Theoretical growth morphology of whewellite CaC2O4·H2O

The morphological theory of Hartman and Perdok (1955, 1956) allows to deduce the character of a growth form {hkl} on the basis of structural data alone. Its application to the structure of whewellite leads to the identification of forms {100}, {010}, {021}, {011}, {12 \(\bar 1\) } and {121} which show during the growth a flat surface profile (flat forms F). These forms occur very frequently in the crystals we grew from pure aqueous solutions at supersaturation β≦1,90. Other forms, {001} and {10 \(\bar 1\) }, possibly show a double character (F or S, where S stays for related faces showing a stepped profile during the growth) according to the bonds assumed within some periodic bond chains (PBCs). Alternative ways of bonding water molecules lead to different structures of the same PBC. The different energy corresponding to these structures may explain the complex morphology of both natural and synthetic crystals grown at high β values.     

Economic damages due to extreme precipitation during tropical storms: evidence from Jamaica

Natural Hazards - This study investigates economic damage risk due to extreme rainfall during tropical storms in Jamaica. To this end, remote sensing precipitation data are linked to regional...     

Prediction of the effects of size and morphology on the structure of water around hematite nanoparticles

Compared with macroscopic surfaces, the structure of water around nanoparticles is difficult to probe directly. We used molecular dynamics simulations to investigate the effects of particle size and morphology on the time-averaged structure and the dynamics of water molecules around two sizes of hematite (α-Fe₂O₃) nanoparticles. Interrogation of the simulations via atomic density maps, radial distribution functions and bound water residence times provide insight into the relationships between particle size and morphology and the behavior of interfacial water. Both 1.6 and 2.7 nm particles are predicted to cause the formation of ordered water regions close to the nanoparticle surface, but the extent of localization and ordering, the connectivity between regions of bound water, and the rates of molecular exchange between inner and outer regions are all affected by particle size and morphology. These findings are anticipated to be relevant to understanding the rates of interfacial processes involving water exchange and the transport of aqueous ions to surface sites.     

Chaos in N-body systems

Here is a selection of applications of what is now called theory of dynamical systems in galactic dynamics and N-body systems. The study of chaotic motions in potentials used as a model for elliptical galaxies is a first example of these applications. The interest in this problem stems from the fact that there are now many theoretical and observational evidences that the overall potentials of galaxies are indeed non-integrable. There are classes of objects, for example small and intermediate luminosity elliptical galaxies, for which the presence of the famous third integral is not necessary or others in which we observe peculiarities in their photometry or kinematics. We address here some of these issues and their implications in modifying our current understanding of the structure and evolution of galaxies.More in general, there is the natural question of how the systems we see have settled to their present status and what would happen if some external cause perturbs it. This issue is related to the question of the stochasticity involved in the general N-body dynamics, especially when N is very large. An N-body dynamical system is definitely chaotic, as shown by several numerical investigations, at least for N not very large. However, this statement must be reconciled with the picture of non-collisional equilibrium of big systems. The second part of this review presents a survey of numerical experiments and an interpretation of the results obtained using standard chaoticity indicators.     

Combining Seismic Noise Techniques for Landslide Characterization

A strong topographic relief and the presence of weakly consolidated sediments create favorable conditions for the development of landslides around the eastern rim of the Fergana Basin (Central Asia). In summer 2012, a field experiment employing small aperture seismic arrays was carried out on an unstable slope, using ambient vibration recordings. The aim of the study was to constrain the seismic response of a potential future landslide and to map lateral and vertical changes in the shear-wave velocity of the surficial soil layers. Strong variations of horizontal-to-vertical spectral ratios in terms of amplitude and directionality indicated clear differences in local site effects, probably reflecting the stability of different sections of the slope. Results further showed resonant frequencies of both the entire unstable block, as well as for smaller, individual parts. The use of an ad hoc, passive seismic tomography approach based on noise correlograms allowed for the mapping of the shear-wave velocities of the sliding material, even in cases of significant topography relief. Based on the recording of seismic noise only, we clearly identified a low-velocity body of weakly consolidated claystone and limestone material, which can be interpreted as the landslide body, with laterally varying thickness.     

