlyin dykes and in the border facies of the intrusion, may be dueto contamination by the gecissic basement.     

Investigation of a eutrophic tidal basin: part 1—factors affecting the distribution and biomass of macroalgae

The distribution and biomass of macroalgae, principally Enteromorpha spp., have been estimated in Langstone Harbour, a 19 km² tidal basin in southenrn England. Comprehensive mapping was carried out annually at the time of maximum biomass and monthly mapping of selected areas allowed seasonal changes to be studied. Aerial false-colour photography and ground-level mapping were used for assessing the area and density of cover of macroalgae, but have identified no continuous trends between 1973 and 1982. In nine years, some 48% of the intertidal mudflat has supported >75% macroalgal cover at some stage, but generally only one-third of this potential has been achieved annually. The average peak biomass was determined by a stratified sampling method and varied about a mean of 38.5 g dry weight per square metre and showed significant annual differences. The processes controlling macroalgal growth and distribution reviewed, but, in general, factors other than nutrient availability are effective in determining areas supporting high macroalgal cover in any particular year.     

The Askervein hill project: A finite control volume prediction of three-dimensional flows over the hill

A three-dimensional nonlinear numerical model, that has been extensively used previously to predict environmental water flows, was applied to predict the flow over an isolated hill, Askervein. Predictions are reported for winds approaching the hill from 210 ° and 180 ° clockwise from north, both under almost neutral atmospheric conditions.The model predictions were compared with data collected during a major field study in 1983. From the comparisons it was concluded that the model predicts the mean flow variables with good accuracy. Larger discrepancies were found for quantities related to the turbulence, pointing to deficiencies in the turbulence model, and perhaps in some of the measurements.     

The Role of Forests in the Implementation of Russia’s Low-Carbon Development Strategy

Doklady Earth Sciences - The potential role of forests in achieving carbon neutrality in the Russian Federation by 2060 is analyzed. It is shown that the key rate in the Strategy for the...     

Stability and phase relations of nonstoichiometric clinopyroxenes in the join diopside-Ca-Eskola component at high pressures

The stability of nonstoichiometric clinopyroxenes in the Di-CaEsk join was experimentally studied, and phase diagrams were constructed for this join at pressures of 2.0 and 3.0 GPa. It was found that melting in the diopside part of the join occurs at anomalously low temperatures, and nonstoichiometric clinopyroxene coexists with a phase approaching diopside in composition. Phase relations along the Di-CaEsk join can be described and consistently interpreted only assuming that the diopside phase (α-diopside) is thermodynamically stable. The following phase volumes were observed along the solidus of the join at a pressure of 3.0 GPa: Cpx, αDi+Cpx, αDi+Cpx+Qtz, αDi+Cpx+Grt+Qtz, Cpx+Grt+Qtz, Cpx+Grt+Ky+Qtz, Grt+Ky+Qtz. Melting occurs via the eutectic reaction αDi+Cpx+Grt+Qtz=L at a temperature of about 1200°C in the diopside part of the system and via the eutectic reaction Cpx+Grt+Ky+Qtz=L at a temperature of 1400°C in the calcium-rich part of the system. At a pressure of 2.0 GPa, melting occurs at temperatures of 1200–1300°C via the eutectic reaction αDi+Cpx+ An + Qtz=L. The invariant equilibrium (L, An, Cpx, Grt, αDi, Qtz) lies within the pressure range 2.0–3.0 GPa. Nonstoichiometric clinopyroxenes form complex solid solutions, the compositions of which are not strictly confined to the Di-CaEsk join and depend on temperature, pressure, and phase association. Grossular garnets coexist with nonstoichiometric clinopyroxenes and α-diopside.     

Non-linear fluid dynamics of eccentric discs

A new theory of eccentric accretion discs is presented. Starting from the basic fluid-dynamical equations in three dimensions, I derive the fundamental set of one-dimensional equations that describe how the mass, angular momentum and eccentricity vector of a thin disc evolve as a result of internal stresses and external forcing. The analysis is asymptotically exact in the limit of a thin disc, and allows for slowly varying eccentricities of arbitrary magnitude. The theory is worked out in detail for a Maxwellian viscoelastic model of the turbulent stress in an accretion disc. This generalizes the conventional alpha viscosity model to account for the non-zero relaxation time of the turbulence, and is physically motivated by a consideration of the nature of magnetohydrodynamic turbulence. It is confirmed that circular discs are typically viscously unstable to eccentric perturbations, as found by Lyubarskij, Postnov & Prokhorov, if the conventional alpha viscosity model is adopted. However, the instability can usually be suppressed by introducing a sufficient relaxation time and/or bulk viscosity. It is then shown that an initially uniformly eccentric disc does not retain its eccentricity as had been suggested by previous analyses. The evolutionary equations should be useful in many applications, including understanding the origin of planetary eccentricities and testing theories of quasi-periodic oscillations in X-ray binaries.     

Quantification of the environmental structural risk with spoiling ties: is randomization worthwhile?

Many recent works show that copulas turn out to be useful in a variety of different applications, especially in environmental sciences. Here the variables of interest are usually continuous, being times, lengths, weights, and so on. Unfortunately, the corresponding observations may suffer from (instrumental) adjustments and truncations, and eventually may show several repeated values (i.e., ties). In turn, on the one hand, a tricky issue of identifiability of the model arises, and, on the other hand, the assessment of the risk may be adversely affected. A possible remedy is to adopt suitable randomization procedures: here three different strategies are outlined. The goal of the work is to carry out a simulation study in order to evaluate the effects of the randomization of multivariate observations when ties are present. In particular, it is investigated whether, how, and to what extent, the randomization may change the estimation of the structural risk: for this purpose, a coastal engineering example will be used, as archetypical of a broad class of models and problems in engineering applications. Practical advices and warnings about the use of randomization techniques are hence given.     

Modeling of deep-seated high-alumina parageneses on the basis of the stability fields of corundum- and spinel-normative assemblages of the system CaO–MgO–Al2O3–SiO2

To elaborate physicochemical models for the origin of crystalline rocks, experimental studies of the field of high-alumina assemblages of the system CaO–MgO–Al₂O₃–SiO₂ were carried out at 10–30 kbar and 1250–1535 °C. We have determined the phase relations between the melt (L) and An, Sp, Cpx, Cor, and Ga, the slope of the rays of the monovariant reactions An + Sp = Cpx + Cor + (Ga) and L = Cpx +Ga + Cor + Sp, the position of the nonvariant point (An, Sp, Cpx, Cor, Ga, L), and the compositions of phases participating in these reactions. Based on a topological analysis of the studied segment of the system CaO–MgO–Al₂O₃–SiO₂, we have substantiated that “eclogitization” must follow the reaction Opx + An + Sp = Cpx + Ga. A fundamental continuous series of eutectic monovariant equilibria was observed: L = Cpx + Opx + Fo + An, L = Cpx + Opx + An + Sp, L = Cpx (+ Ga) + An + Sp, and L = Cpx + Cor (+ Ga) + An. A change in the melt composition in this series of eutectic reactions depending on pressure must reflect the most likely magma genesis trend in nature. Comparision of the composition fields in which the above series of reactions is observed with the composition fields of the rocks of magmatic formations showed that this series is most similar to the alkali-earth series of rocks. The mineralogical compositions of cumulates and phenocrysts found in the effusive and dike varieties of these rocks correspond to unique sets of subsolidus phase associations and individual subsolidus phases crystallizing in this fundamental eutectic series.