Estimating parameters of the channel width–flow discharge relation using rill and gully channel junction data

Eroding channels can usually be characterized by a power relationship between channel width (W) and channel discharge (Q). This paper examines the WQ relation using a recently developed channel junction approach to extend the validity of the WQ relation and to develop a procedure for estimating the WQ exponent and proportionality coefficient. Rill and gully channel data from the literature, and new data collected in different badland areas and in a few forest mountain streams, are analysed. Analysis shows that the WQ relation for channel width collected in badlands and forests agrees with trends observed for cropland. The exponent increases with increasing channel width in a continuous fashion rather than in a step‐like way and tends to a maximum whose value ranges between 0·5 and 0·6. The proportionality coefficient can be split into two terms, one expressing the case in which an eroding channel can broaden, the other reflecting the difficulties in removing the less erodible clods or rock fragments from the channel bed. Its splitting allows the development of a more correct form of the WQ relation in agreement with modern approaches of channel geometry: one part has the dimension of a discharge and makes the power base dimensionless, while the other brings the dimension of a length, needed for the channel width, into the WQ relation. The interpretation of the two constants is supported by data collected in rainfall‐runoff simulation experiments conducted in the field. Values characterizing the two constants in some environments are also given. Nevertheless the approach is not sufficiently parameterized yet to be of practical use (e.g. in models or for estimating peak discharge in areas where rill channels have formed). Copyright © 2009 John Wiley & Sons, Ltd.     

Partially non-ergodic region specific GMPE for Europe and Middle-East

The ergodic assumption considers the time sampling of ground shaking generated in a given region by successive earthquakes as equivalent to a spatial sampling of observed ground motion across different regions. In such cases the estimated aleatory variability in source, propagation, and site seismic processes in ground motion prediction equations (GMPEs) is usually larger than with a non-ergodic approach. With the recently published datasets such as RESORCE for Europe and Middle-East regions, and exploiting algorithms like the non-linear mixed effects regression it became possible to introduce statistically well-constrained regional adjustments to a GMPE, thus ‘partially’ mitigating the impact of the assumption on regional ergodicity. In this study, we quantify the regional differences in the apparent attenuation of high frequency ground motion with distance and in linear site amplification with V_s30, between Italy, Turkey, and rest of the Europe-Middle-East region. With respect to a GMPE without regional adjustments, we obtain up to 10 % reduction in the aleatory variability σ, primarily contributed by a 20 % reduction in the between-station variability. The reduced aleatory variability is translated into an epistemic uncertainty, i.e. a standard error on the regional adjustments which can be accounted for in the hazard assessment through logic-tree branches properly weighted. Furthermore, the between-event variability is reduced by up to 30 % by disregarding in regression the events with empirically estimated moment magnitude. Therefore, we conclude that a further refinement of the aleatory variability could be achieved by choosing a combination of proxies for the site response, and through the homogenization of the magnitude scales across regions.     

“Galileo Galilei” (GG) a small satellite to test the equivalence principle of Galileo, Newton and Einstein

“Galileo Galilei” (GG) is a small satellite designed to fly in low Earth orbit with the goal of testing the Equivalence Principle—which is at the basis of the General Theory of Relativity—to 1 part in 10¹⁷. If successful, it would improve current laboratory results by 4 orders of magnitude. A confirmation would strongly constrain theories; proof of violation is believed to lead to a scientific revolution. The experiment design allows it to be carried out at ambient temperature inside a small 1-axis stabilized satellite (250 kg total mass). GG is under investigation at Phase A-2 level by ASI (Agenzia Spaziale Italiana) at Thales Alenia Space in Torino, while a laboratory prototype (known as GGG) is operational at INFN laboratories in Pisa, supported by INFN (Istituto Nazionale di fisica Nucleare) and ASI. A final study report will be published in 2009.